Impacts of Biodiesel on Pollutant Emissions of a JP-8–Fueled Turbine Engine

Abstract

The impacts of biodiesel on gaseous and particulate matter (PM) emissions of a JP-8–fueled T63 engine were investigated. Jet fuel was blended with the soybean oil-derived methyl ester biofuel at various concentrations and combusted in the turbine engine. The engine was operated at three power settings, namely ground idle, cruise, and takeoff power, to study the impact of the biodiesel at significantly different pressure and temperature conditions. Particulate emissions were characterized by measuring the particle number density (PND; particulate concentration), the particle size distribution, and the total particulate mass. PM samples were collected for off-line analysis to obtain information about the effect of the biodiesel on the polycyclic aromatic hydrocarbon (PAH) content. In addition, temperature-programmed oxidation was performed on the collected soot samples to obtain information about the carbonaceous content (elemental or organic). Major and minor gaseous emissions were quantified using a total hydrocarbon analyzer, an oxygen analyzer, and a Fourier Transform IR analyzer. Test results showed the potential of biodiesel to reduce soot emissions in the jet-fueled turbine engine without negatively impacting the engine performance. These reductions, however, were observed only at the higher power settings with relatively high concentrations of biodiesel. Specifically, reductions of ～15% in the PND were observed at cruise and takeoff conditions with 20% biodiesel in the jet fuel. At the idle condition, slight increases in PND were observed; however, evidence shows this increase to be the result of condensed uncombusted biodiesel. Most of the gaseous emissions were unaffected under all of the conditions. The biodiesel was observed to have minimal effect on the formation of polycyclic aromatic hydrocarbons during this study. In addition to the combustion results, discussion of the physical and chemical characteristics of the blended fuels obtained using standard American Society for Testing and Materials (ASTM) fuel specifications methods are presented.     

Procedures in Sampling and Handling Auto Exhaust

Both the composition and discharge rate of auto exhausts vary widely and rapidly as speed and load demands upon the engine are changed. Moreover, among the combustion products are compounds that are highly reactive under proper conditions and others that are readily bound by receptive surfaces or absorbents. Under these conditions both the sampling procedure and subsequent sample handling must be such that (1) the sample that is recovered contains all or a fixed proportion of each incremental volume of the total to be represented and (2) the products so sampled are not allowed either to react with each other or to be lost or diminished in sample storage or transfer. Experimental research and development relevant to each requirement have been carried out, and results are reported and discussed. Two methods have been used for recovering sample-volume samples representative of the total volume produced during any combination of steady or transient engine modes. One employs a servo-followup system appropriately coupled to both the engine air-intake and to the sampling element; the sampling rate is continuously controlled to bear at all times a fixed ratio to the engine air-intake rate. The second method employs variable dilution, involving addition of diluent gas necessary to maintain a constant total of [exhaust + diluent]. If the mixture is sampled at a constant rate, the sample will contain exhaust appropriately proportioned. Experiments have shown differences in both hydrocarbon and NO_x values determined for comparable samples obtained by the two methods. The seriousness of this problem is discussed in relation to the sampling and sample handling procedures that are used.     

Variability in herbivore-induced odour emissions among maize cultivars and their wild ancestors (teosinte)

Summary. Maize plants respond to caterpillar feeding with the release of relatively large amounts of specific volatiles, which are known to serve as cues for parasitoids to locate their host. Little is known about the genetic variability in such herbivore-induced plant signals and about how the emissions in cultivated plants compare to those of their wild relatives. For this reason we compared the total quantity and the qualitative composition of the odour blend among eleven maize cultivars and five wild Zea (Poaceae) species (teosinte), as well as among the offspring of eight Zea mays mexicana plants from a single population. Young plants were induced to release volatiles by mechanically damaging the leaves and applying oral secretions of Spodoptera littoralis (Lepidoptera: Noctuidae) caterpillars to the wounded sites. Volatiles were collected 7 h after treatment and subsequently analysed by gas chromatography. The total amounts of volatiles released were significantly different among maize cultivars as well as among the teosintes. Moreover, striking differences were found in the composition of the induced odour blends. Caryophyllene, for instance, was released by some, but not all varieties and teosintes, and the ratios among monoterpenes and sesquiterpenes varied considerably. The offspring of different mother plants of the Z. m. mexicana population showed some variation in the total amounts that they released, but the composition of the odour blend was very consistent within the population of this teosinte species. We discuss the ecological significance of these findings in terms of specificity and reliability of induced plant signals for parasitoids.     

