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581.
Federico M. San Martini J. Jason West Benjamin de Foy Luisa T. Molina Mario J. Molina Gustavo Sosa 《Journal of the Air & Waste Management Association (1995)》2013,63(6):803-815
Abstract Based on data from the 1997 Investigación sobre Materia Particulada y Deterioro Atmosférico-Aerosol and Visibility Evaluation Research (IMADA-EVER) campaign and the inorganic aerosol model ISORROPIA, the response of inorganic aerosols to changes in precursor concentrations was calculated. The aerosol behavior is dominated by the abundance of ammonia and thus, changes in ammonia concentration are expected to have a small effect on particle concentrations. Changes in sulfate and nitrate are expected to lead to proportional reductions in inorganic fine particulate matter (PM2.5). Comparing the predictions of ISORROPIA with the observations, the lowest bias and error are achieved when the aerosols are assumed to be in the efflorescence branch. Including crustal species reduces the bias and error for nitrate but does not improve overall model performance. The estimated response of inorganic PM2.5 to changes in precursor concentrations is affected by the inclusion of crustal species in some cases, although average responses are comparable with and without crustal species. Observed concentrations of particle chloride suggest that gas phase concentrations of hydrogen chloride may not be negligible, and future measurement campaigns should include observations to test this hypothesis. Our ability to model aerosol behavior in Mexico City and, thus, design control strategies, is constrained primarily by a lack of observations of gas phase precursors. Future campaigns should focus in particular on better understanding the temporal and spatial distribution of ammonia concentrations. In addition, gas phase observations of nitric acid are needed, and a measure of particle water content will allow stable versus metastable aerosol behavior to be distinguished. 相似文献
582.
An existing model of radiocaesium transfer to grasses was extended to include wheat and barley and parameterised using data from a wide range of soils and contact times. The model structure was revised and evaluated using a subset of the available data which was not used for model parameterisation. The resulting model was then used as a basis for systematic model reduction to test the utility of the model components. This analysis suggested that the use of 4 model variables (relating to radiocaesium adsorption on organic matter and the pH sensitivity of soil solution potassium concentration) and 1 model input (pH) are not required. The results of this analysis were used to develop a reduced model which was further evaluated in terms of comparisons to observations. The reduced model had an improved empirical performance and fewer adjustable parameters and soil characteristic inputs. 相似文献
583.
This study was conducted to identify the principle selenate carrier phases for two selected soils, by comparing their reactivity with selenate to that of pure phases of the solids. Silica, calcium carbonate, aluminium hydroxide, goethite, bentonite and humic acid were selected as the main soil carrier phases. Comparisons were made first on the parameter values obtained with the best fit of a kinetic sorption model which can discriminate instantaneous sorption from kinetically limited sorption. Then comparisons were made of the ability for each solid to stabilise selenate by measuring the ratio of the partition coefficient for sorption (Kdsorption) over that of the desorption (Kddesorption). Kinetics and stabilisation were used to help elucidate the nature of interactions with the test solid phases for a large range of selenate concentrations. The experiments were conducted over 165 h in batch reactors, the solid being isolated from the solution by dialysis tubing, at two pH (5.4 and 8) and three selenate concentrations (1 × 10−3, 1 × 10−6 and 1 × 10−8 mol L−1). The results obtained showed that only aluminium hydroxide can sorb selenate throughout the studied pH range (pH 5.4 to 8.0). The sorption capacity on this mineral was high (Kdsorption > 100 to 1 × 104 L kg−1) and the selenate was mainly stabilized by the formation of inner sphere complexes. The sorption on goethite occurred at pH 5.4 (Kdsorption 52 L kg−1), mainly as outer sphere complexes, and was null at pH 8. On silica, a weak sorption was observed only at pH 5.4 and at 165 h (Kdsorption 4 L kg−1). On bentonite, calcium carbonate and humic acid no significant sorption was observed. Concerning the two soils studied, different behaviours were observed for selenate. For soil Ro (pH 5.4), Kdsorption was low (8 L kg−1) compared to soil Bu (pH 8) (70 L kg−1). The sorption behaviour of selenate on soil Ro was mainly due to outer sphere complexes, as for goethite, whereas for soil Bu the sorption was mainly attributed to inner sphere complexes followed by reduction mechanisms, probably initiated by microorganisms, in which no steady state was reached at the end of the 165 h experiments. The sorption of selenate decreased when concentrations reached 1 × 10−3 mol L−1, due to solid saturation, except for aluminium hydroxide. Reduction of selenate seemed also to occur on goethite and soil Ro, for the same concentration, but without preventing a decrease in sorption. Thus, this work shows that the comparison of selenate behaviour between soil and pure phases helps to elucidate the main carrier phases and sorption mechanisms in soil. 相似文献
584.
Kurnaz A Kucukomeroglu B Damla N Cevik U 《Journal of environmental radioactivity》2011,102(4):393-399
The activity concentrations and absorbed gamma dose rates due to primordial radionuclides and 137Cs have been ascertained in 222 soil samples in 18 counties of the Trabzon province of Turkey using a HPGe detector. The mean activity concentrations of 238U, 232Th, 40K and 137Cs in soil samples were 41, 35, 437 and 21 Bq kg−1, respectively. Based on the measured concentrations of these radionuclides, the mean absorbed gamma dose in air was calculated as 59 nGy h−1 and hence, the mean annual effective dose due to terrestrial gamma radiation was calculated as 72 μSv y−1. In addition, outdoor in situ gamma dose rate (D) measurements were performed in the same 222 locations using a portable NaI detector and the annual effective dose was calculated to be 66 μSv y−1 from these results. The results presented in this study are compared with other parts of Turkey. Radiological maps of the Trabzon province were composed using the results obtained from the study. 相似文献
585.
