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491.
Chlorinated paraffins (CPs) are straight chain hydrocarbons that are produced as complex mixtures and are used as flame retardants
and paint additives. These mixtures are extremely difficult to characterize using conventional chromatographic methods, as
conventional gas chromatography results in unresolved complex chromatograms that preclude the identification and quantification
of individual congeners or any reasonable assessment of the average carbon chain length. Carbon chain length is an important
parameter for assessing physical properties and the toxicity of these materials. We have modified and improved a previously
published gas chromatography–flame ionization detector method that uses Pd catalyst held in the gas chromatograph injector
to simultaneously dechlorinate the CPs and separate the resulting alkanes. In addition, we have adapted this method to gas
chromatography–mass spectrometry. Dehalogenation of other compounds was also studied with this system to investigate potential
application to other complex halogenated mixtures. 相似文献
492.
Cruceru I Iancu V Petre J Badea IA Vladescu L 《Environmental monitoring and assessment》2012,184(5):2783-2795
A simple, sensitive and reliable HPLC-FLD method for the routine determination of 4-nonylphenol, 4-NP and 4-tert-octylphenol, 4-t-OP content in water samples was developed. The method consists in a liquid–liquid extraction of the target analytes with dichloromethane at pH 3.0–3.5 followed by the HPLC-FLD analysis of the organic extract using a Zorbax Eclipse XDB C8 column, isocratic elution with a mixed solvent acetonitrile/water 65:35, at a flow rate of 1.0 mL/min and applying a column temperature of 40°C. The method was validated and then applied with good results for the determination of 4-NP and 4-t-OP in Ialomi?a River water samples collected each month during 2006. The concentration levels of 4-NP and 4-t-OP vary between 0.08–0.17 μg/L with higher values of 0.24–0.37 μg/L in the summer months for 4-NP, and frequently <0.05 μg/L but also between 0.06–0.09 μg/L with higher values of 0.12–0.16 μg/L in July and August for 4-t-OP and were strongly influenced by sesonial and anthropic factors. The method was also applied on samples collected over 2 years 2007 and 2008 from urban wastewaters discharged into sewage or directly into the rivers by economic agents located in 30 Romanian towns. Good results were obtained when the method was used for analysis of effluents discharged into surface waters by 16 municipal wastewater treatment plants, during the year 2008. 相似文献
493.
Kharroubi A Gargouri D Baati H Azri C 《Environmental monitoring and assessment》2012,184(6):4001-4014
Concentrations of selected heavy metals (Cd, Pb, Zn, Cu, Mn, and Fe) in surface sediments from 66 sites in both northern and
eastern Mediterranean Sea–Boughrara lagoon exchange areas (southeastern Tunisia) were studied in order to understand current
metal contamination due to the urbanization and economic development of nearby several coastal regions of the Gulf of Gabès.
Multiple approaches were applied for the sediment quality assessment. These approaches were based on GIS coupled with chemometric
methods (enrichment factors, geoaccumulation index, principal component analysis, and cluster analysis). Enrichment factors
and principal component analysis revealed two distinct groups of metals. The first group corresponded to Fe and Mn derived
from natural sources, and the second group contained Cd, Pb, Zn, and Cu originated from man-made sources. For these latter
metals, cluster analysis showed two distinct distributions in the selected areas. They were attributed to temporal and spatial
variations of contaminant sources input. The geoaccumulation index (I
geo) values explained that only Cd, Pb, and Cu can be considered as moderate to extreme pollutants in the studied sediments. 相似文献
494.
Impact of socioeconomic development on ecosystem services and its conservation strategies: a case study of Shandong Province,China 总被引:1,自引:0,他引:1
Ecosystems and their components provide a lot of benefits for the welfare of human beings. Coupled with increasing socioeconomic
development, most of the rapidly developing and transitional countries and regions have been experiencing dramatic land use
changes. This has resulted in a large amount of forestland, grassland, and wetland being occupied as residential and industrial
land or reclaimed for arable land, which in turn results in a sharp deterioration of ecosystem services around the world.
Shandong Province, an economically powerful province of China, was chosen as a case study in order to capture the impact of
socioeconomic development on ecosystem services. By way of the study, land uses and their changes were categorized between
1980 and 2006, and the ecosystem services capital and changes of 111 counties of Shandong Province in different phases were
evaluated, as well as the total ecosystem services capital, followed by the zoning of ecosystem services function region of
Shandong Province. We found that the counties in mountainous areas and wetlands, where generally the prefectural-level cities
are located with a rapid socioeconomic development, experienced a successive deterioration of ecosystem services especially
during the 2000s. Finally, three conservation strategies for managing and improving ecosystem services were proposed and discussed
with the aim of achieving coordinate and sustainable development of the socioeconomy, environment, and ecosystems not only
in Shandong Province but also in other provinces of China, as well as in other developing and transitional countries and regions. 相似文献
495.
