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191.
An understanding of the environmental effects of the use of wildland fire retardant is needed to provide informed decision-making regarding forest management. We compiled data from all post-fire surface water monitoring programs where the fire retardant constituents ammonia, phosphorus, and cyanide were measured, and data were available in the public domain. For streams near four major wildfires, we evaluated whether these chemicals originated primarily from fire or from retardant use. We compared measured concentrations in streams where chemical wildland fire retardant was applied with concentrations in streams draining areas where retardant was not used. Correlations with calcium provided an additional line of evidence, because calcium concentrations in ash are much higher than in retardant. Ammonia, phosphorus, and total cyanide were found in streams in burned areas where retardant was not used, at concentrations similar to those found in areas where retardant was applied. Concentrations of weak acid dissociable cyanide were generally non-detected or very low, whether or not wildland fire retardant was used in the watershed. These results indicate that the application of wildland fire retardant had minimal effects on proximate surface water quality. Cyanide concentrations in post-fire stormwater runoff were not affected by the presence of ferrocyanide in the retardant formulas and were due to pyrogenic sources. 相似文献
192.
Reactive properties of aquifer solid phase materials play an important role in solute fate and transport in the natural subsurface on time scales ranging from years in contaminant remediation to millennia in dynamics of aqueous geochemistry. Quantitative tools for dealing with the impact of natural heterogeneity in solid phase reactivity on solute fate and transport are limited. Here we describe the use of a structural variable to keep track of solute flux exposure to reactive surfaces. With this approach, we develop a non-reactive tracer model that is useful for determining the signature of multi-scale reactive solid heterogeneity in terms of solute flux distributions at the field scale, given realizations of three-dimensional reactive site density fields. First, a governing Eulerian equation for the non-reactive tracer model is determined by an upscaling technique in which it is found that the exposure time of solution to reactive surface areas evolves via both a macroscopic velocity and a macroscopic dispersion in the artificial dimension of exposure time. Second, we focus on the Lagrangian approach in the context of a streamtube ensemble and demonstrate the use of the distribution of solute flux over the exposure time dimension in modeling two-dimensional transport of a solute undergoing simplified linear reversible reactions, in hypothetical conditions following prior laboratory experiments. The distribution of solute flux over exposure time in a given case is a signature of the impact of heterogeneous aquifer reactivity coupled with a particular physical heterogeneity, boundary conditions, and hydraulic gradient. Rigorous application of this approach in a simulation sense is limited here to linear kinetically controlled reactions. 相似文献
193.
Yang K Xu Q Townsend TG Chadik P Bitton G Booth M 《Journal of the Air & Waste Management Association (1995)》2006,56(8):1130-1138
Hydrogen sulfide (H2S) generation in construction and demolition (C&D) debris landfills has been associated with the biodegradation of gypsum drywall. Laboratory research was conducted to observe H2S generation when drywall was codisposed with different C&D debris constituents. Two experiments were conducted using simulated landfill columns. Experiment 1 consisted of various combinations of drywall, wood, and concrete to determine the impact of different waste constituents and combinations on H2S generation. Experiment 2 was designed to examine the effect of concrete on H2S generation and migration. The results indicate that decaying drywall, even alone, leached enough sulfate ions and organic matter for sulfate-reducing bacteria (SRB) to generate large H2S concentrations as high as 63,000 ppmv. The codisposed wastes show some effect on H2S generation. At the end of experiment 1, the wood/drywall and drywall alone columns possessed H2S concentrations > 40,000 ppmv. Conversely, H2S concentrations were < 1 ppmv in those columns containing concrete. Concrete plays a role in decreasing H2S by increasing pH out of the range for SRB growth and by reacting with H2S. This study also showed that wood lowered H2S concentrations initially by decreasing leachate pH values. Based on the results, two possible control mechanisms to mitigate H2S generation in C&D debris landfills are suggested. 相似文献
194.