Alexandrova M Rozhko T Vydryakova G Kudryasheva N 《Journal of environmental radioactivity》2011,102(4):407-411
The effect of americium-241 (241Am), an alpha-emitting radionuclide of high specific activity, on luminous bacteria Photobacterium phosphoreum was studied. Traces of 241Am in nutrient media (0.16-6.67 kBq/L) suppressed the growth of bacteria, but enhanced luminescence intensity and quantum yield at room temperature. Lower temperature (4 °C) increased the time of bacterial luminescence and revealed a stage of bioluminescence inhibition after 150 h of bioluminescence registration start. The role of conditions of exposure the bacterial cells to the 241Am is discussed. The effect of 241Am on luminous bacteria was attributed to peroxide compounds generated in water solutions as secondary products of radioactive decay. Increase of peroxide concentration in 241Am solutions was demonstrated; and the similarity of 241Am and hydrogen peroxide effects on bacterial luminescence was revealed. The study provides a scientific basis for elaboration of bioluminescence-based assay to monitor radiotoxicity of alpha-emitting radionuclides in aquatic solutions. 相似文献
586.
The states of the populations of five dominant species of predatory mammals living in the area affected by the Kalinin Nuclear
Power Plant (NPP) and in remote districts of Tver’ oblast have been compared. A total of 1120 skulls, including 708 skulls
from the vicinity of the NPP, have been examined. The data on parameters characterizing similarities between the samples,
the degree and structure of intrapopulation diversity, and ontogenetic stability suggest with a high probability that the
Kalinin NPP has no effect on wild populations of predatory mammals. 相似文献
587.
The results of studies on the radial increment of larch and pine in central Yakutia are presented. The application of dendroclimatological
methods to the study of tree-ring chronologies has made it possible to evaluate tree growth response to the dynamics of climatic
factors over the past 120 years. The results of analysis of radial tree increment show that the onset of the growing season
has shifted to earlier dates by the end of the 20th century. 相似文献
588.
Matilda Palm Madelene Ostwald Indu K. Murthy Rajiv K. Chaturvedi N. H. Ravindranath 《Regional Environmental Change》2011,11(2):423-435
This paper analyses environmental and socio-economic barriers for plantation activities on local and regional level and investigates
the potential for carbon finance to stimulate the increased rates of forest plantation on wasteland, i.e., degraded lands,
in southern India. Building on multidisciplinary field work and results from the model GCOMAP, the aim is to (1) identify
and characterize the barriers to plantation activities in four agro-ecological zones in the state of Karnataka and (2) investigate
what would be required to overcome these barriers and enhance the plantation rate and productivity. The results show that
a rehabilitation of the wasteland based on plantation activities is not only possible but also anticipated by the local population
and would lead to positive environmental and socio-economic effects at a local level. However, in many cases, the establishment
of plantation activities is hindered by a lack of financial resources, low land productivity and water scarcity. Based on
the model used and the results from the field work, it can be concluded that certified emission reductions such as carbon
credits or other compensatory systems may help to overcome the financial barrier; however, the price needs to be significantly
increased if these measures are to have any large-scale impact. 相似文献
589.
P. Valkering R. van der Brugge A. Offermans N. Rijkens-Klomp 《Regional Environmental Change》2011,11(2):229-241
Climate adaptation is a complex task surrounded by uncertainty. To support climate adaptation policies, a new scenario approach
is pursued to explore possible discontinuous future developments of societal perspectives on climate adaptation issues. The
scenario approach was tested for a case study on Dutch river management. In a series of scenario development workshops, a
select group of stakeholders explored the perspectives on the management of the River Meuse in the past, present, and future.
The process was supported by an analytical perspectives mapping tool to illustrate and analyze the development of perspectives
over time. The process and analytical tools contributed to insight into the drivers of perspective change for the case study
at hand. Moreover, the stakeholders highlighted the potential of the approach for water management policy for creating awareness
about the plurality of perspectives and the dynamics of perspective change, monitoring perspectives and perspective change
as part of a flexible policy approach, and anticipating on the occurrence of shock events. Further work is required to better
represent the social dynamics of perspectives change, to better empirically ground the perspective change model, and to apply
integrated water models in the scenario development process to assess water–society interactions. 相似文献
590.
Long-term (1860–2010) catchment mass balance calculations rely on models and assumptions which are sources of uncertainty
in acidification assessments. In this article, we report on an application of MAGIC to model acidification at the four Swedish
IM forested catchments that have been subject to differing degrees of acidification stress. Uncertainties in the modeled mass
balances were mainly associated with the deposition scenario and assumptions about sulfate adsorption and soil mass. Estimated
base cation (BC) release rates (weathering) varied in a relatively narrow range of 47–62 or 42–47 meq m−2 year−1, depending on assumptions made about soil cation exchange capacity and base saturation. By varying aluminum solubility or
introducing a dynamic weathering feedback that allowed BC release to increase at more acidic pHs, a systematic effect on predicted
changes in acid neutralizing capacity (ΔANC ca. 10–41 μeq l−1) and pH (ca. ΔpH = 0.1–0.6) at all sites was observed. More robust projections of future changes in pH and ANC are dependent
on reducing uncertainties in BC release rates, the timing, and extent of natural acidification through BC uptake by plants,
temporal changes in soil element pools, and fluxes of Al between compartments. 相似文献