Temporal and Spatial Turbidity Patterns Over 30 Years in a Managed Forest of Western Washington1

Abstract: Forest practices have progressively changed over the last 30 years in the Pacific Northwest to address water quality concerns. There have been some assessments of these new management practices made at a site scale but very few studies have attempted to evaluate their efficacy at reducing cumulative sediment production at a watershed scale. Such an evaluation is difficult due to the spatial and temporal variability in sediment delivery and transport processes. Due to this inherent variability, detecting a response to management changes requires a long‐term data record. We utilized a water quality dataset collected over 30 years at four locations in the Deschutes River watershed (western Washington) to assess trends in turbidity and whether sediment control procedures implemented over this time period had any detectable influence. The sample sites ranged from small headwater streams (2.4 and 3.0 km²) to the mainstem of the Deschutes River (150 km²). Declining trends in turbidity were detected at all the permanently monitored sites. The mainstem Deschutes River site, which integrates sediment processes from the entire study watershed, showed dramatic declines in turbidity even with continued active forest management. For the small basins, logging and road construction occurred in the 1970s and 1980s and turbidity declined thereafter, achieving prelogging levels by 2000. There are no temporal trends in flow that could be responsible for the observed trends in turbidity. Our results suggest that increased attention to reducing sediment production from roads and minimizing the amount of road runoff reaching stream channels has been the primary cause of the declining turbidity levels observed in this study.     

Comparison of slope stability in two Brazilian municipal landfills

The implementation of landfill gas to energy (LFGTE) projects has greatly assisted in reducing the greenhouse gases and air pollutants, leading to an improved local air quality and reduced health risks. The majority of cities in developing countries still dispose of their municipal waste in uncontrolled 'open dumps.' Municipal solid waste landfill construction practices and operating procedures in these countries pose a challenge to implementation of LFGTE projects because of concern about damage to the gas collection infrastructure (horizontal headers and vertical wells) caused by minor, relatively shallow slumps and slides within the waste mass. While major slope failures can and have occurred, such failures in most cases have been shown to involve contributory factors or triggers such as high pore pressures, weak foundation soil or failure along weak geosynthetic interfaces. Many researchers who have studied waste mechanics propose that the shear strength of municipal waste is sufficient such that major deep-seated catastrophic failures under most circumstances require such contributory factors. Obviously, evaluation of such potential major failures requires expert analysis by geotechnical specialists with detailed site-specific information regarding foundation soils, interface shearing resistances and pore pressures both within the waste and in clayey barrier layers or foundation soils. The objective of this paper is to evaluate the potential use of very simple stability analyses which can be used to study the potential for slumps and slides within the waste mass and which may represent a significant constraint on construction and development of the landfill, on reclamation and closure and on the feasibility of a LFGTE project. The stability analyses rely on site-specific but simple estimates of the unit weight of waste and the pore pressure conditions and use "generic" published shear strength envelopes for municipal waste. Application of the slope stability analysis method is presented in a case study of two Brazilian landfill sites; the Cruz das Almas Landfill in Maceio and the Muribeca Landfill in Recife. The Muribeca site has never recorded a slope failure and is much larger and better-maintained when compared to the Maceio site at which numerous minor slumps and slides have been observed. Conventional limit-equilibrium analysis was used to calculate factors of safety for stability of the landfill side slopes. Results indicate that the Muribeca site is more stable with computed factors of safety values in the range 1.6-2.4 compared with computed values ranging from 0.9 to 1.4 for the Maceio site at which slope failures have been known to occur. The results suggest that this approach may be useful as a screening-level tool when considering the feasibility of implementing LFGTE projects.     

