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381.
Winkelmann K Sharma VK Lin Y Shreve KA Winkelmann C Hoisington LJ Yngard RA 《Chemosphere》2008,72(11):1694-1699
The aqueous photocatalytic degradation of cyanate (NCO(-)), which is a long-lived neurotoxin formed during the remediation of cyanide in industrial waste streams, was studied in the ferrate(VI)-UV-TiO2-NCO(-) system. Kinetics measurements of the photocatalytic reduction of ferrate(VI) were carried out as a function of [NCO(-)], [ferrate(VI)], [O(2)], light intensity (I(o)), and amount of TiO2 in suspensions at pH 9.0. The photocatalytic reduction rate of ferrate(VI) in the studied system can be expressed as -d[Fe(VI)]/dt=kI(o)(0.5) [NCO(-)] [TiO2]. The rate of photocatalytic oxidation of cyanate with ferrate(VI) was greater than the rate in the analogous system without ferrate(VI). The possibility of involvement of reactive ferrate(V) species for this enhancement was determined by studying the reactivity of ferrate(V) with NCO(-) in a homogeneous solution using a premix pulse radiolysis technique. The rate constant for the reaction of ferrate(V) and NCO(-) in alkaline medium was estimated to be (9.60+/-0.07) x 10(2) M(-1) s(-1), which is much slower than the ferrate(VI) self-decomposition reaction (k approximately 10(7) M(-1) s(-1)). An analysis of the kinetic data in the Fe(VI)-UV-TiO2-NCO(-) system suggests that ferrate(V) is not directly participating in the oxidation of cyanate. Possible reactions in the system are presented to explain results of ferrate(VI) reduction and oxidation of cyanate. 相似文献
382.
Orchestrating Ecosystem Management: Challenges and Lessons from Sequoia National Forest 总被引:2,自引:1,他引:1
Catherine M. Rigg 《Conservation biology》2001,15(1):78-90
Abstract: Numerous agencies and organizations have adopted the concept of ecosystem management as a guiding principle in natural resource management. Despite this widespread interest, no single definition of ecosystem management has been accepted, and there are no specific guidelines or standards by which to apply the concept. I examined how one federal agency, the U.S. Forest Service, is applying the principles of ecosystem management at a local level. I present a case study examining management of giant sequoia ( Sequoiadendron giganteum ) in Sequoia National Forest, California, to illuminate the challenges of practicing ecosystem management by associating on-the-ground management activities with ecosystem management themes, characteristics, and mechanisms identified in academic, industry, and agency literature. Experience at Sequoia National Forest suggests that the application of ecosystem management is compromised by poor relations between managers and stakeholders, multifarious policy requirements, budgetary uncertainty, and limited ecological research on which to base management decisions. To facilitate successful application of ecosystem management in the future, I recommend that managers (1) build confidence and trust in the process, (2) acknowledge bias, (3) reconcile policy and funding constraints with long-term planning, (4) invest in scientific research, data collection, and monitoring capacity, and (5) explore the relationship between values and science. These recommendations, although based on the U.S. Forest Service experience, are relevant to natural resource management in general. 相似文献
383.
Catherine Higgens 《生态毒理学报》2001,23(4):38-41
提出运输的环境影响,需要一个全方位的方法,例如为了促进旨在改变行为,技术和基础结构而相互支援的一体化行动,这样一种考虑系统的方方面面的方法.政府的关键作用(由加拿大运输部门的国家气候变化过程阐叙)是提供一种支持的框架结构. 相似文献
384.
Shaun A. Watmough Julian Aherne M. Catherine Eimers Peter J. Dillon 《Water, Air, & Soil Pollution: Focus》2007,7(1-3):301-306
In response to reduced sulphur emissions, there has been a large decrease in sulphate (; −0.97 μeq l−1 year−1) and hydrogen (−1.18 μeq l−1 year−1) ion concentration in bulk precipitation between 1980 and 2000 at Plastic Lake in central Ontario. The benefit of this large
reduction in deposition on stream water chemistry was assessed using the gauged outflow from a conifer-forested catchment (PC1; 23.3 ha),
which is influenced by a small wetland located immediately upstream of the outflow. Sulphate concentrations declined, but
not significantly due to large inter-annual variation in concentration. Between 1980 and 2000, there were significant increases in dissolved organic carbon, ammonium and potassium
concentration likely reflecting increased mineralisation in the wetland. Calcium concentrations in PC1 decreased during the
two decade period (−2.24 μeq l−1 year−1), as a consequence there was no improvement in stream pH and the Ca:Al ratio in PC1 continued to decline. A similar response
was noted in an upland-draining sub-catchment of PC1-08 that has been monitored since 1987. Despite large reductions in deposition and almost complete retention of nitrogen in soil, there has been no improvement (in terms of pH) in stream water
at PC1 due to a combination of soil acidification and climatic (droughts, increased mineralisation) perturbations. 相似文献
385.
