Cysteine as a green corrosion inhibitor for Cu37Zn brass in neutral and weakly alkaline sulphate solutions

The aim of this study was to investigate electrochemical properties of brass in neutral and weakly alkaline solutions in the presence of cysteine as a nontoxic and ecological corrosion inhibitor. Potentiodynamic measurements, open circuit potential measurements, as well as chronoamperometric measurements were the methods used during investigation of the inhibitory effect of cysteine on the corrosion behaviour of brass. Potentiodynamic measurements showed that cysteine behaves as a mixed-type inhibitor in the investigated media. Based on polarization curves for brass in a weakly alkaline solution of sodium sulphate at varying cysteine concentrations, an interaction occurs between Cu⁺ ions and the inhibitor, resulting in the formation of a protective complex on the electrode surface. The results of chronoamperometric measurements confirm the results obtained by potentiodynamic measurements. Optical microphotography of the brass surface also confirms the formation of a protective film in the presence of a 1?×?10^?4 mol/dm³ cysteine. Adsorption of cysteine on the brass surface proceeds according to the Langmuir adsorption isotherm.     

Assessing ecological risk on a regional scale

Society needs a quantitative and systematic way to estimate and compare the impacts of environmental problems that affect large geographic areas. This paper presents an approach for regional risk assessment that combines regional assessment methods and landscape ecology theory with an existing framework for ecological risk assessment. Risk assessment evaluates the effects of an environmental change on a valued natural resource and interprets the significance of those effects in light of the uncertainties identified in each component of the assessment process. Unique and important issues for regional risk assessment are emphasized; these include the definition of the disturbance scenario, the assessment boundary definition, and the spatial heterogeneity of the landscape. Although the research described in this article has been funded wholly or in part by the United States Environmental Protection Agency (EPA) through Interagency Agreement Number DW89932112-01-2 to the U.S. Department of Energy, it has not been subjected to EPA review and therefore does not necessarily reflect the views of EPA and no official endorsement should be inferred.     

Analysis of high-level waste glass performance by the physical and geochemical simulation code STRAG4

A source term release analysis code for high-level waste glass has been developed for simulation of long-term dissolution behavior under repository conditions. The STRAG4 code consists of models for (a) element diffusion in both the bulk glass and surface layer, (b) glass dissolution kinetics at the interface between glass and water, and (c) geochemical reactions of dissolved elements in underground water. The simulations for various conditions of glass dissolution, including a static and dynamic system, show accordance with the experimental observations even in the relatively complicated case where bentonite is present. Long-term dissolution analyses of a borosilicate waste glass were carried out as preliminary study. The calculations were achieved by considering detrimental effects due to interactions between the glass and surrounded materials which are presumed to be in a repository environment (i.e., compacted bentonite, corrosion products from the iron overpack, and underground water). The environmental conditions such as temperature and geochemical reactions are also taken into account in the calculations. The results suggest the life of the waste glass would be more than 50,000 years even if the glass surface area increased by a factor of 10 due to crack formation.     

Vacuum pyrolysis process for remediation of hydrocarbon-contaminated soils

A vacuum pyrolysis process was used for the remediation of hydrocarbon–contaminated soils from “Les Vidangeurs de Montréal” site in Mascouche in the province of Québec, near Montréal. Ten samples were tested on a laboratory scale batch reactor, and one sample was tested on a prototype process development unit. The process is simple, efficient, reliable, and economically competitive with other existing technologies. The vacuum pyrolysis process efficiently treated soils contaminated with a variety of pollution levels and types, irrespective of the soil matrix, providing treated soils meeting the A criterion (noncontaminated, residential level) of the Ministry of Environment Québec (MENVIQ). The pyrolytic oil and the noncondensable pyrolytic gases can be used as makeup fuel in the process, because they have a high calorific value and their combustion should not pose any emission problems. The waterphase effluent must be treated before discharge.     

Recommended Methods for the Disposal of Sanitary Wastes from Temporary Field Medical Facilities

Emergency field medical facilities constructed after a disaster are frequently managed by medical staff even though many of the day-to-day problems of hospital management are unrelated to medicine. In this paper we discuss the short-term management of one of these problems, namely the control and disposal of sanitary wastes. It is aimed at persons in the medical profession who may find themselves responsible for a temporary hospital and have little or no previous experience of managing such situations. The wastes commonly generated are excreta, sullage and refuse. In addition, surface water must also be considered because its inadequate disposal is a potential health hazard. The paper concentrates on short-term measures appropriate for the first six months of the hospital or clinic's existence. Facilities expected to last longer are recommended to install conventional waste management systems appropriate to the local community and conditions. In most situations, wastes should be disposed of underground either by burial (for solids) or infiltration (for liquids). The design, construction and management of appropriate disposal systems are described.     

