An improved dual channel PERCA instrument for atmospheric measurements of peroxy radicals

This paper describes a new dual-channel PEroxy RadiCal Amplification (PERCA) instrument, which has been designed to improve the time resolution and signal to noise and to reduce the interference caused by variations in ambient ozone concentrations. The instrument was run at the Weybourne Atmospheric Observatory (WAO), North Norfolk, during WAOWEX (Weybourne Atmospheric Observatory Winter Experiment) in January/February 2002 and INSPECTRO (Influence of clouds on the spectral actinic flux in the lower troposphere) in September 2002. The performance of the instrument is assessed and compared to that of a single channel instrument. In particular, it is shown how the precision is greatly improved in fluctuating background ozone conditions. In addition the improved time response of the instrument allows changes in peroxy radical concentrations to be related to rapid changes in nitric oxide concentrations and the ozone photolysis frequency, j(O(1)D).     

Effective Population Size in Red-Cockaded Woodpeckers: Population and Model Differences

Loss of genetic variability in isolated populations is an important issue for conservation biology. Most studies involve only a single population of a given species and a single method of estimating rate of loss. Here we present analyses for three different Red-cockaded Woodpecker ( Picoides borealis ) populations from different geographic regions. We compare two different models for estimating the expected rate of loss of genetic variability, and test their sensitivity to model parameters. We found that the simpler model (Reed et al. 1988) consistently estimated a greater rate of loss of genetic variability from a population than did the Emigh and Pollak (1979) model. The ratio of effective population size (which describes the expected rate of loss of genetic variability) to breeder population size varied widely among Red-cockaded Woodpecker populations due to geographic variation in demography. For this species, estimates of effective size were extremely sensitive to survival parameters, but not to the probability of breeding or reproductive success. Sensitivity was sufficient that error in estimating survival rates in the field could easily mask true population differences in effective size. Our results indicate that accurate and precise demographic data are prerequisites to determining effective population size for this species using genetic models, and that a single estimate of rate of loss of genetic variability is not valid across populations.     

AN ASSESSMENT OF USES MADE OF A MULTIPURPOSE RESERVOIR'

ABSTRACT: Data were collected from residents of a rural community at two time periods to assess attitudes toward uses made of a reservoir which had been recently constructed in the area. The findings revealed that attitudes became significantly more favorable for flood control, water supply, and recreation uses of the reservoir. Attitudes toward fish and wildlife conservation use were not significantly different over time but these uses were perceived positively at both time periods. The data were also analyzed in the context of a vested interest perspective using cross-sectional design. The findings demonstrated that the theoretical model used to guide the investigation was quite useful in predicting attitudes toward the four uses examined.     

Age dependence of potentially toxic elements (Sb,Cd, Pb,Ag) in human liver tissue from paediatric subjects

Toxic elements are present at low concentrations in the environment. This work was undertaken to investigate the age dependence of the liver content of selected elements in paediatric populations, as an index of internal exposure. Liver samples were collected at autopsy from 157 subjects, aged < 1 day to 6 years, as part of investigations on a possible role of Sb compounds in sudden infant death syndrome (SIDS). In addition to Sb, the concentrations of Ag, Cd and Pb were also determined by inductively coupled plasma mass spectrometry on the remaining digest. Comparison of 95% confidence intervals of the median concentrations of the four elements suggested that there were no differences between the two categories of cause of death, SIDS or those who had died of an identified disease. Cadmium, lead and antimony median concentrations were lower than corresponding values observed in adult populations. Silver concentrations were significantly higher at birth and decreased with age. Cadmium levels were almost negligible in neonates and infants, but increased in older children. The finding of non-negligible concentrations of both Ag and Pb in neonatal liver provides further direct evidence that these elements cross the human placental barrier. The reported data, by far the largest collection observed in subjects less than 1 year old, are the result of exposure, during pregnancy and in early childhood, to present levels of these elements in the environment. They can serve as a reference to compare post-mortem values from individuals or groups of subjects in this age range when an exposure risk is suspected and to highlight trends in human exposure.     

