Iron-impregnated zeolite catalyst for efficient removal of micropollutants at very low concentration from Meurthe river

In this paper, for the first time, faujasite Y zeolite impregnated with iron (III) was employed as a catalyst to remove a real cocktail of micropollutants inside real water samples from the Meurthe river by the means of the heterogeneous photo-Fenton process. The catalyst was prepared by the wet impregnation method using iron (III) nitrate nonahydrate as iron precursor. First, an optimization of the process parameters was conducted using phenol as model macro-pollutant. The hydrogen peroxide concentration, the light wavelength (UV and visible) and intensity, the iron loading immobilized, as well as the pH of the solution were investigated. Complete photo-Fenton degradation of the contaminant was achieved using faujasite containing 20 wt.% of iron, under UV light, and in the presence of 0.007 mol/L of H₂O₂ at pH 5.5. In a second step, the optimized process was used with real water samples from the Meurthe river. Twenty-one micropollutants (endocrine disruptors, pharmaceuticals, personal care products, and perfluorinated compounds) including 17 pharmaceutical compounds were specifically targeted, detected, and quantified. All the initial concentrations remained in the range of nanogram per liter (0.8–88 ng/L). The majority of the micropollutants had a large affinity for the surface of the iron-impregnated faujasite. Our results emphasized the very good efficiency of the photo-Fenton process with a cocktail of a minimum of 21 micropollutants. Except for sulfamethoxazole and PFOA, the concentrations of all the other microcontaminants (bisphenol A, carbamazepine, carbamazepine-10,11-epoxide, clarithromycin, diclofenac, estrone, ibuprofen, ketoprofen, lidocaine, naproxen, PFOS, triclosan, etc.) became lower than the limit of quantification of the LC-MS/MS after 30 min or 6 h of photo-Fenton treatment depending on their initial concentrations. The photo-Fenton degradation of PFOA can be neglected. The photo-Fenton degradation of sulfamethoxazole obeys first-order kinetics in the presence of the cocktail of the other micropollutants.     

The Establishment of Marine Protected Areas in Senegal: Untangling the Interactions Between International Institutions and National Actors

International institutions, understood as sets of rules contained in international agreements, are aimed at orienting national governments towards specific policy options. Nevertheless, they can determine a change in national policies and practices only if states are willing and capable of incorporating international obligations into their national legislations and ensuring their application and enforcement in areas that follow completely under national jurisdiction. The establishment of marine protected areas promoted by international agreements as a tool for the protection of marine resources represents an interesting case for revealing the complex interactions between international institutions and national actors. Particularly, the establishment of these areas in Senegal shows the salience of domestic constellations of actors who may support or undercut national commitments to international regimes: political elites, bureaucracies, the general public and target groups. By anchoring the empirical analysis to an actor-centred institutionalist perspective, the article explains how dynamic constellations of actors can distort the penetration of international objectives in the national policy framework. Different constellations of national actors can indeed bend international institutions at different moments: during the formulation of a new law in line with international obligations; in the definition of its implementation framework; and in the enforcement of national policies.     

Atlantic storminess and historical sand drift in Western Europe: implications for future management of coastal dunes

Historical records of sand drift and dune-building along the coastline of Western Europe provide insights into the natural processes of sand dune accretion and both the impacts of, and human responses to, sand incursions. The analysis of documentary records, instrumental data and proxy records over the last 1,000 years indicates that this period, which included the Little Ice Age (AD 1570–1900), featured numerous episodes of sand drift and dune development driven by strong winds associated with Atlantic storms. It is estimated that sand drift affected over a quarter of a million hectares of coastal land in Western Europe. The widespread use of vegetation to stabilise coastal dune systems and prevent sand drift is documented across Europe from AD 1100 and by the start of the 20th century all of the larger coastal dune systems in Portugal, France, Britain and Denmark were comparatively inactive. Given that Atlantic storminess has remained more or less unchanged over the last 200 years, modern dune management strategies which consider dune devegetation, driven by an increasing focus on ‘naturalness’, may give rise to a recurrence of sand drift problems. Predictions of increased storm frequencies by the end of the 21st century, coupled with sea level rise and potential changes in sand supply will present further challenges for the more ‘dynamic’ dune management strategies.     

Net negative growth detected in a population of <Emphasis Type="Italic">Leptogorgia sarmentosa</Emphasis>: quantifying the biomass loss in a benthic soft bottom-gravel gorgonian

Gorgonian species may contribute to the three-dimensional seascape in soft bottom-gravel areas, but the information on their biology and ecology is very scarce. The biometry and secondary production of the Mediterranean soft bottom-gravel passive suspension feeder Leptogorgia sarmentosa (Cnidaria: Octocorallia) was studied using photographic monitoring of the primary branches from May 1998 to September 2000. The primary branches observed had a high density of polyps (2.2 ± 0.2 SD polyps mm⁻¹) and a high organic matter content (63.2 ± 9.1 SD %). During the two-year sampling period, there was a net negative growth in 90% of the gorgonian population. The mean loss during the 27-month period was −2.9 ± 0.9 SD cm per branch (5.7 mg C branch⁻¹). However, considering only the initial and final diameters and maximum height in the 27 months elapsed time, the gorgonians showed positive growth, which meant that photographic sampling of single branches was a more appropriate method for gorgonian secondary production monitoring. A water mass anomaly detected in 1999 in the north-western Mediterranean Sea may have been the cause of the net negative growth in L. sarmentosa in the studied area. Partial mortality due to different factors, such as strong currents, predation, disease, etc., could be a common strategy in sessile colonial benthic populations that would facilitate their maintenance even during very stressful circumstances.     

Production of plant growth–promoting bacteria inoculants from composting leachate to develop durable agricultural ecosystems

Environmental Science and Pollution Research - Composting process of residual organic material generates considerable amounts of liquid leachate which contains high organic load. This waste stream...     

An in vitro bioassay to assess the potential global toxicity of waters on spermatogenesis: a pilot study

Environmental Science and Pollution Research - Many toxicants are present in water as a mixture. Male infertility is one of the environmental impacts in developed countries. Using our rat...     

Decision process in large-scale crisis management

This paper deals with the decision-aiding process in large-scale crisis such as natural disasters. It consists in four phases: decision context characterisation, system modelling, aggregation and integration. The elements of the context, such as crisis level, risk situation, decision-makers, problem issue are defined through the characterisation phase. At the feared event occurrence, these elements will interact on a target system. Through the model on this system, the consequences to stakes could be assessed or estimated. The presented aggregation approaches will allow taking the right decisions. The architecture of a Decision Support System is presented in the integration phase.     

Slip Resistance of Industrial Floor Surfaces: Development of an Elastomer Suited to In-Situ Measurement

Slips contribute to 12% of occupational accidents. A slip resistant floor is a mean to prevent slipping accidents occurring in workshops. Floor slip resistance is often evaluated by measuring a friction index, proportional to the force opposing slipping of a reference elastomer on the floor surface under test. When implementing a portable appliance, slip resistance measurements carried out on lubricated floors were not stabilized. The authors advanced the hypothesis of oil impregnating the elastomer. A new elastomer suited to in-situ measurement has been developed to achieve stable measuring conditions. This study highlights the fact that the nature and characteristics of a reference elastomer must be specified when slip resistance measurements are carried out.