ACID PRECIPITATION AND WEATHERING BY ORGANIC ACIDS IN LABRAI)OR LAKE BASINS1

ABSTRACT: Thirty-five lakes in southern Labrador sampled in 1981 were resampled in 1989 and water chemistry values were compared between visits. Results showed higher pH, specific conductance, acid neutralization capacity, color, and base cations values in 1989, though sulfate, the ion most likely to reflect acid precipitation impacts, did not vary. The major ion changes measured were probably due to natural hydrological variations and not to changes in acid inputs. Results from the 1989 data showed a slight, but significant, decrease in water sulfate concentration trend from western to eastern Labrador, though most values, even in the western portion of the study area, fell close to the values considered “background” by Brakke et at. (1989). Base cation concentrations exceeded those which could be predicted from weathering by carbonic and bicarbonic acid. Assuming that little weathering is generated by acid precipitation in this region, the excess cations measured are probably a result of bedrock dissolution from organic acids generated by plant decomposition. Calculations showed that organic acid effect could be responsible for 9 to 52 percent of total weathering in the study basins.     

Correlation of indoor radon concentration to commonly available geologic data

Over the last several years, the inhalation of decay products coming from radon-222 has become a national health concern. It is estimated that somewhere between 16,000 and 20,000 people die annually in the United States from lung cancer due to exposure to these decay products. Nationwide, 95% of all homes have not been tested for radon, and so it would seem that any methodology that could give a general idea of indoor radon concentrations (without actually testing the house itself) might be useful. While not intended to replace a radon test, which is both simple and inexpensive, our project attempts to predict indoor radon concentrations based on easily obtainable information from Soil Conservation Service county soil surveys and US Geological Survey surficial geology maps. We have chosen four parameters: soil permeability, surficial geology, soil shrink-swell potential, and distance to the nearest geologic fault. Of these four variables, surficial geology and distance to fault correlated well to winter indoor radon concentrations as measured by short-term (48-h) tests. While it is understood that there are limits to this methodology, primarily because of map scale problems, the correlations mentioned above were very strong and suggest further study would be useful.     

Is motion more important than it sounds?: The medium of presentation in environment perception research

This study assessed the incremental validity of different media for representing landscapes with significant dynamic elements. The experimental design independently varied the presence of motion and sound in different representations of a wild and scenic river in order to evaluate the adequacy or sufficiency of the surrogate to reflect physical changes in the landscape. Three representational conditions were identified: (1) video/sound, (2) video/no sound, and (3) static/no sound. A pilot study assessed the ability of the static images to represent river flow levels per se, and confirmed comparability with prior results (Brown & Daniel, 1989, Journal of Environmental Psychology, 7, 233–250). Scenic beauty judgments were then collected within each representational condition. Multiple regression analyses were used to determine the relationship of flow level to perceived scenic beauty for each representation condition. The results demonstrated that motion and sound, individually and conjointly, influenced judgements of scenic beauty for a landscape with a significant dynamic element.     

CENTRAL NEBRASKA RIVER BASINS,NEBRASKA1

ABSTRACT: The Central Nebraska Basins (NAWQA) study unit includes the Platte River and two major tributaries, the Loup and Elkhorn Rivers. Platte River flows are variable in the western part of the study unit because of diversions, but the Loup and Elkhorn Rivers originate in an area of dune sand covered by grassland that generates consistent base flows. More frequent runoff in the eastern part of the study unit also sustains stream flow. Ground water in the study unit has no regional confining units and the system is a water table aquifer throughout. Macroinvertebrate and fish taxa at biological sampling sites in the state were related to stream flow. One of the four wetland complexes identified in the study unit includes habitat for threatened and endangered bird species. The study unit is an agricultural area that includes row crops, both irrigated and nonirrigated in the eastern and southern parts, and rangeland in the Sand Hills of the western part. A water quality assessment will be based on the differences in environmental setting in each of four subunits within the study unit.]     

