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921.
Unrine JM Tsyusko OV Hunyadi SE Judy JD Bertsch PM 《Journal of environmental quality》2010,39(6):1942-1953
To investigate the role of particle size on the oxidation, bioavailability, and adverse effects of manufactured Cu nanoparticles (NPs) in soils, we exposed the earthworm Eisenia ferida to a series of concentrations of commercially produced NPs labeled as 20- to 40-nm or < 100-nm Cu in artificial soil media. Effects on growth, mortality, reproduction, and expression of a variety of genes associated with metal homeostasis, general stress, and oxidative stress were measured. We also used X-ray absorption spectroscopy and scanning X-ray fluorescence microscopy to characterize changes in chemical speciation and spatial distribution of the NPs in soil media and earthworm tissues. Exposure concentrations of Cu NPs up to 65 mg kg(-1) caused no adverse effects on ecologically relevant endpoints. Increases in metallothionein expression occurred at concentrations exceeding 20 mg kg(-1) of Cu NPs and concentrations exceeding 10 mg kg(-1) of CuSO4. Based on the relationship of Cu tissue concentration to metallothionein expression level and the spatial distribution and chemical speciation of Cu in the tissues, we conclude that Cu ions and oxidized Cu NPs were taken up by the earthworms. This study suggests that oxidized Cu NPs may enter food chains from soil but that adverse effects in earthworms are likely to occur only at relatively high concentrations (> 65 mg Cu kg(-1) soil). 相似文献
922.
This study describes the spatial variability in nitrogen (N) transformation within a constructed wetland (CW) treating domestic effluent. Nitrogen cycling within the CW was driven by settlement and mineralization of particulate organic nitrogen and uptake of NO3-. The concentration of NO3- was found to decrease, as the delta15N-NO3- signature increased, as water flowed through the CW, allowing denitrification rates to be estimated on the basis of the degree of fractionation of delta15N-NO3-. Estimates of denitrification hinged on the determination of a net isotope effect (eta), which was influenced byprocesses that enrich or deplete 15NO3- (e.g., nitrification), as well as the rate constants associated with the different processes involved in denitrification (i.e., diffusion and enzyme activity). The influence of nitrification on eta was quantified; however, it remained unclear how eta varied due to variability in denitrification rate constants. A series of stable isotope amendment experiments was used to further constrain the value of eta and calculate rates of denitrification, and nitrification, within the wetland. The maximum calculated rate of denitrification was 956 +/- 187 micromol N m(-2) h(-1), and the maximum rate of nitrification was 182 +/- 28.9 micromol N m(-2) h(-1). Uptake of NO3- was quantitatively more important than denitrification throughoutthe wetland. Rates of N cycling varied spatially within thewetland, with denitrification dominating in the downstream deoxygenated region of the wetland. Studies that use fractionation of N to derive rate estimates must exercise caution when interpreting the net isotope effect. We suggest a sampling procedure for future natural abundance studies that may help improve the accuracy of N cycling rate estimates. 相似文献
923.
This work was undertaken to analyze nutrient contents of vegetation in an alpine meadow—Tungnath, North-West Himalaya, India.
The study pertains to the uptake, transfer and release of four main macronutrients (organic carbon, total nitrogen, total
potassium and total phosphorus) in grazed (exposed to extensive grazing by cattles) and ungrazed (grazing completely prohibited)
communities. Mineral concentration was recorded higher for the ungrazed sites compared to the grazed sites, and maximum standing
state of nutrients was found in roots. Belowground compartment (roots) contributed maximum share of mineral elements to soil.
Litter nutrients release was low because of low microbial activity and continuous removal of phytomass. Observations reveal
that there was very little amount of nutrient release from phytomass and vegetation in alpine are very poor source of mineral
recycling. Low transfer rate of minerals from one compartment to other is adequate for greater amount of these minerals that
are translocated back into the storage organs. A small proportion get removed through rain splash or through the removal of
hay during grazing as relatively high release rates in ungrazed sites when compared to grazed sites was observed. This translocation
can be considered as an important adaptation in alpine plants for survival during adverse environmental conditions, against
all types of biotic pressures and also for regeneration in the forthcoming growing season. 相似文献
924.
