Arsenic stability and mobilization in soil at an amenity grassland overlying chemical waste (St. Helens, UK)

A 6.6 ha grassland, established on a former chemical waste site adjacent to a residential area, contains arsenic (As) in surface soil at concentrations 200 times higher than UK Soil Guideline Values. The site is not recognized as statutory contaminated land, partly on the assumption that mobility of the metalloid presents a negligible threat to human health, groundwater and ecological receptors. Evidence for this is evaluated, based on studies of the effect of organic (green waste compost) and inorganic (iron oxides, lime and phosphate) amendments on As fractionation, mobility, plant uptake and earthworm communities. Arsenic mobility in soil was low but significantly related to dissolved organic matter and phosphate, with immobilization associated with iron oxides. Plant uptake was low and there was little apparent impact on earthworms. The existing vegetation cover reduces re-entrainment of dust-blown particulates and pathways of As exposure via this route. Minimizing risks to receptors requires avoidance of soil exposure, and no compost or phosphate application.     

The phenology of phytoplankton blooms: Ecosystem indicators from remote sensing

Remote sensing offers many advantages in the development of ecosystem indicators for the pelagic zone of the ocean. Particularly suitable in this context are the indicators arising from time series that can be constructed from remotely sensed data. For example, using ocean-colour radiometry, the phenology of phytoplankton blooms can be assessed. Metrics defined in this way show promise as informative indicators for the entire pelagic ecosystem. A simple phytoplankton–substrate model, with forcing dependent on latitude and day number is used to explore the qualitative features of bloom phenology for comparison with the results observed in a suite of 10-year time series of chlorophyll concentration, as assessed by remote sensing, from the Northwest Atlantic Ocean. The model reveals features of the dynamics that might otherwise have been overlooked in evaluation of the observational data.     

Promoting felt responsibility for constructive change and proactive behavior: exploring aspects of an elaborated model of work design

Although new theoretical models that are suggestive of how work design might be used to foster proactive motivation and proactive performance have been proposed, these models need further elaboration and testing if they are to be useful tools for contemporary organizations. Accordingly, we examine the extent to which feelings of responsibility for constructive change is a proactive psychological mechanism that explains how work design characteristics influence constructive change‐oriented behavior and proactive performance. Specifically, we examine job autonomy, position in the organizational hierarchy, access to resources, access to strategy‐related information, and role ambiguity as antecedents to felt responsibility for constructive change (FRCC). We also examine the extent to which feelings of responsibility for constructive change are positively related to voice behavior (i.e., constructive, change‐oriented communication) and continuous improvement (i.e., proactive role performance). Results indicate hierarchical position and access to resources are positively related to FRCC. Results also indicate proactive personality moderates the relationship between access to resources and FRCC and the relationship between access to strategy‐related information and FRCC. Plots of the interactions reveal that these relationships are enhanced for individuals with proactive personalities. The results also indicate that FRCC is positively related to voice behavior and continuous improvement. Perhaps more importantly, the results suggest that FRCC explains the psychological process by which structural and socio‐structural forces influence proactive behavior. The results are discussed as they pertain to updated work design theory and theories of high involvement work systems, job characteristics, and leadership prototypes. Copyright © 2006 John Wiley & Sons, Ltd.     

Crusting of stored dairy slurry to abate ammonia emissions: pilot-scale studies

Storage of cattle slurry is a significant source of ammonia (NH3) emissions. Emissions can be reduced by covering slurry stores, but this can incur significant costs, as well as practical and technical difficulties. In this pilot-scale study, slurry was stored in small tanks (500 L) and the effectiveness of natural crust development for reducing NH3 emissions was assessed in a series of experiments. Also, factors important in crust development were investigated. Measurements were made of crust thickness and specially adapted tank lids were used to measure NH3 emissions. Slurry dry matter (DM) content was the most important factor influencing crust formation, with no crust formation on slurries with a DM content of <1%. Generally, crusts began to form within the first 10 to 20 d of storage, at which time NH3 emission rates would decrease. The formation of a natural crust reduced NH3 emissions by approximately 50%. The type of bedding used in the free stall barn did not influence crust formation, nor did ambient temperature or air-flow rate across the slurry surface. There was a large difference in crust formation between slurries from cattle fed a corn (Zea mays L.) silage-based diet and those fed a grass silage-based diet, although dietary differences were confounded with bedding differences. The inclusion of a corn starch and glucose additive promoted crust formation and reduced NH3 emission. The maintenance of a manageable crust on cattle slurry stores is recommended as a cost-effective means of abating NH3 emissions from this phase of slurry management.     

