Recovery efficiency of the hydrofluorocarbon (HFC‐134a) by activated carbons of different physicochemical properties

The adsorption characteristics of 1,1,1,2‐tetrafluoroethane (HFC‐134a) on activated carbon were investigated to evaluate the recovery efficiency of HFC‐134a by six activated carbons (two granular activated carbons (GAC1 and GAC2), one high‐surface area activated carbon (HAC), and three activated carbon fibers (ACF10, ACF15, and ACF20)). HFC‐134a adsorption on the activated carbons increased with increase in the specific surface area and pore volume of the activated carbon. The differential heat of the HFC‐134a adsorption decreased with increase in the percentage of the micropore volume to the total pore volume. The adsorption model of HFC‐134a on the activated carbon could be based on the Langmuir model. The constant a of the Langmuir plot of HAC and ACF20 is smaller than GAC1 or GAC2 and ACF10 or ACF15, respectively. The constant W_s of HAC has the largest value. The constant a was correlated to the heat of adsorption. It is concluded that the largest amount of HFC‐134a was adsorbed on HAC, and the least amount of interaction occurred between HFC‐134a and the HAC. The amount of HFC‐134a adsorbed on the activated carbons over time was applied to the Sameshima equation. The adsorption rate constant of HFC‐134a on HAC was the largest. The HAC could be suitable for the recovery of HFC‐134a.     

POLICY RELEVANT INFORMATION AND PUBLIC ATTITUDES: IS PUBLIC IGNORANCE A BARRIER TO NONPOINT POLLUTION MANAGEMENT?1

ABSTRACT: This study examines the extent to which knowledge deficits pose a significant barrier to public support for nonpoint pollution management strategies. Such barriers would obtain if all of the following conditions are present: (1) many in the public lack knowledge relevant to those strategies; (2) variations in knowledge are linked only to relatively unchanging personal attributes; and (3) individuals with more knowledge are more likely to support the implementation of management strategies. Each of these conditions is subjected to empirical analysis in this study. The findings reported here derive from a survey of citizens in Spokane, Washington, the site of a major 208 Water Quality Management Program study. The results of the survey indicate that: portions of the public have enough knowledge to evaluate technically based management strategies; sources of public knowledge are sufficiently elastic that both policy area concern and policy relevant knowledge can be elevated in the short run; and both knowledge levels and general attitudes are related to the public's specific water policy preferences. The study concludes that the apparent lack of knowledge among the public is not necessarily a significant barrier to policy implementation, and that support for implementation may be generated through both knowledge enhancement and the tapping of existing political orientations through the placement of emphasis upon the seriousness of water resource problems.