The toxicity and bioaccumulation of two heavy metals—lead (Pb) and cadmium (Cd)—in a semi-aquatic plant, Colocasia esculenta (L. Schott), from a synthetic heavy metal solution were studied. Young plants of equal size were grown hydroponically in shallow raceways containing Hoagland medium amended with 20, 40, and 60 mg l?1 of Pb and 2, 4, and 6 mg l?1 of Cd. The medium containing heavy metals was allowed to flow through the raceways with a change in influent heavy metal solution on every 5th day. The experiment was continued for 20 days. A set of control raceways—one comprised of nutrient medium with heavy metal supplements, devoid of plants, and another with the plants and nutrient medium having no metal supplement—was also simultaneously run. Chlorosis in the leaves was the prominent toxicity symptom observed due to Pb and Cd on the test plants. A significant decrease in the relative growth, biomass productivity, and total chlorophyll content were noticed in the plants with an increase in concentration of metal supplement in the solution and exposure time. Both metals accumulated to higher concentrations in the roots than in shoots, suggesting that the metals were bound to the root cells and their translocation to the leaves was limited. The results of the 20-day-long experiments indicate that from a phytoremediation perspective, C. esculenta is a promising plant species for remediation of wastewater polluted with lower concentrations of Pb and Cd. 相似文献
925.
By means of environmental education, teachers are supposed to intervene in pupils’ awareness and concern of environmental
issues. Teachers’ environmental attitudes, however, have rarely been studied. We analysed 367 German pre- and in-service teachers’
environmental attitudes for their structure and socio-economic correlates within the frame of a European project. Thus, we
retrieved for adults the two-dimensional model of ecological values (2-MEV) presented for adolescents by Bogner and Wiseman
(Sci Educ Int 15(1):27–48, 2004). For the two domains, Preservation and Utilisation, the psychometric structure was confirmed and discriminative correlations
with age, gender and teaching subject were unveiled. Further research is needed to deduce the implications for teaching practice. 相似文献
926.
927.
928.
A laboratory-scale bioremediation unit was designed, built and tested for the bio-removal of several Direct textile dyes.
Four experiments were carried out to assess the efficiency of the bioremediation unit using Aspergillus niger fungal strain. Three commonly used Direct dyes and textile dyes mixture (simulated effluent: Direct brown, Direct violet,
Direct green) were tested in this study. The strain of A. niger was efficient in the removal of the three Direct dyes. The decolorization percentages of the dyes after 24 h of incubation
were 56.2, 51.7, and 95.4% for Direct brown, Direct green, Direct violet dyes, respectively. The percentages increased up
to 79.4, 86.4, and 96.7% after 72 h of incubation for the same dyes, respectively. The results also showed that the fungal
strain reduced the chemical oxygen demand values of simulated dye effluents from 165 to 564 mg/l with most of the dyes. The
assessment of bioremediation products on biomodel was conducted using a fresh water fish. The liver and brain of Nile tilapia
were tested to evaluate the expression of genes coding for several proteins related to stress such as metallothioneins (MTs),
cytochrome P450 (CYP450), and heat shock proteins (HSPs). To assess the alterations in the gene expression, ten animals from
each group were killed after 4 weeks of treatment. The results revealed significant increases in the brain and hepatic mRNA
levels of all stress protein genes MT, CYP450, Hsp70a, b, and Hsp47 in the fish groups treated with industrial Direct violet,
green, and brown dye water. Exposure of tilapia to bioremediation products after treatment with A. niger fungi reduced the over-expression of the stress protein genes in the brain and liver tissues. 相似文献
929.
S. O. Asagba G. E. Eriyamremu J. O. T. Emudainohwo I. Okoro 《The Environmentalist》2010,30(3):260-266
The activities of some oxidative enzymes (aldehyde oxidase, AO, EC 1.2.3.1; xanthine oxidase, XO, EC 1.17.3.2; sulphite oxidase,
SO, EC 1.8.3.1; and monoamine oxidase, MO, EC 1.4.3.4) were investigated in the liver, gill, kidney, brain and muscle of a
variety of African catfish (Clarias gariepinus) after 7 and 21 days of exposure to 0.1, 0.2 and 0.4 ppm cadmium (Cd) in ambient water. MO, SO and AO activities were significantly
(p < 0.05) decreased in a dose-dependent manner in the liver, kidney and gill in the 7-day Cd-exposed fish when compared to
control. Conversely, brain MO, AO and SO activities were significantly (p < 0.05) elevated in a dose-dependent manner in the same fishes relative to control. As in the 7-day Cd-exposed fish, the
activities of MO, AO and SO were significantly (p < 0.05) decreased in a dose-dependent manner in the gill, kidney and liver of catfish exposed for 21 days. Same is true for
XO in these organs after both duration of exposure, except in the liver where no significant change was observed relative
to control. The inhibition of these oxidative enzymes in the liver, gill and kidney of catfish may interfere with their biotransformation
function, and ultimately the survival of the fish may be compromised. 相似文献
930.