Concern over impacts of atmospheric nitrogen deposition to ecosystems in Rocky Mountain National Park, Colorado, has prompted the National Park Service, the State of Colorado Department of Public Health and Environment, the Environmental Protection Agency, and interested stakeholders to collaborate in the Rocky Mountain National Park Initiative, a process to address these impacts. The development of a nitrogen critical load for park aquatic resources has provided the basis for a deposition goal to achieve resource protection, and parties to the Initiative are now discussing strategies to meet that goal by reducing air pollutant emissions that contribute to nitrogen deposition in the Park. Issues being considered include the types and locations of emissions to be reduced, the timeline for emission reductions, and the impact of emission reductions from programs already in place. These strategies may serve as templates for addressing ecosystem impacts from deposition in other national parks. 相似文献
386.
Investigation of the removal of heavy metals from sediments using rhamnolipid in a continuous flow configuration 总被引:2,自引:0,他引:2
Heavy metal contamination of sediments is hazardous to benthic organisms and needs more attention in order to prevent entry of these heavy metals into the food chain. Biosurfactants have shown the capability to remove heavy metals from soils and sediments. The objective of this research was to evaluate the performance of rhamnolipid, a glycolipid biosurfactant, in a continuous flow configuration (CFC) for removal of heavy metals (copper, zinc, and nickel) from the sediments taken from Lachine Canal, Canada, to simulate a flow through remediation technique. In this configuration, rhamnolipid solution with a constant rate was passed through the sediment sample within a column. Important parameters such as the concentration of rhamnolipid and the additives, time and the flow rate were investigated. The removal of heavy metals from sediments was up to 37% of Cu, 13% of Zn, and 27% of Ni when rhamnolipid without additives was applied. Adding 1% NaOH to 0.5% rhamnolipid improved the removal of copper by up to 4 times compared with 0.5% rhamnolipid alone. This information is valuable for designing a remediation protocol for sediment washing. 相似文献
387.
Eimers MC Watmough SA Buttle JM Dillon PJ 《Environmental monitoring and assessment》2007,127(1-3):399-407
Increased sulphate (SO4) export from wetlands following summer droughts in central Ontario, Canada has been associated with the delayed chemical
recovery of downstream surface waters following decreased sulphur (S) emissions. Prolonged summer droughts result in a decrease
or cessation of stream flow, declines in wetland water table level and oxidation of reduced S compounds to SO4, which is subsequently flushed into drainage streams when stream flow resumes. Sulphate input-output budget calculations
(1983–1995 and 1999–2001) at a conifer Sphagnum swamp in the Plastic Lake catchment, indicate that SO4 is retained in most years but is exported on a net basis following particularly severe summer droughts that result in the
cessation of stream flow for more than 54 days (95% CI: 41–72 days). Hindcast calculations using long-term (1916–2000) stream
discharge records from a nearby station indicate that while droughts occurred frequently in south-central Ontario over the
past 85 years, sufficiently dry conditions to cause net SO4 export occurred in only18 of the past 85 years, and indicate a cumulative positive SO4 balance for the swamp (i.e. net SO4 retention). Furthermore, the S pool at the Plastic Lake swamp has been estimated to be ∼1500 kg S/ha in the upper 40 cm peat
layer, which is large compared to the amount of net SO4 export that occurs even in years with particularly dry summers (e.g. −43 kg S/ha in 1987/88). Together, these data suggest
that the wetland S pool at Plastic Lake has not been depleted by previous droughts and will continue to sustain episodic drought-related
SO4 export for the foreseeable future. 相似文献
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