MacDonald CP McCarthy MC Dye TS Wheeler NJ Hafner HR Roberts PT 《Journal of the Air & Waste Management Association (1995)》2006,56(7):961-976
Data analysis and modeling were performed to characterize the spatial and temporal variability of wintertime transport and dispersion processes and the impact of these processes on particulate matter (PM) concentrations in the California San Joaquin Valley (SJV). Radar wind profiler (RWP) and radio acoustic sounding system (RASS) data collected from 18 sites throughout Central California were used to estimate hourly mixing heights for a 3-month period and to create case studies of high-resolution diagnostic wind fields, which were used for trajectory and dispersion analyses. Data analyses show that PM episodes were characterized by an upper-level ridge of high pressure that generally produced light winds through the entire depth of the atmospheric boundary layer and low mixing heights compared with nonepisode days. Peak daytime mixing heights during episodes were -400 m above ground level (agl) compared with -800 m agl during nonepisodes. These episode/nonepisode differences were observed throughout the SJV. Dispersion modeling indicates that the range of influence of primary PM emitted in major population centers within the SJV ranged from -15 to 50 km. Trajectory analyses revealed that little intrabasin pollutant transport occurred among major population centers in the SJV; however, interbasin transport from the northern SJV and Sacramento regions into the San Francisco Bay Area (SFBA) was often observed. In addition, this analysis demonstrates the usefulness of integrating RWP/RASS measurements into data analyses and modeling to improve the understanding of meteorological processes that impact pollution, such as aloft transport and boundary layer evolution. 相似文献
195.
Hyperspectral and LiDAR remote sensing of fire fuels in Hawaii Volcanoes National Park. 总被引:1,自引:0,他引:1
Alien invasive grasses threaten to transform Hawaiian ecosystems through the alteration of ecosystem dynamics, especially the creation or intensification of a fire cycle. Across sub-montane ecosystems of Hawaii Volcanoes National Park on Hawaii Island, we quantified fine fuels and fire spread potential of invasive grasses using a combination of airborne hyperspectral and light detection and ranging (LiDAR) measurements. Across a gradient from forest to savanna to shrubland, automated mixture analysis of hyperspectral data provided spatially explicit fractional cover estimates of photosynthetic vegetation, non-photosynthetic vegetation, and bare substrate and shade. Small-footprint LiDAR provided measurements of vegetation height along this gradient of ecosystems. Through the fusion of hyperspectral and LiDAR data, a new fire fuel index (FFI) was developed to model the three-dimensional volume of grass fuels. Regionally, savanna ecosystems had the highest volumes of fire fuels, averaging 20% across the ecosystem and frequently filling all of the three-dimensional space represented by each image pixel. The forest and shrubland ecosystems had lower FFI values, averaging 4.4% and 8.4%, respectively. The results indicate that the fusion of hyperspectral and LiDAR remote sensing can provide unique information on the three-dimensional properties of ecosystems, their flammability, and the potential for fire spread. 相似文献
196.
197.
Chencho Norbu Prof. Timothy J. Downs Edward Yeboah Dr. L.J.R. Scholtens Dr. Jyotsna Bapat Maren Oelbermann Ph.D. Sayyed Ahang Kowsar Jaime Alexandra Webbe Bram Govaerts Ph.D. Nele Verhulst M. Sc. Goodspeed Kopolo Maria Rosário Partidário Mr. N’guessan Alphonse Kouassi John All Ph.D. JD Narcisa Pricope Leslie Lipper 《Natural resources forum》2008,32(3):252-256
198.
