Properties,synthesis and toxicity of silver nanoparticles

Silver nanoparticles are actually used in several industrial sectors and end up in the environment, thus inducing a possible toxicity for living organisms. This article reviews the properties, synthesis and toxicology of silver nanoparticles, with focus on the toxicity for insects such as Bombyx mori.     

Trace elements and organochlorine pollutants in selected fish species from Lake Phewa,Nepal

Lake water and fish livers and gills of sahar (Tor putitora), spiny eel (Mastacembelus armatus), African magur (Clarias gariepinus), and tilapia (Oreochromis niloticus) from Lake Phewa, Nepal, were assessed for the concentrations of trace metals/elements and persistent organic pollutants. The lake water was neutral with low ionic and metallic concentrations as compared to high-altitude lakes of Nepal. The four elements Cu, Zn, Se, and Cd had highest concentrations in livers, indicating uptake from diet, whereas four other metallic elements Cr, Mn, Ni, and Pb had highest concentrations in gills, indicating uptake from lake water. O. niloticus tended to have most of trace metals in the liver at higher concentrations than the other species but significant differences among the different species were found only for Mn, Ni, and Zn in the gills. A pilot study on the concentrations of persistent organic pollutants in muscle revealed that dichlorodiphenyltrichloroethane and related compounds were the dominant organochlorine pesticides, having highest concentrations in C. gariepinus and lowest in O. niloticus.     

Integration of traditional and innovative characterization techniques for flux-based assessment of Dense Non-aqueous Phase Liquid (DNAPL) sites

Key attributes of the source zone and the expanding dissolved plume at a trichloroethene (TCE) site in Australia were evaluated using trends in groundwater monitoring data along with data from on-line volatile organic compound (VOC) samplers and passive flux meters (PFMs) deployed in selected wells. These data indicate that: (1) residual TCE source mass in the saturated zone, estimated using two innovative techniques, is small ( 10 kg), which is also reflected in small source mass discharge ( 3 g/day); (2) the plume is disconnecting, based on TCE concentration contours and TCE fluxes in wells along a longitudinal transect; (3) there is minimal biodegradation, based on TCE mass discharge of  6 g/day at a plume control plane  175 m from source, which is also consistent with aerobic geochemical conditions observed in the plume; and (4) residual TCE in the vadose zone provides episodic inputs of TCE mass to the plume during infiltration/recharge events. TCE flux data also suggest that the small residual TCE source mass is present in the low-permeability zones, thus making source treatment difficult. Our analysis, based on a synthesis of the archived data and new data, suggests that source treatment is unwarranted, and that containment of the large TCE plume ( 1.2 km long,  0.3 km wide; 17 m deep;  2000–2500 kg TCE mass) or institutional controls, along with a long-term flux monitoring program, might be necessary. The flux-based site management approach outlined in this paper provides a novel way of looking beyond the complexities of groundwater contamination in heterogeneous domains, to make intelligent and informed site decisions based on strategic measurement of the appropriate metrics.     

Adsorption of Reactive Dye on Chitin

The adsorption of reactive dye on chitin has been investigated with a view to obtain the design data for batch processing of effluents for dye adsorption. The effect of several factors governing the dye adsorption such as the adsorbent concentration, adsorbent size, temperature and pH have been elicited. Desorption of the dye at different temperatures and pH have also been investigated.     

Effect of crude oil contamination on the chlorophyll content and morpho-anatomy of Cyperus brevifolius (Rottb.) Hassk

Chlorophyll plays a pivotal role in the plant physiology and its productivity. Cultivation of plants in crude oil contaminated soil has a great impact on the synthesis of chlorophyll pigment. Morpho-anatomy of the experimental plant also shows structural deformation in higher concentrations. Keeping this in mind, a laboratory investigation has been carried out to study the effect of crude oil on chlorophyll content and morpho-anatomy of Cyperus brevifolius plant. Fifteen-day-old seedling of the plant was planted in different concentrations of the crude oil mixed soil (i.e., 10,000, 20,000, 30,000, 40,000, and 50,000 ppm). A control setup was also maintained without adding crude oil. Results were recorded after 6 months of plantation. Investigation revealed that there is a great impact of crude oil contamination on chlorophyll content of the leaves of the experimental plant. It also showed that chlorophyll a, chlorophyll b, and total chlorophyll content of leaves grown in different concentrations of crude oil were found to be lower than those of the control plant. Further, results also demonstrated that chlorophyll content was lowest in the treatment that received maximum dose of crude oil. It also showed that chlorophyll content was decreased with increased concentration of crude oil. Results also demonstrated that there was a reduction in plant shoot and root biomass with the increase of crude oil concentration. Results also revealed that the shoot biomass is higher than root biomass. Morphology and anatomy of the experimental plant also show structural deformation in higher concentrations. Accumulation of crude oil on the cuticle of the transverse section of the leaves and shoot forms a thick dark layer. Estimation of the level of pollution in an environment due to oil spill is possible by the in-depth study of the harmful effects of oil on the morphology and anatomy and chlorophyll content of the plants grown in that particular environment.     