PROBABILISTIC GREAT LAKES HYDROLOGY OUTLOOKS1

ABSTRACT: The Great Lakes Environmental Research Laboratory developed a semiautomatic software package for making hydrological outlooks for the Great Lakes. These include basin moisture storages, basin runoff, lake heat storage, lake evaporation, heat fluxes, and net lake supplies, one or more full months into the future. The package combines GLERL's rainfall-runoff and lake evaporation models with near real-time data reduction techniques to represent current system states. Users select historical meteorologic record segments as candidate future scenarios to generate deterministic near real-time hydrological outlooks. GLERL has extended the package to make probabilistic outlooks for a decision-maker who must estimate the risk associated with his decisions. GLERL matches National Weather Service meteorologic outlook probabilities by selecting groups of historical meteorologic sequences, and constructs embedded outlook intervals for each hydrologic variable of interest. Interval probabilities are assigned from comparisons over a recent evaluation period. This physically-based approach for generating outlooks offers the ability, as compared to other statistically-based approaches, to incorporate improvements in the understanding, of process dynamics as they occur in the future and to respond reasonably to conditions initial to a forecast (such as heat and moisture storages), not observed in the past.     

REGIONAL WATER QUALITY MANAGEMENT GREAT MIAMI RIVER,OHIO1

The Miami Conservancy District was organized shortly after the disastrous flood of March 1913 to provide flood protection to municipalities along the Great Miami River. The District system is a classic solution which was entirely locally financed and is now operated and maintained by special benefit assessments on 45,000 parcels of property, 9 cities and 5 counties.     

Biodegradation of Slow-Release Fertilizers (Methyleneureas) in Soil

The biodegradation of urea and condensation products thereof (ureaforms or methyleneureas), their nitrification, and their influence on the respiratory rate of soil was studied over periods of up to 100 days. The total methyleneurea content of the soil was determined after its acidic extraction, using a convenient colorimetric assay, and an HPLC protocol was established to analyze for specific components of methyleneureas. Urea, unfractionated methyleneureas, and hot-water soluble methyleneureas were rapidly metabolized to ammonium, which accumulated to high concentrations and was consequently oxidized to nitrate; an accumulation of nitrite was observed during urea but not during methyleneurea degradation. Hot water-insoluble methyleneureas were degraded much more slowly, and ammonium formed from these compounds was oxidized to nitrate without being released in significant amounts. These results suggest that the use of methyleneureas of optimized composition with regard to their water solubility may help to resolve problems such as the toxicity of ammonia to plant growth as well as nitrogen loss by leaching of nitrate, denitrification and volatilization.     

WalkSafe: a school-based pedestrian safety intervention program

OBJECTIVE: To evaluate the effectiveness of the WalkSafe program, an elementary school-based pedestrian safety program in a single high-risk district in Miami-Dade County. METHODS: Sixteen elementary schools were identified in a single high-risk district and enrolled in a one-year study. All schools implemented the WalkSafe program on the last week of January 2003. A pre, post, and three-month post testing of pedestrian safety knowledge was conducted. An observational component was also implemented at four schools that were randomly chosen. Engineering recommendations and law enforcement initiatives were also performed. RESULTS: A total of 6467 children from K-5th grade from 16 elementary schools participated in the program. Of these 5762 tests were collected over three different testing times. A significant difference (p-value < 0.001) was found between the pre and post testing conditions across all grade levels. There was no significant difference found between the post and three-month post testing conditions across all grade levels (p-value > 0.05). The observational data collected at four schools across the different testing times demonstrated a significant difference found between pre and post testing conditions for Group A (stop at the curb and look left, right, left) and also for Group B (midstreet crossing and darting out) (p-value < 0.05). There was no difference found between comparing the pre-test or post-test condition with the three-month post-test time. There were many environmental modifications that were recommended and actually performed. CONCLUSION: The WalkSafe program implemented in a single high-risk district was shown to improve the pedestrian safety knowledge of elementary school children. The observational data demonstrated improved crossing behaviors from pre-test to post-testing conditions. Future research will focus on sustaining the program in this district and expanding the program throughout our county.