George R. Holdren Jr. Timothy C. Strickland Bernard J. Cosby David Marmorek David Bernard Robert Santore Charles T. Driscoll Linda Pardo Carolyn Hunsaker Robert S. Turner John Aber 《Environmental management》1993,17(3):355-363
The critical loads approach is emerging as an attractive means for evaluating the effects of atmospheric deposition on sensitive
terrestrial and aquatic ecosystems. Various approaches are available for modeling ecosystem responses to deposition and for
estimating critical load values. These approaches include empirical and statistical relationships, steady-state and simple
process models, and integrated-effects models. For any given ecosystem, the most technically sophisticated approach will not
necessarily be the most appropriate for all applications; identification of the most useful approach depends upon the degree
of accuracy needed and upon data and computational requirements, biogeochemical processes being modeled, approaches used for
representing model results on regional bases, and desired degree of spatial and temporal resolution. Different approaches
are characterized by different levels of uncertainty. If the limitations of individual approaches are known, the user can
determine whether an approach provides a reasonable basis for decision making. Several options, including point maps, grid
maps, and ecoregional maps, are available for presenting model results in a regional context. These are discussed using hypothetical
examples for choosing populations and damage limits.
The research described in this article has been funded by the US Environmental Protection Agency. This document has been prepared
at the EPA Environmental Research Laboratory in Corvallis, Oregon, through contract #68-C8-0006 with ManTech Environmental
Technology, Inc., and Interagency Agreement #1824-B014-A7 with the U.S. Department of Energy and at Oak Ridge National Laboratory
managed by Martin Marietta Energy Systems, Inc., under Contract DE-AC05-84OR21400 with the US Department of Energy. Environmental
Sciences Division Publication No. 3904. It has been subjected to the agency’s peer and administrative review and approved
for publication. Mention of trade names or commercial products does not constitute endorsement or recommendation for use. 相似文献
199.
Carolyn Hunsaker Robin Graham Robert S. Turner Paul L. Ringold George R. Holdren Jr. Timothy C. Strickland 《Environmental management》1993,17(3):335-341
The United States Environmental Protection Agency, with support from the US Department of Energy and the National Oceanographic
and Atmospheric Administration, has been evaluating the feasibility of an effects-based (critical loads) approach to atmospheric
pollutant regulation and abatement. The rationale used to develop three of the six steps in a flexible assessment framework
(Strickland and others, 1992) is presented along with a discussion of a variety of implementation approaches and their ramifications.
The rationale proposes that it is necessary to provide an explicit statement of the condition of the resource that is considered
valuable (assessment end point) because: (1) individual ecosystem components may be more or less sensitive to deposition,
(2) it is necessary to select indicators of ecosystem condition that can be objectively measured and that reflect changes
in the quality of the assessment end point, and (3) acceptable status (i.e., value of indicator and quality of assessment
end point at critical load) must be defined. The rationale also stresses the importance of defining the assessment regions
and subregions to improve the analysis and understanding of the indicator response to deposition. Subregional definition can
be based on a variety of criteria, including informed judgment or quantitative procedures. It also depends on the geographic
scale at which exposure and effects models are accurate and on data availability, resolution, and quality.
The research described in this article has been funded by the US Environmental Protection Agency. This document has been prepared
at the EPA Environmental Research Laboratory in Corvallis, Oregon, through contract #68-C8-0006 with ManTech Environmental
Technology, Inc., and Interagency Agreement #1824-B014-A7 with the US Department of Energy and at Oak Ridge National Laboratory
managed by Martin Marietta Energy Systems, Inc., under Contract DE-AC05-84OR21400 with the US Department of Energy. Environmental
Sciences Division Publication No. 3903. It has been subjected to the agency’s peer and administrative review and approved
for publication. Mention of trade names or commercial products does not constitute endorsement or recommendation for use. 相似文献
200.
Hyde Tools, Inc., of Southbridge, Massachusetts, is a medium-sized firm employing about three hundred persons. In 1988, it learned of a company that eliminated its wastewater discharge after being threatened with massive Clean Water Act fines resulting from a suit brought by a Massachusetts environmental group. Hyde decided to devise a similar program to attain zero water discharge and do it within five years. More than 75 percent toward its goal, Hyde'S environmental success, detailed in this article, still relies heavily on the company'S Total Quality Management system and the efforts of a dedicated environmental staff. Hyde'S success typifies TQEM in action—showing how small continuous improvements can lead to significant financial paybacks. 相似文献