Nitrogen removal from landfill leachate via ex situ nitrification and sequential in situ denitrification

Ex situ nitrification and sequential in situ denitrification represents a novel approach to nitrogen management at landfills. Simultaneous ammonia and organics removal was achieved in a continuous stirred tank reactor (CSTR). The results showed that the maximum nitrogen loading rate (NLR) and the maximum organic loading rate (OLR) was 0.65 g N l^?1 d^?1 and 3.84 g COD l^?1 d^?1, respectively. The ammonia and chemical oxygen demand (COD) removal was over 99% and 57%, respectively. In the run of the CSTR, free ammonia (FA) inhibition and low dissolved oxygen (DO) were found to be key factors affecting nitrite accumulation. In situ denitrification was studied in a municipal solid waste (MSW) column by recalculating nitrified leachate from CSTR. The decomposition of MSW was accelerated by the recirculation of nitrified leachate. Complete reduction of total oxidized nitrogen (TON) was obtained with maximum TON loading of 28.6 g N t^?1 TS d^?1 and denitrification was the main reaction responsible. Additionally, methanogenesis inhibition was observed while TON loading was over 11.4 g N t^?1 TS d^?1 and the inhibition was enhanced with the increase of TON loading.     

含砷废水净化剂的制备及其应用研究

本文描述了用黄铁矿和还原铁粉或其代用品为原料制备含砷废水净化剂－硫化亚铁的新方法，获得了制备的最佳条件，探讨了其在含砷废水处理中的应用条件和影响因素，结果表明，该净化剂的生产及其处理含砷废水的工艺简单，经济高效，具有良好的开发应用前景。     

存在截渗墙情况下地下咸水恢复的优化方案

本文首先分析了咸水分布区的自然地理和水文地质条件，然后对研究区的水文地质条件进行了概化，建立了相应的地下水水量和水质的数值模型，最后通过地下水模拟软件Visual—MODFLOW3.1对存在截渗墙情况下的不同咸水恢复方案进行了数值分析。研究结果表明。单纯的抽水方案对于高浓度咸水的去除非常有效，但是低浓度咸水残留量较大；抽水——注水方案对高低浓度的去除效果都比较好；而抽水优化方案对高浓度和低浓度的咸水的去除更加经济、快速和彻底。     

Deriving fuel-based emission factor thresholds to interpret heavy-duty vehicle roadside plume measurements

Remote sensing devices have been used for decades to measure gaseous emissions from individual vehicles at the roadside. Systems have also been developed that entrain diluted exhaust and can also measure particulate matter (PM) emissions. In 2015, the California Air Resources Board (CARB) reported that 8% of in-field diesel particulate filters (DPF) on heavy-duty (HD) vehicles were malfunctioning and emitted about 70% of total diesel PM emissions from the DPF-equipped fleet. A new high-emitter problem in the heavy-duty vehicle fleet had emerged. Roadside exhaust plume measurements reflect a snapshot of real-world operation, typically lasting several seconds. In order to relate roadside plume measurements to laboratory emission tests, we analyzed carbon dioxide (CO₂), oxides of nitrogen (NO_X), and PM emissions collected from four HD vehicles during several driving cycles on a chassis dynamometer. We examined the fuel-based emission factors corresponding to possible exceedances of emission standards as a function of vehicle power. Our analysis suggests that a typical HD vehicle will exceed the model year (MY) 2010 emission standards (of 0.2 g NO_X/bhp-hr and 0.01 g PM/bhp-hr) by three times when fuel-based emission factors are 9.3 g NO_X/kg fuel and 0.11 g PM/kg using the roadside plume measurement approach. Reported limits correspond to 99% confidence levels, which were calculated using the detection uncertainty of emissions analyzers, accuracy of vehicle power calculations, and actual emissions variability of fixed operational parameters. The PM threshold was determined for acceleration events between 0.47 and 1.4 mph/sec only, and the NO_X threshold was derived from measurements where after-treatment temperature was above 200°C. Anticipating a growing interest in real-world driving emissions, widespread implementation of roadside exhaust plume measurements as a compliment to in-use vehicle programs may benefit from expanding this analysis to a larger sample of in-use HD vehicles.

Implications: Regulatory agencies, civil society, and the public at large have a growing interest in vehicle emission compliance in the real world. Leveraging roadside plume measurements to identify vehicles with malfunctioning emission control systems is emerging as a viable new and useful method to assess in-use performance. This work proposes fuel-based emission factor thresholds for PM and NOx that signify exceedances of emission standards on a work-specific basis by analyzing real-time emissions in the laboratory. These thresholds could be used to prescreen vehicles before roadside enforcement inspection or other inquiry, enhance and further develop emission inventories, and potentially develop new requirements for heavy-duty inspection and maintenance (I/M) programs, including but not limited to identifying vehicles for further testing.     

