全文获取类型
收费全文 | 3014篇 |
免费 | 42篇 |
国内免费 | 25篇 |
专业分类
安全科学 | 163篇 |
废物处理 | 154篇 |
环保管理 | 612篇 |
综合类 | 334篇 |
基础理论 | 725篇 |
环境理论 | 5篇 |
污染及防治 | 752篇 |
评价与监测 | 212篇 |
社会与环境 | 106篇 |
灾害及防治 | 18篇 |
出版年
2023年 | 21篇 |
2022年 | 37篇 |
2021年 | 26篇 |
2020年 | 21篇 |
2019年 | 31篇 |
2018年 | 66篇 |
2017年 | 67篇 |
2016年 | 89篇 |
2015年 | 58篇 |
2014年 | 84篇 |
2013年 | 280篇 |
2012年 | 143篇 |
2011年 | 177篇 |
2010年 | 120篇 |
2009年 | 122篇 |
2008年 | 154篇 |
2007年 | 187篇 |
2006年 | 152篇 |
2005年 | 105篇 |
2004年 | 104篇 |
2003年 | 116篇 |
2002年 | 89篇 |
2001年 | 67篇 |
2000年 | 46篇 |
1999年 | 51篇 |
1998年 | 38篇 |
1997年 | 43篇 |
1996年 | 43篇 |
1995年 | 40篇 |
1994年 | 41篇 |
1993年 | 34篇 |
1992年 | 37篇 |
1991年 | 26篇 |
1990年 | 29篇 |
1989年 | 19篇 |
1988年 | 13篇 |
1987年 | 20篇 |
1986年 | 25篇 |
1985年 | 17篇 |
1984年 | 18篇 |
1983年 | 28篇 |
1982年 | 28篇 |
1981年 | 25篇 |
1980年 | 19篇 |
1979年 | 16篇 |
1977年 | 11篇 |
1976年 | 9篇 |
1975年 | 9篇 |
1974年 | 10篇 |
1971年 | 11篇 |
排序方式: 共有3081条查询结果,搜索用时 233 毫秒
381.
Gerhard Scherer Thomas Ruppert Helmut Daube Irmtrud Kossien Kirsten Riedel Anthony R. Tricker Franz Adlkofer 《Environment international》1995,21(6)
The concentrations of environmental tobacco smoke (ETS) constituents including benzene were measured in the living rooms of 10 nonsmoking households and 20 households with at least one smoker situated in the city and suburbs of Munich. In the city, the median benzene levels during the evening, when all household members were at home, were 8.1 and 10.4 μg/m3 in nonsmoking and smoking homes, respectively. The corresponding levels of 3.5 and 4.6 μg/m3 were considerably lower in the suburbs. Median time-integrated 1-week benzene concentrations in the city were 10.6 μg/m3 in nonsmoking homes and 13.1 μg/m3 in smoking homes. In the suburbs, the corresponding values were 3.2 and 5.6 μg/m3. While the benzene concentrations in nonsmoking homes located in the city were significantly higher (p < 0.05) than in suburban nonsmoking households, no difference was found between smoking and nonsmoking households located either in the city or in the suburbs. Individual exposures to benzene and to specific markers for tobacco smoke of all household members (82 nonsmokers and 32 smokers) were determined by questionnaire, personal monitoring, and biomonitoring. Within the city, the benzene exposure determined by personal samplers was 11.8 μg/m3 for nonsmokers living in nonsmoking homes and 13.3 μg/m3 for nonsmokers in smoking homes. The corresponding values for nonsmokers living in the suburbs were 5.9 and 6.9 μg/m3, respectively. Neither difference was statistically significant. Nonsmokers living in nonsmoking households in the city had significantly higher exposure to benzene compared to their counterparts living in the suburbs (personal samplers: 11.8 vs 5.9 μg/m3, p < 0.001; benzene in exhalate: 2.4 vs. 1.1 μg/m3, p < 0.05; trans,trans-muconic acid excretion in urine: 92 vs. 54 μg/g creatinine, p < 0.05). Nonsmokers from all households with smokers were significantly more exposed to benzene than nonsmokers living in the nonsmoking households (personal samplers: 13.2 vs. 7.0 μg/m3, p < 0.05; benzene in exhalate: 2.6 vs. 1.8 μg/m3, p < 0.01; trans,trans-muconic acid excretion in urine: 73 vs. 62 μg/g creatinine), but the contribution of ETS to the total benzene exposure was relatively low compared to that from other sources. Analysis of variance showed that at most 15% of the benzene exposure of nonsmokers living in smoking homes was attributable to ETS. For nonsmokers living in nonsmoking households benzene exposure from ETS was insignificant. 相似文献
382.