A watershed management framework for mountain areas: Lessons from 25 years of watershed conservationin Nepal

A watershed management framework for mountain areas is based on lessons learned from watershed management experience, social and institutional learning, and the use of a watershed management program evaluation in Nepal. The lessons led to the adoption of a subwatershed-based ecosystem approach based on local participation at the subwatershed level. An integrated watershed management framework (IWMF) consisting of eight steps with three checklists was developed focusing on improvement-oriented adaptive management. The eight steps lead to the preparation of a watershed management plan. In the process three checklists are used. While the first checklist has general questions pertaining to watershed analysis, the second allows participation analysis of stakeholders in terms of their strengths, weaknesses, opportunities and threats and opens up new prospects for further reinforcing or building new user group institutions based on consensus. The final checklist consists of hierarchical watershed management objectives, including goals, results and activities leading to a program planning matrix. The framework was applied to watershed planning in the Chure Region to compare the framework-based planning with conventional planning procedures. A significant difference in quality and substance of the output, with and without the use of the framework, suggests that an integrated framework is a useful tool for an ecosystem-based approach to natural resource management and socio-technical conservation.     

In situ thermal remediation of DNAPL and LNAPL using electrical resistance heating

Electrical resistance heating (ERH) is an in situ treatment for soil and groundwater remediation that can reduce the time to clean up volatile organic compounds (VOCs) from years to months. The technology is now mature enough to provide site owners with both performance and financial certainty in their site‐closure process. The ability of the technology to remediate soil and groundwater impacted by chlorinated solvents and petroleum hydrocarbons regardless of lithology proves to be beneficial over conventional in situ technologies that are dependent on advective flow. These conventional technologies include: soil vapor recovery, air sparging, and pumpand‐treat, or the delivery of fluids to the subsurface such as chemical oxidization and bioremediation. The technology is very tolerant of subsurface heterogeneities and actually performs as well in low‐permeability silts and clay as in higher‐ permeability sands and gravels. ERH is often implemented around and under buildings and public access areas without upsetting normal business operations. ERH may also be combined with other treatment technologies to optimize and enhance their performance. This article describes how the technology was developed, how it works, and provides two case studies where ERH was used to remediate complex lithologies. © 2005 Wiley Periodicals, Inc.     

An ecological approach to environmental impact assessment

Carbon cycling analysis is presented as a means for assessing anthropogenic perturbations in an ecosystem. Data from oligotrophic, eutrophic, and dystrophic (bog) lakes are used to show general trends in the lacustrine carbon cycle. The oligotrophic lake is an unstressed system and the eutrophic lake is under nutrient enrichment with high algal standing crops and productivity. The bog lake is a pH-stressed environment that is primarily a grazing ecosystem. It is hoped that a more effective environmental impact assessment will result from the use of carbon cycling as a unifying concept in ecosystem analysis.     

Spatial and Temporal Patterns of Low Streamflow and Precipitation Changes in the Chesapeake Bay Watershed

Spatial and temporal patterns in low streamflows were investigated for 183 streamgages located in the Chesapeake Bay Watershed for the period 1939–2013. Metrics that represent different aspects of the frequency and magnitude of low streamflows were examined for trends: (1) the annual time series of seven‐day average minimum streamflow, (2) the scaled average deficit at or below the 2% mean daily streamflow value relative to a base period between 1939 and 1970, and (3) the annual number of days below the 2% threshold. Trends in these statistics showed spatial cohesion, with increasing low streamflow volume at streamgages located in the northern uplands of the Chesapeake Bay Watershed and decreasing low streamflow volume at streamgages in the southern part of the watershed. For a small subset of streamgages (12%), conflicting trend patterns were observed between the seven‐day average minimum streamflow and the below‐threshold time series and these appear to be related to upstream diversions or the influence of reservoir‐influenced streamflows in their contributing watersheds. Using multivariate classification techniques, mean annual precipitation and fraction of precipitation falling as snow appear to be broad controls of increasing and decreasing low‐flow trends. Further investigation of seasonal precipitation patterns shows summer rainfall patterns, driven by the Atlantic Multidecadal Oscillation, as the main driver of low streamflows in the Chesapeake Bay Watershed.