Fluorescence behaviour of Zn and Ni complexes of humic acids from different sources

Conventional fluorescence spectroscopy in the excitation, emission and synchronous scan modes and three-dimensional fluorescence spectroscopy in the form of an excitation-emission matrix (EEM) of fluorescence intensity as a function of excitation and emission wavelengths have been applied to the study of three humic acids (HAs) extracted from soil (SHA), peat (PHA) and compost (CHA) and their interaction products with Zn(II) and Ni(II) ions. Fluorescence spectra of HAs appear to be related to the nature and origin of the sample. A strong reduction of intensity of all peaks is observed in the spectra of HAs-metal complexes as compared to those of untreated HAs. Ni(II) exhibits greater quenching ability than Zn(II). Fluorescence quenching measured for complexes of HAs at increasing Ni(II) concentrations was linearly correlated with metal ion concentration. The different capacity to interact with metal ions showed by various HAs is attributed to their different molecular complexity.     

Characterization of black crusts developed on historic stones with diverse mineralogy under different air quality environments

Environmental Science and Pollution Research - Black crusts (BCs) are one of the most critical alteration forms found on stones belonging to architectural heritage. Since they could be considered...     

Calcitic-based stones protection by a low-fluorine modified methacrylic coating

Environmental Science and Pollution Research - Atmospheric pollutants, such as NOx, SO2, and particulate matter, together with water percolation inside the stone pores, represent the main causes of...     

Gathering new knowledge from existing monitoring dataset of Campania marine coastal area (Southern Italy)

Environmental Science and Pollution Research - In this study we propose, a multi-step strategy of selection and characterization of long-term dataset of contaminant concentrations in different...     

Uptake and toxicity of Cr(III) in celery seedlings

The present study shows that in celery Cr(III) induces deleterious effects on seedling development and morphology, and a number of metabolic responses related to stress. Exogenous CrCl3 from 0.01 to 1 mM increasingly inhibited seed germination and hypocotyl elongation, or completely blocked it (10 mM), while the root apparatus was dramatically damaged even at the lowest dose. Seedlings took up exogenous Cr(III) in a dose-dependent manner, roots being the site of major metal accumulation; translocation towards the hypocotyl and cotyledonary leaves was also detected. Either total or chlorophyll a content was significantly reduced by chromium as low as 0.01 mM. A large accumulation of free and, to a lesser extent, conjugated polyamines occurred in all segments of treated plants. A dose-dependent relationship linking actual amounts of Cr(III) recovered in the entire seedling or organ and the respective polyamine titre was evidenced. Free putrescine, in particular, was the polyamine exhibiting the highest rate of increase, and cotyledonary leaves the organ where the major response occurred. A marked increase in ubiquitin-protein conjugates after Cr(III) treatment was also observed, particularly in roots. Thus, the study suggests for the first time a possible relationship between ubiquitination and Cr(III)-stress. The putative function of polyamines as a stress response, and the recruitment of the ubiquitin pathway to remove damaged or aberrant proteins which might have been produced in metal-treated seedlings are discussed.     

Fetal aortic root dilation: a prenatal feature of the Loeys-Dietz syndrome

Loeys-Dietz syndrome is a recently described autosomal dominant disorder with cardinal manifestations in cardiovascular, craniofacial and skeletal systems. Although the disease has some phenotypic overlap with Marfan syndrome, the disease, that is caused by mutations in the transforming growth factor beta-receptor 1 (TGFBR1) or transforming growth factor beta-receptor 2 (TGFBR2) genes, presents many distinctive features and a particularly aggressive cardiovascular course. We describe prenatal identification of an aortic root aneurysm in a fetus of 19 week of gestation as an early marker of Loeys-Dietz syndrome. Copyright © 2006 John Wiley & Sons, Ltd.     

The role of motorized boats in fishers’ productivity in marine protected versus non-protected areas in Davao Gulf,Philippines

Environment, Development and Sustainability - The Philippine fisheries sector continues to play a critical role in the livelihood of coastal households; however, the country’s fisheries...     

Impacts of the deforestation driven by agribusiness on urban population and economic activity in the Dry Chaco of Argentina

Agriculture expansion oriented to global market has changed the relation between population and deforestation in South America. Actually, the population dynamic in an agricultural frontier turned into a consequence of deforestation (rather than the cause). For Dry Chaco of Argentina during the period 1991–2001, we explore the impacts of deforestation over urban population and employment dynamics in small- and medium-size urban centers. We used deforestation maps from remote sensing data and demographic information from the national census. We found a positive relation between population growth and deforestation. Additionally, urban centers in a context of new and active deforestation stages generate more jobs than in a context of advanced stages. Based on our results, we suggest a boom and bust pattern. Agriculture expansion and deforestation generate transient jobs and benefits, but in a long-run perspective, positive impacts are uncertain.     

A retrospective statistical review of deaths owing to migration through the southeasternmost land borders of the European Union,Greece 2000–14

The land borders of Evros, Greece, have been a common entry point for undocumented migrants on their way to Europe through Turkey. Adverse conditions, however, have resulted in many human casualties over the years. On the Greek side, 334 cadavers were retrieved between 2000 and 2014. This study provides a detailed forensic account of the humanitarian disaster in Evros to create an official scientific record of the situation. It showcases the gravity of the global issue of migration relating to health and mortality, and encourages communication and continual improvement of the approach and patterns of practices surrounding the subject. A retrospective statistical research review was conducted of border‐related fatalities between 2000 and 2014, assessing the age and gender of victims, the cause of death, the location of bodies, identification rates, and country of origin. Age ranged generally from 24 to 29 years, but infants and children were among the deceased.