The carajas iron ore project: The strategy of a third world state- owned enterprise in a depressed market

This paper describes how the Carajas iron ore project was set up in February 1985 at a time of deep recession in the iron ore and steel industries. Development of the project was met with much criticism, mainly from North American steel makers, who argued that the project would only be successful through the support of a Third World government, highly dependent on foreign exchange, without any consideration being given to its economic feasibility or to the fundamentals of the market. The authors explain why the World Bank took the step of setting up the project and how its development can be partly explained by the interests of the Japanese and European steel makers. The role of the Brazilian government is explained and the authors conclude that the relatively low rate of investment anticipated by the project will be overshadowed by the high gains in foreign exchange.     

EFFECTIVENESS OF DROUGHT POLICIES FOR MUNICIPAL WATER MANAGEMENT1

During the 1976–77 drought, three principal mechanisms were used to reduce water use in Utah communities: price increases, maximum monthly use restrictions, and restrictions on outdoor watering times. A regression model was developed to explain observed changes in water use, with price, type of restriction, household size, and summer rainfall as independent variables. For an average system, a 1 percent increase in price would reduce water use by 0.07 to 0.09 percent. A 1 percent increase in outdoor watering time restriction reduces use by 0.064 to 0.075 percent. A 1 percent increase in quantity restrictions leads to a reduction in water use of 0.014 to 0.054 percent. The effectiveness of rationing policies is influenced by system characteristics. For example, outdoor watering time restrictions were less effective in systems with above average household size and below average monthly use.     

Determining regional water quality patterns and their ecological relationships

A multivariate statistical method for analyzing spatial patterns of water quality in Georgia and Kansas was tested using data in the US Environmental Protection Agency's STORET data system. Water quality data for Georgia and Kansas were organized by watersheds. We evaluated three questions: (a) can distinctive regional water quality patterns be detected and predicted using only a few water quality variables, (b) are regional water quality patterns correlated with terrestrial biotic regions, and (c) are regional water quality patterns correlated with fish distributions? Using existing data, this method can distinguish regions with water quality very different from the average conditions (as in Georgia), but it does not discriminate well between regions that do not have diverse water quality conditions (as in Kansas). Data that are spatially and temporally adequate for representing large regions and for multivariate statistical analysis are available for only a few common water quality parameters. Regional climate, lithology, and biotic regimes all have the potential to affect water quality, and terrestrial biotic regions and fish distributions do compare with regional water quality patterns, especially in a state like Georgia, where watershed characteristics are diverse. Thus, identifiable relationships between watershed characteristics and water quality should allow the development of an integrated landaquatic classification system that would be a valuable tool for resource management. Because geographical distributions of species may be limited by Zoogeographic and environmental factors, the recognition of patterns in fish distributions that correlate with regional water quality patterns could influence management strategies and aid regional assessments.     

Operating Experience with Biogas Plants in Sri Lanka

Three hundred and three biogas plants, representing a majority of the units installed in Sri Lanka up to 1984, were inspected, and it was found that 280 of these had been put into commission at some time prior to the study. Of the 280 commissioned plants, 170 (61%) were functioning satisfactorily providing biogas for cooking and/or lighting. The remaining 110 (39%) were either not functioning or were supplying very little gas owing to gas leaks, inadequate input of dung, or poor plant management. The most common plant was the 6 m³, fixed dome, household plant, and the most common raw material used was cattle dung. In the majority of household plants the cost of construction was partly or wholly subsidized.     

APPROACHES TO WATER RESOURCE POLICY AND PLANNING IN TEXAS1

ABSTRACT: Texas is one of the states in which limitations in water supplies could severely constrain economic growth in certain areas. The traditional planning approach for addressing this problem has involved devising schemes for large water development projects, which for many years included the importation of water from other states. Now the attitude towards water resource management is changing, and it is generally agreed that better management of existing supplies is the preferred approach. In this paper we review some of the changes that have recently occurred in Texas, including attempts to streamline the water institutions in such a way that they might be more responsive to the need for more comprehensive management of water resources statewide, with greater emphasis on social and environmental concerns.