Thomas C. Pederson 《Environment international》1981,5(4-6)
This study examines whether chemical components from diesel exhaust particulates react with DNA to form covalently bound adducts. Experiments in this report describe the in vitro reaction of purified DNA with a dichloromethane extract of diesel exhaust particulates in the absence or presence of enzyme activation by rat liver microsomes. The reactivity of the particle extract was compared to that of benzo[a]pyrene metabolites using low temperature fluorescence techniques which detect small quantities of polycyclic aromatic compounds bound to DNA. Incubation of DNA with the particle extract in the presence of microsomal enzymes produced no detectable fluorescent adducts in contrast to model experiments using benzo[a]pyrene. However, addition of the particle extract to incubation mixtures containing benzo[a]pyrene markedly decreased formation of benzo[a]pyrene-DNA adducts because the particle extract inhibits microsomal enzymes which activate benzo[a]pyrene and other polycyclic aromatic hydrocarbons. In the absence of microsomal enzymes, fluorescent material was detected in DNA exposed to high concentrations of the particle extract, but probably not as a result of covalent binding because the mutagenic activity of the particle extract remained unchanged during prolonged incubation with DNA. This stability is in contrast to the rapid decrease in mutagenic activity of benzo[a]pyrene-4,5-oxide during incubation with DNA. Thus, direct mutation of bacteria by the particle extract may require activation by bacterial enzymes as is known to occur with nitroaromatic compounds. 相似文献
383.
The National Oceanic and Atmospheric Administration's (NOAA) National Status and Trends (NS&T) Programme has analyzed samples of surface sediment collected at almost 300 coastal and estuarine sites throughout the United States since 1984. the overall distributions for concentrations of each element are approximately lognormal allowing a definition of geometric means and of “high” concentrations as those exceeding the mean plus one standard deviation of the lognormal distribution. Those mean and “high” concentrations should be useful for comparing the NS&T data set and with other reports on sediment contamination. A world-wide data set, constructed from data in the literature, was summarized in an identical manner. It was found, after excluding locally extreme values, that the NS&T and world-wide data sets yielded very similar mean and “high” concentrations for Cu, Ni, Pb and Zn. Chromium was the sole element showing higher summary statistics in the NS&T data set, a result attributed to NS&T sampling in areas of naturally (not contaminated) elevated Cr content. It remains undetermined, however, why the world-wide data set, even with exclusion of “hot spots”, yielded higher means and “highs” for Cd, Hg, As, and Ag. 相似文献
384.
The dissolved organic matter in aquatic systems consists of a heterogeneous mixture of compounds with wide ranging chemical properties and diverse origins. the presence of organic matter (OM) in surface and ground waters has important implications with regard to the mobility and therefore fate of many potential organic and inorganic pollutants. the majority of the analytical approaches in current use require exhaustive pre-treatment steps which may lead to the formation of artefacts within the sample. an analytical technique based upon gel permeation chromatography is proposed as a more reliable procedure for the characterisation of naturally occurring dissolved organic matter. 相似文献
385.
Summary. Previous studies indicated the presence of antennally-active compounds in extracts of eggs laid by female cabbage root flies,
Delia radicum, that stimulated oviposition by conspecific females. We confirmed that previously laid D. radicum eggs stimulated oviposition by other D. radicum females, in a dose-dependent manner. Methanol extracts of conspecific eggs stimulated oviposition by females D. radicum, whereas egg extracts of D. antiqua and Psila rosae had no effect. Electrophysiological recordings from the tarsal sensilla of D. radicum females indicated that neurones of the C5 sensillum responded to the egg extracts from both D. radicum and D. antiqua, but not P. rosae. Chemical analysis revealed that the extract of eggs from D. radicum contained the thia-triaza-fluorene compound, 1,2-dihydro-3-thia-4,10,10b-triaza-cyclopenta[.a.]fluorene-1-carboxylic acid
(CIF-1), an oviposition stimulant found previously only in cruciferous plants. Another potentially active component has yet
to be identified. 相似文献
386.
387.
Several tetrachlorodibenzofuran isomers were photolyzed by ultraviolet irradiation and the relative amounts of the various trichlorodibenzofurans produced were determined. A simple set of guidelines for predicting the relative amounts of these photolysis products has been formulated. 相似文献
388.
389.
390.