黑河流域土地退化分类研究

黑河流域位于我国的西北内陆干旱区。人类不合理利用水资源造成的土地退化，已成为黑河流域一个非常严重的生态问题。土地荒漠化是该流域最典型和最严重的土地退化形式。对该流域土地退化的空间分布、特点、退化面积等方面还没有较为详细的研究，因此探讨这个问题就显得非常重要。文章通过最新的遥感影像资料(2000年)，在分析已有的研究成果的基础上，结合野外调查，利用遥感和地理信息系统(GIS)技术，初步分析了黑河流域土地退化的情况。研究结果表明，黑河流域土地退化主要有5种类型，即：水土流失、干旱化、植被退化、盐渍化和沙漠化。土地退化面积达29971．91km^2，占整个流域面积的23．06％；其中，水土流失主要分布在祁连山的南部山区，面积为5747．68km^2，占整个流域土地退化面积的19．18％，主要是由于过度开垦和放牧造成的；由于人类活动的影响，造成水资源在时空上的重新分配而导致的干旱化土地主要分布在山前部分冲、洪积平原的河流沿岸附近，其面积为1369.96km^2，占整个流域土地退化面积的4．57％；盐渍化土地是该流域土地退化的主要类型之一，面积为10591．82km^2，占整个流域土地退化面积的35．34％，分布在流域的低地、冲积扇的边缘等位置，主要是由于干旱的气候条件造成的；沙化土地，包括流动沙丘(地)，是研究区土地退化面积最大的类型，为10771．97km^2，占整个流域土地退化面积的35.94％，这其中也包括历史时期形成的沙漠和现代形成的大部分沙地；植被退化土地面积为1490．48km^2，只占整个流域土地退化面积的4．97％。通过分析可知，黑河流域土地退化严重，特别是在下游地区。人类不合理的经济活动，尤其是对该流域内有限水资源的不合理利用，是导致该地区土地生态系统脆弱的主要因素。     

煤与瓦斯突出的物理模拟和数值模拟研究

利用自行设计的实验装置,通过现场采集具有突出倾向的煤样,分别向实验装置煤样中充入吸附能力较大的CO2和吸附能力较小的N2来模拟不同级别的煤与瓦斯突出现象,物理试验结果表明:瓦斯压力越大,突出强度越大;当瓦斯压力相近时,吸附和解吸能力大的瓦斯突出强度大。通过数值模拟对煤与瓦斯突出进行研究,数值模拟再现了煤矿开采过程中诱发的煤与瓦斯突出全过程,同时验证了煤与瓦斯突出是瓦斯压力、地应力及煤岩体的力学性质综合作用的结果,该验证对进一步深入理解认识煤与瓦斯突出的机理具有重要的理论和实践意义。     

中小企业化学品职业危害预防控制指南

为了帮助中小企业控制预防控制化学品职业危害,本文详细介绍了国际劳工组织所推行的中小企业化学品职业危害控制指南,包括化学职业卫生管理的主要内容和基本步骤,关键点危险区的确定方法,改进化学品职业危害管理、实施化学品管理的良好规范、制定化学品管理行动计划和编制全面的化学品清单等方法,以达到系统提高化学品管理水平和持续改进的目标和要求.     

高危职业危害监测内涵及预警系统探讨

我国目前职业病危害形势严峻,职业卫生管理和服务模式不能适应社会发展的需求,优先管理高危职业危害,建立高危职业危害监测预警系统是控制和减少重大职业危害事故的关键.通过职业危害监测、风险评估、风险分级和预警等术语阐述高危职业危害监测的内涵,并探讨建立利用现有技术平台、重点监控、多部门合作、多层次的纵向多维监测预警系统.     

兰西城市群县域土地利用效率时空差异研究

在考虑绿色发展内涵的基础上,运用SBM-Undesirable模型测度了2006—2018年兰西城市群县域土地利用效率值,并采用泰尔指数、空间自相关方法揭示其时空差异特征。结果表明:①2006—2018年兰西城市群县域土地利用效率稳步提升,区域差异先扩大后缩小。②兰西城市群县域土地利用效率呈现“中部高—外围低、西高东低、南北分异”的空间差异规律,两省域呈现“西—东”的递减规律。③兰西城市群县域土地利用效率空间集聚特征显著,局部范畴上高—高集聚区在中部地区较为典型,低—低集聚区出现由东南向西南的扩散现象。