ACCUMULATION OF SELECTED TRACE METALS IN SOILS OF URBAN RUNOFF SWALE DRAINS1

ABSTRACT: Field investigations were conducted at three sites in the Washington, D.C., area to detect the accumulation patterns of the trace metals, cadmium, copper, lead and zinc in the soils of roadside grassed swale drains that had been receiving urban stormwater runoff. Two sites were residential areas and one site was an intensively used highway. The research results seem to indicate that the use of swale drains to control urban stormwater runoff had few harmful effects to fine textured soils with respect to the study metals. With the exception of zinc, typical roadside patterns of decreasing metal concentrations with increasing distance from roads were observed for the upper 5 cm of study soils. Zinc accumulated in residential grassed swales due to leachate from galvanized curverts. Sampling to a depth of 60 cm revealed no evidence of subsurface trace metal enrichment in the study swales. Although the percentage of soil zinc in leachable form was as high as 20 percent of total zinc concentrations, the other study metals had small leachable components. Leachable lead was always less than 1 percent of the total lead.     

Classifying hazardous events

Classification is an information management technique that helps achieve the goals of scientific and applied research by simplifying and ordering complex and varied observations. This paper is intended as a guide to the use and application of classifications of hazardous events. Proposed classifications are reviewed and evaluated in terms of their purposes, methods, supportive evidence and the scientific and applied goals of classification. The review is structured according to the metaphor of the natural life history of a hazard that distinguishes three stages of human-environment interaction: (a) hazard causes, (b) physical and psychosocial characteristics of hazards, and (c) individual and aggregate responses to hazards. The life history perspective has the advantage of being multidimensional and transactional. The structure highlights the relationship between proposed classifications, identifies needed areas of conceptual and empirical development, and provides a general guideline for the selection and use of classifications for hazard management.     

Evaluation of soil-washing process for “unwashable” clays and silts from the palmerton zinc site

The Palmerton Zinc Site is a Superfund site in Palmerton, Pennsylvania. Its former mineral processing operations have contaminated nearby wells and soils with zinc and cadmium. Preliminary analysis of soil and dust sampling conducted in May 1991 has revealed that the dust poses a potential threat to human health. Based on the results of a previous study, which showed a high percentage of silt and clay in soils from Palmerton residential properties, it was concluded that soil washing is not likely to be a viable method to treat the soil and dust contamination in Palmerton. However, since the completion of this study, a soil-washing process for “unwashable” clays and silts has been developed. A residential soil sample from Palmerton, which had low concentrations of arsenic, cadmium, and lead, and a somewhat high concentration of zinc, was washed in a bench-scale version of this process. The results showed that the new soil-washing process for “unwashable” clays and silts may be a viable method to treat the soil and dust contamination in Palmerton, depending on the soil quality criteria concentrations selected for site cleanup.     

Abiotic reduction reactions of anthropogenic organic chemicals in anaerobic systems: A critical review

This review is predicated upon the need for a detailed process-level understanding of factors influencing the reduction of anthropogenic organic chemicals in natural aquatic systems. In particular, abiotic reductions of anthropogenic organic chemicals are reviewed. The most important reductive reaction is alkyl dehalogenation (replacement of chloride with hydrogen) which occurs in organisms, sediments, sewage sludge, and reduced iron porphyrin model systems. An abiotic mechanism involving a free radical intermediate has been proposed. The abstraction of vicinal dihalides (also termed dehalogenation) is another reduction that may have an abiotic component in natural systems. Reductive dehalogenation of aryl halides has recently been reported and further study of this reaction is needed. Several other degradation reactions of organohalides that occur in anaerobic environments are mentioned, the most important of which is dehydrohalogenation. The reduction of nitro groups to amines has also been thoroughly studied. The reactions can occur abiotically, and are affected by the redox conditions of the experimental system. However, a relationship between nitro-reduction rate and measured redox potential has not been clearly established. Reductive dealkylation of the N- and O-heteroatom of hydrocarbon pollutants has been observed but not investigated in detail. Azo compounds can be reduced to their hydrazo derivatives and a thorough study of this reaction indicates that it can be caused by extracellular electron transfer agents. Quinone-hydroquinone couples are important reactive groups in humic materials and similar structures in resazurin and indigo carmine make them useful as models for environmental redox conditions. The interconversion of sulfones, sulfoxides, and sulfides is a redox process and is implicated in the degradation of several pesticides though the reactions need more study. Two reductive heterocyclic cleavage reactions are also mentioned. Finally, several difficulties (both semantic and experimental) that recur in the studies reviewed are discussed. The subtle effects of various sterilization techniques on extracellular biochemicals and complex chemical reducing agents in sediment have stifled attempts to separate abiotic from biological degradation reactions. The characterization of redox conditions in a natural system is still problematic since measured redox potential is not adequate. Suggestions for future research toward a process-level understanding of abiotic chemical reductions are made.     

Pollen dispersal and intensity as criteria for the minimum viable population and species reserves

In small populations the lack of mating individuals may cause a reduction in reproductive potential which can restrict population expansion or cause further population declines. This is especially true in outcrossing monoecious and self-incompatible dioecious plant species. Principles of pollen dispersal suggest that many small to medium size population reserves of round shape will maximize the pollen interaction within and between island reserves. Diverse and low-density ecosystems require more total area in reserves than low-diversity and high-density ecosystems.     

A PLANNING METHOD FOR EVALUATING DOWNSTREAM EFFECTS OF DETENTION BASINS1

While storm water detention basins are widely used for controlling increases in peak discharges that result from urbanization, recent research has indicated that under certain circumstances detention storage can actually cause increases in peak discharge rates. Because of the potential for detrimental downstream effects, storm water management policies often require downstream effects to be evaluated. Such evaluation requires the design engineer to collect additional topographic and land use data and make costly hydrologic analyses. Thus, a method, which is easy to apply and which would indicate whether or not a detailed hydrologic analysis of downstream impacts is necessary, should decrease the average cost of storm water management designs. A planning method that does not require either a large data base or a computer is presented. The time co-ordinates of runoff hydrographs are estimated using the time-of-concentration and the SCS runoff curve number; the discharge coordinates are estimated using a simple peak discharge equation. While the planning method does not require a detailed design of the detention basin, it does provide a reasonably accurate procedure for evaluating whether or not the installation of a detention basin will cause adverse downstream flooding.