Tropical storm off Myanmar coast sweeps reefs in Ritchie’s Archipelago, Andaman

The reefs in some islands of Andaman and Nicobar suffered severe damage following a tropical storm in the Bay of Bengal off Myanmar coast during 13–17 March 2011. Surveys were conducted at eight sites in Andaman, of which five were located in the Ritchie’s Archipelago where maximum wind speeds of 11 m?s^-1 was observed; and three around Port Blair which lay on the leeward side of the storm and had not experienced wind speeds of more than 9 m?s^-1. Corals in the shallow inshore reefs were broken and dislodged by the thrust of the waves. Significant damage in the deeper regions and offshore reefs were caused by the settlement of debris and sand brought down from the shallower regions. The fragile branching corals (Acropora sp.) were reduced to rubbles and the larger boulder corals (Porites sp.) were toppled over or scarred by falling debris. The reefs on the windward side and directly in the path of the storm winds were the worst affected. The investigation exposes the vulnerability of the reefs in Andaman to the oceanographic features which generally remain unnoticed unless the damage is caused to the coastal habitats.     

Unique phenotypes in the sperm of the earthworm Eudrilus eugeniae for assessing radiation hazards

The earthworm, Eudrilus eugeniae is a segmented worm. It has two pairs of testes whose cells are highly proliferative. It was found that the earthworm, which is irradiated with X-ray, shows the following phenotypic changes in its sperm: fragmented acrosome in the head, break in the tail, and the appearance of zigzag sperm tail. Sperm morphology can be used as a tool to study radiation hazards in local areas. These three phenotypes were not observed in the sperm of worms exposed to different concentration of toxic chemicals such as sodium arsenate, lead acetate, and mercuric chloride. In contrast, exposure of worms to ethidium bromide caused fragmented acrosome in the head of their sperm cells.     

Calibration and Validation of SWAP to Simulate Conjunctive Use of Fresh and Saline Irrigation Waters in Semi-Arid Regions

Soil–Water–Atmosphere–Plant (SWAP) version 2.0 was evaluated for its capability to simulate crop growth and salinity profiles at Agra (India) located in a semi-arid region having deep water table and monsoon climate. The data of 12 conjunctive use treatment combinations simulating cyclic and mixing modes of fresh and saline water for wheat were used to calibrate and validate the model. Absolute deviations between the SWAP simulated and observed relative yields during calibration ranged from 2.5 to 2.9 %. A close agreement in the trend and values of measured and simulated soil salinity profiles was observed. Scenario building simulations carried out with the validated SWAP revealed that the maximum crop yields varied from 97 to 99 % with the best available water (EC 3.6 dS m^?1) while the minimum ranged from 65 to 79 % in the treatment with all saline water. Other than this, the relative yield varied from 80 to 98 % in 10 other cyclic and mixing mode treatments. It was established that notwithstanding the seasonal build-up of salts due to saline water use, there would be no long-term build-up of salts as leaching during the monsoon season would render the soil profile salt free at the time of sowing of rabi (winter) crops. Thus, short-term field observations could be used in conjunction with SWAP to show that there seems to be an assured long-term sustainability when saline water is used in conjunctive mode with fresh water in monsoon climatic conditions with deep water table. These results are in conformity with the observation that many farmers in India are using saline and fresh water in conjunctive mode on a long-term basis.     

Temporal Moment Analysis of Multi-Species Radionuclide Transport in a Coupled Fracture-Skin-Matrix System with a Variable Fracture Aperture

This paper presents an analysis using temporal moments to study multi-species radionuclide transport along a single fracture with variable fracture aperture in a fracture-skin-matrix system. In the present study, a decay chain having three elements is considered and transport of each member in the decay chain is modeled by solving a coupled system of partial differential equations for fracture, fracture-skin, and rock matrix using explicit finite difference method. Having obtained the concentration distribution, lower order temporal moments of radionuclide distribution are computed to analyze the effective velocity and macro-dispersion coefficient of radionuclides in the fracture. In the present study, effect of varying fracture aperture on transport characteristics of radionuclides is also analyzed. It is found that the fracture aperture variation profile has significant impact on radionuclide distribution along the fracture. Sensitivity analysis is carried out in a fracture-skin-matrix system with sinusoidal fracture aperture to study the effect of various parameters like fracture aperture thickness, fracture-skin porosity, fracture-skin diffusion coefficient, flow rate, radioactive decay constant, and Freundlich sorption isotherm exponent on transport characteristics of radionuclide. The results suggest that the above mentioned parameters significantly influence concentration, distribution, mobility, and effective macro-dispersion coefficient of radionuclides along the fracture.