Freisetzung von Schwermetallen aus dem bodenbildenden Tonmineral Illit durch Aminosäuren

Kaolin W from Lohrheim (51% Illite, 31% Kaolinite, 18% Quarz, no Carbon) was loaded with various amounts of heavy metal ions (0.11–6.0 mmol/100g Cu, Ni, Cd) from their nitrate solutions. In the next step the release of the bound metals was tested with or without aminoacids (penicillamine and histidine) in solutions of weak acidity or alkalinity. It was found an evident influence of the aminoacids to the metal release in dependence of metalcoating, metal-aminoacid-ratio and experimental pH. Especially in alkali environment a multiplication of the copper release (to a factor of 39 (pen) or 27 (his)) was observed. An increased nickel (factor 53) and cadmium release (factor 4.5) was found with histidine. In this cases 80 to 100% of the heavy metals were removed from the clay-mineral-surface.     

Female sex pheromone in immature insect males—a case of pre-emergence chemical mimicry?

Sexual selection by competition for mates is a formidable force that has led to extraordinary adaptations in males. Here we present results suggesting a novel case of pheromone mimicry in males of Lariophagus distinguendus, a parasitic wasp of beetle larvae that develop in stored grain. Females of L. distinguendus produce a pheromone even before they emerge from a grain. Males are attracted to the parasitised grain and wait for females to emerge. Males emerging later than others are under enormous selection pressure since females mate only once. We show evidence that developing males fool their earlier emerging competitors by mimicking the female pheromone. Males exposed to pupae of either sex exhibit typical courtship behaviour. Searching males are not only arrested by grains containing developing females but spend as much time on grains containing developing males. Hence, by distracting their competitors away from receptive females late males may increase their own chance to mate with these females. After emergence, males decompose the active compounds within 32 h probably to decrease molestation during their own search for mates. Chemical analyses of active pheromone extracts and bioassays using fractions demonstrate that the active compounds are among the cuticular hydrocarbons.     

Choosing an appropriate soil-gas survey method

Three types of soil-gas surveys were performed over the same location at an industrial facility. The surveys performed were (1) a passive technique using buried collectors, (2) an active technique in which samples were collected in the field by pumping with subsequent analysis at a field laboratory, and (3) a screening technique that employed a hand-held survey instrument. Each of the surveys had desirable features, but there was considerable variability in the quality of data obtained, cost, and ease of performance. The passive and active surveys provided excellent detection limits, but the passive technique does not provide data in real time. The active survey was also time-consuming and required an analytical chemist in the field. Neither the active nor the passive survey were able to delineate the plume of contaminated groundwater. Consequently, the results from the rapid and inexpensive reconnaissance technique provided functionally equivalent data.Publication No. 3672, Environmental Sciences Division, ORNL.Operated by Martin Marietta Energy Systems, Inc. for the U.S. Department of Energy under Contract No. DE-AC05-840R21400.