Behavior of bigeye (<Emphasis Type="Italic">Thunnus obesus</Emphasis>) and skipjack (<Emphasis Type="Italic">Katsuwonus pelamis</Emphasis>) tunas within aggregations associated with floating objects in the equatorial eastern Pacific

The horizontal and vertical movements of bigeye (Thunnus obesus Lowe, 1839) and skipjack (Katsuwonus pelamis Linnaeus, 1758) tunas within large multi-species aggregations associated with moored buoys or a drifting vessel were investigated, using ultrasonic telemetry and archival tags, along with sonar imaging, in the equatorial eastern Pacific Ocean (at 2°S–95°W and 2°N–95°W). Four sets of observations, each consisting of the concurrent monitoring of pairs of skipjack and/or bigeye with implanted acoustic or archival tags, were conducted in May 2002 and 2003. Ultrasonic telemetry data were not collected until 24 h or more after the fish were tagged and released, to avoid any abnormal behavior as a consequence of tagging. The pairs of acoustically tagged bigeye and skipjack, and also the entire aggregations, were primarily upcurrent of the moored buoy and downcurrent of the drifting vessel during the day. At night the aggregations were observed to be more diffuse, and the fish were feeding on organisms of the deep scattering layer. The aggregations returned to positions upcurrent of the buoy or downcurrent of the drifting vessel at dawn, commonly breezing at the surface within cohesive monospecific schools. The bigeye and skipjack had concurrent changes in depth records, occupying significantly greater mean depths at night than during the day, in most cases. When associated with a moored buoy, bigeye depth distributions were deeper during the day and night than those of skipjack, but bigeye depth distributions were shallower during the day and night than those of skipjack when associated with the drifting vessel. Simultaneous depth records of a large and a small bigeye with archival tags associated with a moored buoy also indicated diel changes in depth. The mean depth at night was significantly less than during the day for the larger bigeye, but the mean depth during the day was significantly less than during the night for the smaller bigeye. The mean depths during the day and night were significantly greater for the larger bigeye than the smaller.Electronic Supplementary Material  Supplementary material is available in the online version of this article at http://dx.doi.org/10.1007/s00227-004-1480-xCommunicated by J.P. Grassle, New Brunswick     

Population Declines and Range Contractions among Lowland Farmland Birds in Britain

We used extensive atlas and census data to assess trends in the distribution and population levels of birds on lowland farmland in Britain between the late 1960s and early 1990s. Many species of farmland birds have become less widespread or have declined in numbers, or both, but few have become more wide-spread or have increased. Of the 28 species classified as farmland birds the distributions of 24 contracted between 1970 and 1990. Of the 18 farmland species for which it was possible to assess population change, 15 were less abundant in 1990 than in 1970. Seven of the species were estimated to have undergone population decreases of at least 50%. Farmland species showing the largest population declines tended also to show substantial range contractions. Farmland species underwent an appreciably larger contraction of distribution than species associated with any other habitat. Furthermore, farmland species tended to decrease in abundance, whereas woodland species tended to increase. Population declines among farmland birds became evident in the mid- to late 1970s, a period when several fundamental changes were taking place in British agricultural practices. These included a great reduction in the spring sowing of cereals, a simplification of crop rotations, increased use of chemical pesticides and inorganic fertilizers, and more-intensive grassland management. We suggest that the declines of farmland bird species have been caused or aggravated by this pervasive intensification of agriculture. Existing research on declining farmland birds, however, indicates that there is no single mechanism underlying the population changes. We identify priorities for research, focusing mainly on relationships between bird populations and agricultural practices, but we also recognize a need for a better understanding of the role of predation.