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401.
Mi Yan Xiao Dong Li Sheng Yong Lu Tong Chen Yong Chi Jian Hua Yan 《Journal of Material Cycles and Waste Management》2011,13(3):213-218
The huge amount of medical waste (MW) has caused a tough challenge to environmental protection in China because of its serious
infectious potential. At present, incineration is the most common technology for MW disposal. Unfortunately, the medical waste
incinerator (MWI) is considered one of the major sources of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs). This study was conducted to investigate the generation and the components of MW; the
fingerprint of PCDD/Fs in MWI; and PCDD/F, polychlorinated biphenyl (PCB) and hexachlorobenzene concentrations in residue
ash. The estimated annual production of MW was estimated to be 0.97 million tons in China in 2008; in addition, plastic and
rubber accounted for 24.5% of MW contents. PCDD/F emissions from MWI could be divided into two main groups according their
fingerprints, and the ratio of PCDFs/PCDDs was mostly over 1.5, with a mean value of 3.43. The toxic equivalent of PCDD/Fs
was over 30 times that of the value of PCBs in the residue ash, and PCDD/F contents in fly ash accounted for approximately
67% of the total output of PCDD/Fs, which was in line with the UNEP default emission factors for MWI (class 3, 63.7%). 相似文献
402.
In this study, aerobic granules were cultivated in sequencing batch reactors with activated sludge as the seed. The reactors were operated for 12 h per cycle with the organic loading rate (OLR) increasing in double stepwise from 0.5 to 4.0 g COD L−1 d−1. Within the 40 d running, black granules with regular and smooth morphology were cultivated, which had high wet density and high settling velocity. During the granulation process, foams emerged and disappeared in the reactor, coinciding with the proliferation of filamentous microorganisms in the granules, implying that surfactants might exist and play an important role in the granulation. Using ultra performance liquid chromatography-tandem mass spectrometry, the surfactants were identified as homologous compounds of polyethylene glycol (PEG) with molecular weights ranging mainly from 100 to 500 Da. Their general formulas were proposed as HO-[CH2-CH2-O]n-H. The source of PEG still needs further investigation. 相似文献
403.
Thermal removal of PCDD/Fs from medical waste incineration fly ash--effect of temperature and nitrogen flow rate 总被引:2,自引:0,他引:2
The fly ash used in this study was collected from a bag filter in a medical waste rotary kiln incineration system, using lime and activated carbon injection followed by their collection as mixed fly ash. Experiments were conducted on fly ash in a quartz tube, heated in a laboratory-scale horizontal tube furnace, in order to study the effect of temperature and nitrogen flow rate on the removal of PCDD/Fs. Results indicated that in this study PCDD/Fs in the fly ash mostly were removed and desorbed very little into the flue gas under thermal treatment especially when the heating temperature was higher than 350 °C, and dechlorination and destruction reactions took important part in the removal of PCDD/Fs. However, in terms of flow rate, when flow rate was higher than 4 cm s−1, destruction efficiency of PCDD/Fs decreased dramatically and the main contributors were P5CDF, H6CDF and H7CDF desorbed to flue gas, the PCDD/Fs in the fly ash decreased with enhanced flow rate. 相似文献
404.
针对黄磷生产尾气具有强化学活性和腐蚀性的特点,选择了TDX-01型碳分子筛色谱柱,采用气相色谱法测定黄磷尾气中的CO2。实验结果表明:黄磷尾气中高浓度的CO2用TCD检测器检测,CO2体积分数在0.1%~10%时,检测下限可达到0.05%,方法的平均回收率为93.6%~104.1%,相对标准偏差为2.1%~3.2%;净化后黄磷尾气中的微量CO2经Ni催化甲烷化转化后用FID检测器测定,CO2体积分数在1.0×10-7~1.0×10-4时,方法的检测下限可达到5.0×10-8,相对标准偏差为1.63%。 相似文献
405.
目前运用最为广范的加湿方法是利用浅水盘加湿,根据其加湿原理分析,浅水盘加湿方法一般只能控制在常温以上的湿度。本文介绍一种方法,结合湿度原理在不对设备进行改造的情况下实现了低温高湿的试验应力。同时,反应出国外某些先进设备对试验风险的完善考虑。 相似文献
406.
采用改性粉煤灰对含磷废水进行净化,考察了pH、吸附剂用量、吸附时间和吸附温度对净化效果的影响。结果表明:(1)当pH为9时,磷净化率达到最大值。(2)当改性粉煤灰用量为30g/L时,磷净化率可达99.53%,磷净化后质量浓度为0.91mg/L,达到《污水综合排放标准》(GB8978—1996)中二级标准限值(1.0mg/L);当改性粉煤灰用量为40g/L时,磷净化率可达99.75%,磷净化后质量浓度为0.48mg/L,达到GB8978—1996中一级标准限值(0.5mg/L)。(3)改性粉煤灰对废水中磷的净化速度较快,吸附5min即可使吸附过程达到平衡;进一步提高吸附时间,磷净化率及净化后浓度几乎不再变化。(4)吸附温度对磷净化率的影响较小,当吸附温度为20~40℃时,磷净化率为97.00%~98.62%。(5)改性粉煤灰对磷的吸附等温线较符合Freundlich方程,且1/n=0.374,吸附过程易进行,改性粉煤灰可作为磷的吸附剂用于废水中磷的净化。 相似文献
407.
408.
409.
从稠油罐底泥中回收矿物油 总被引:3,自引:0,他引:3
为了回收稠油罐底泥(简称油泥)中的矿物油并提高油泥焚烧系统的处理能力,分析了辽河油泥的特点,对比传统油泥处理方法的优劣,提出了溶剂萃取-离心分离-稠油热废水洗涤-离心分离技术回收矿物油的工艺路线。实验结果表明:该工艺可回收92.07%的矿物油和56.85%的热能;残渣中矿物油的质量分数小于等于2.00%,热值大于等于5000kJ/kg,不需添加辅助燃料即可焚烧处理。 相似文献
410.
阳离子交换树脂生产中废酸的回收利用及树脂质量控制 总被引:3,自引:0,他引:3
采用 酸套洗工艺代替传统的加水稀释洗涤工艺,成功地解决了阳离子交换树脂生产中废酸的回收利用问题,研究了采用新洗涤工艺后树脂变红的机理和防止对策,结果表明,树脂发红帅微生物的参与而引起的。采以完善洗涤 灭菌措施可防止树脂 ,从而确保了稀酸套洗工艺的顺利实施。 相似文献