Electrical resistivity tomography as monitoring tool for unsaturated zone transport: an example of preferential transport of deicing chemicals

Non-invasive spatially resolved monitoring techniques may hold the key to observe heterogeneous flow and transport behavior of contaminants in soils. In this study, time-lapse electrical resistivity tomography (ERT) was employed during an infiltration experiment with deicing chemical in a small field lysimeter. Deicing chemicals like potassium formate, which frequently impact soils on airport sites, were infiltrated during snow melt. Chemical composition of seepage water and the electrical response was recorded over the spring period 2010. Time-lapse electrical resistivity tomographs are able to show the infiltration of the melt water loaded with ionic constituents of deicing chemicals and their degradation product hydrogen carbonate. The tomographs indicate early breakthrough behavior in parts of the profile. Groundtruthing with pore fluid conductivity and water content variations shows disagreement between expected and observed bulk conductivity. This was attributed to the different sampling volume of traditional methods and ERT due to a considerable fraction of immobile water in the soil. The results show that ERT can be used as a soil monitoring tool on airport sites if assisted by common soil monitoring techniques.     

Memory dynamics and foraging strategies of honeybees

Summary The foraging behavior of a single bee in a patch of four electronic flower dummies (feeders) was studied with the aim of analyzing the informational components in the choice process. In different experimental combinations of reward rates, color marks, odors and distances of the feeders, the behavior of the test bee was monitored by a computer in real time by several devices installed in each feeder. The test bee optimizes by partially matching its choice behavior to the reward rates of the feeders. The matching behavior differs strongly between stay flights (the bee chooses the feeder just visited) and shift flights (the bee chooses one of the three alternative feeders). The probability of stay and shift flights depends on the reward sequence and on the time interval between successive visits. Since functions describing the rising probability of stay flights with rising amounts of sucrose solution just experienced differ for the four feeders, it is concluded that bees develop feeder-specific memories. The choice profiles of shift flights between the three alternative feeders depend on the mean reward rate of the feeder last visited. Good matching is found after visits to the low-reward feeders and poor matching following departure from the high-reward feeders. These results indicate that bees use two different kinds of memories to guide their choice behavior: a transient short-term working memory that is not feeder-specific, and a feeder-specific long-term reference memory. Model calculations were carried out to test this hypothesis. The model was based on a learning rule (the difference rule) developed by Rescorla and Wagner (1972), which was extended to the two forms of memories to predict this operant behavior. The experiments show that a foraging honeybee learns the properties of a food source (its signals and rewards) so effectively that specific expectations guide the choice behavior. Correspondence to: R. Menzel     

Accumulation of orally administered cadmium by the eel (Anguilla anguilla)

Eels were fed on gammarids (Amphipoda: Crustacea) containing high levels of cadmium for 30 days, then the cadmium distribution in the various organs of the fish was investigated. A retention value was calculated for liver + kidney and for whole-body.     

Second german heavy-metal survey by means of mosses,and comparison of the first and second approach in germany and other european countries

This paper shows the geographic distribution in Germany of iron (Fe), nickel (Ni) and lead (Pb) analyzed in mosses in 1995/96 and compares it with the results of the 1990/91 pilot study within a European moss-monitoring programme. Other elements (As, Cd, Cr, Cu, Ti, V, Zn) are compared on basis of the overall element medians for Germany of the 1990/91 and 1995/96 survey. Samples of Pleurozium schreberi, Scleropodium purum, Hypnum cupressiforme and Hylocomium splendens were taken at a total of 1026 sites. In the 1995/96 monitoring campaign, 95% of the original sites of the 1990/91 study were resampled. The results from 1995/96 display local elevated values and many cases of areas affected by known sources of heavy-metal emissions. The industrialized and urban regions of Germany are shown up clearly by the 1995/96 moss-monitoring results: the Ruhr area, parts of Saarland and Baden-Württemberg, as well as areas in eastern Germany. Relatively low values for many elements were found in large areas of Lower Saxony and Bavaria. A comparison of the results of the 1990/91 and 1995/96 moss-monitoring programmes shows a fall in the concentration of the presented elements (except cadmium, copper and zinc) over the relevant period. Especially in the former GDR, chromium (Cr), iron (Fe), titanium (Ti) and vanadium (V) decreased significantly. This is, firstly, a reflection of the closure of and/or technological improvements to large power plants; secondly it is due to the fact that lignite has given way to other fuels. Vanadium (V) and nickel (Ni), typical constituents of crude oil, also show a decrease in the western part and thus document changes in the type of fuel consumed. The significant fall in lead concentration in 1995/96 as compared to 1990/91 in what used to be East and West Germany probably results from the increasing use of lead-free petrol. A comparison of the median values for 1990/91 and 1995/96 in mosses to the rate of emission of heavy metals in Germany for 1990 and 1995 shows similar trends in the case of elements such as arsenic (As), chromium (Cr), nickel (Ni), and lead (Pb). The comparison of the medians of the elements analyzed for 19 European countries indicates for most of the elements a general tendency to lower values in 1995, except for Lithuania, Netherlands, Portugal, Italy and United Kingdom.     

ANOMALOUS NATURAL SULFATE IN WATER WELLS OF THE GREENBRIER GROUP,WEST VIRGINIA1

ABSTRACT: Many water wells developed in the Middle Mississippian Greenbrier Group of central Greenbrier County, West Virginia, are very productive because of the abundant solution conduits in this karst aquifer. Water from these wells, all of which (with one exception) are clustered in a small area about eight kilometers northwest of Lewisburg, West Virginia, is typically very hard (calcium-magnesium-bicarbonate type). Of 74 wells sampled, eight showed sulfate concentrations ranging from 600 to 1700 mg/l. These wells also showed a much higher than average concentration of calcium, magnesium, chloride, sodium, and, in a few cases, iron. The water from several of these wells was not potable. Previously unpublished work has suggested that dolomite and gypsum dissolution have contributed magnesium and sulfate ions to the ground water. It is also likely that, where sodium, chloride, and iron concentrations are above background, halite dissolution and pyrite oxidation are contributing to the problem. All of these minerals are often associated with the basal waterbearing strata of the Greenbrier Group. In addition, it is possible that the wells are receiving deeply circulating ground waters, via fracture zones, which feed many other well-known sulfur and/or thermal springs in the central Appalachians.