Analysis of mobile source air toxics (MSATs)—Near-road VOC and carbonyl concentrations

Exposures to mobile source air toxics (MSATs) have been associated with numerous adverse health effects. While thousands of air toxic compounds are emitted from mobile sources, members of a subset of compounds are considered high priority due to their significant contribution to cancer and noncancer health risks and the contribution of mobile sources to total exposure as evaluated by the U.S. Environmental Protection Agency (EPA) National-Scale Air Toxics Assessments (NATA). These pollutants include benzene, 1,3-butadiene, ethylbenzene, acrolein, acetaldehyde, formaldehyde, naphthalene, polycyclic organic matter, and diesel particulate matter/organic gases. This study provided year-long trends of benzene, 1,3-butadiene, acrolein, acetaldehyde, and formaldehyde in Las Vegas, NV. Results indicated that MSAT concentrations often did not exhibit trends typical of other primary emitted pollutants in this study. Instead, other mobile sources beyond the highway of interest contributed to the measured values, including a major arterial road, a large commercial airport, and a nearby parking lot. The data were compared with relevant census-tract NATA estimates, with estimated ambient 1,3-butadiene concentrations similar to the measured values. Measured benzene values were much lower relative to the NATA total ambient benzene concentrations. Measured acrolein values were much higher relative to the NATA total acrolein concentrations. Measured acetaldehyde and formaldehyde values were also higher relative to the NATA total acetaldehyde and formaldehyde concentrations for all wind conditions and downwind conditions. Some possible explanations for these differences include nearby sources influencing the measured values; meteorological influences that may not be well captured by the NATA modeling regime; chemical reactivity of measured compounds; and additional explanatory variables may be needed for certain urban areas in order to accurately disaggregate anthropogenic air toxics emissions.

Implications: Comparison of air toxics concentrations measured at four long-term near-road sites in Las Vegas, NV, show generally good agreement with the EPA 2005 U.S. Environmental Protection Agency. 2005. National Air Toxics Assessments (NATA)(accessed December 7, 2012) http://www.epa.gov/ttn/atw/natamain/index.html (http://www.epa.gov/ttn/atw/natamain/index.html)  [Google Scholar] NATA total ambient concentrations. Measured concentrations did not compare as well with EPA 2005 U.S. Environmental Protection Agency. 2005. National Air Toxics Assessments (NATA)(accessed December 7, 2012) http://www.epa.gov/ttn/atw/natamain/index.html (http://www.epa.gov/ttn/atw/natamain/index.html)  [Google Scholar] NATA for the on-road mobile portion of the ambient concentrations. This highlights the complexity of air toxic emission sources and impacts in urban areas, especially around large highway facilities; NATA's inability to capture local-scale meteorology and fine-scale ambient gradients; and that additional explanatory variables may be needed for certain urban areas in order to accurately disaggregate anthropogenic air toxics emissions.     

An evaluation of the applicability of microarrays for monitoring toxic algae in Irish coastal waters

The applicability of microarrays to monitor harmful algae across a broad range of ecological niches and toxic species responsible for harmful algal events has been one of the key tasks in the EU Seventh Framework Programme (FP7)-funded Microarrays for the Detection of Toxic Algae project. The technique has a strong potential for improving speed and accuracy of the identification of harmful algae and their toxins to assist monitoring programmes. Water samples were collected from a number of coastal sites around Ireland, including several that are used in the Irish National Phytoplankton and Biotoxin Monitoring Programme. Ribosomal RNA was extracted from filtered field samples, labelled with a fluorescent dye, and hybridised to probes spotted in a microarray format on a glass slide. The fluorescent signal intensity of the hybridisation to >120 probes on the chip was analysed and compared with actual field counts. There was a general agreement between cell counts and microarray signal. Results are presented for field samples taken from a range of stations along the Irish coastline known for harmful algal events during the first field trial (July 2009–April 2010).     

Role of Propagule Size in the Success of Incipient Colonies of the Invasive Argentine Ant

Abstract: Factors that contribute to the successful establishment of invasive species are often poorly understood. Propagule size is considered a key determinant of establishment success, but experimental tests of its importance are rare. We used experimental colonies of the invasive Argentine ant (   Linepithema humile ) that differed both in worker and queen number to test how these attributes influence the survivorship and growth of incipient colonies. All propagules without workers experienced queen mortality, in contrast to only 6% of propagules with workers. In small propagules (10–1,000 workers), brood production increased with worker number but not queen number. In contrast, per capita measures of colony growth decreased with worker number over these colony sizes. In larger propagules ( 1,000–11,000 workers), brood production also increased with increasing worker number, but per capita brood production appeared independent of colony size. Our results suggest that queens need workers to establish successfully but that propagules with as few as 10 workers can grow quickly. Given the requirements for propagule success in Argentine ants, it is not surprising how easily they spread via human commerce.