Chen B Pan Y Wang J Fu Z Zhang Y Zhou Y 《Environmental monitoring and assessment》2012,184(6):3545-3556
Evenly distributed sampling design is generally considered as an efficient sampling design. It is widely used in sampling
for the environmental survey. In this paper, we present a novel method for generating N evenly distributed samples within a given irregular polygon via simulating the movements of some ideal homogeneous point
charges. Initially, charges are randomly put into the sampling region; then, they are freed and held orderly; and after enough
runs, the charges will finally reach a stable state with all of them having a zero resultant force and velocity; and so they
distribute evenly within the region. Their layout can thus be considered as an evenly distributed sampling design. The main
advantages of this method are: (1) it is easy to understand and implement; (2) it is efficient in both running and generating
better designs. Analysis and experimental results indicate that this method is an efficient and robust method for generating
even sampling designs for 2D polygonal sampling region. 相似文献
496.
Smederevac-Lalić M Pešić R Cvejić S Simonović P 《Environmental monitoring and assessment》2012,184(5):2633-2646
The multidisciplinary socio-economic study of fisheries in the bordering part of the Danube River between Serbia and Croatia (at the following sites: Apatin, Ba?ka Palanka, Ba?ko Novo Selo, Bezdan, and Sombor) that was performed in order to investigate various aspects of fish resource utilization (management, policy of protection and exploitation of freshwater fishery resources, present fisheries legislation, catch statistics), was realized during 2004 and 2005. Data were collected via survey with a structured interview. Socio-economic circumstances, together with ecological factors, have had an influence on the fish stock and number of commercial fishermen. Awareness of the occurring problems, both economic and ecological ones, is apparent, regardless of whether it is assessed in the field of commercial or recreational fishing. Fishery sector in Serbia is in a prolonged process of transition, with the enforcement of fishing regulations, but also the lack of control that leaves space for illegal commercial fishing. The statements, consciousness, experience and behavior of commercial fishermen represent a good basis for planning the sustainable development of fishing in this section of the Danube River. 相似文献
497.
The objective of this study is to assess the risk of insufficient water supply posed by high-turbidity water. Several phenomena
can pose risks to the sufficiency of a water supply; this study concerns risks to water treatment plants from particular properties
of rainfall and raw water turbidity. High-turbidity water can impede water treatment plant operations; rainfall properties
can influence the degree of soil erosion. Thus, water turbidity relates to rainfall characteristics. Exceedance probabilities
are presented for different rainfall intensities and turbidities of water. When the turbidity of raw water is higher than
5,000 NTU, it can cause operational problems for a water treatment plant. Calculations show that the turbidity of raw water
at the Ban-Sin water treatment plant will be higher than 5,000 NTU if the rainfall intensity is larger than 165 mm/day. The
exceedance probability of high turbidity (turbidity >5,000 NTU) in the Ban-Sin water treatment plant is larger than 10%. When
any water treatment plant cannot work regularly, its ability to supply water to its customers is at risk. 相似文献
498.
As facile “environmental media”, the outdoor dust may reflect the changes of contaminants in environment more promptly. In
the present study, selected organochlorine contaminants (OCs) include hexachlorocyclohexanes (HCHs), dichlorodiphenyltrichloroethanes
(DDTs), hexachlorobenzene (HCB), and pentachlorobenzene (PeCB) were detected in 20 outdoor dust samples collected from Xinxiang
City. The concentrations of ΣHCHs, ΣDDTs, HCB, and PeCB in dust were in the range of 0.18–5.05 ng/g dry weight, 0.44–13.50 ng/g
dry weight, 0.13–51.61 ng/g dry weight and ND-0.74 ng/g dry weight, respectively. Long-range transport, historical use, and
recent impact of impure pesticides might be the main sources of OCs in the outdoor dust. The results of this study indicated
that impure pesticide application maybe an important source of DDTs and HCB in the environment. 相似文献
499.
Sakizadeh M Esmaeili Sari A Abdoli A Bahramifar N Hashemi SH 《Environmental monitoring and assessment》2012,184(5):3231-3237
The Anzali Wetland is one of the most important ecosystems in the north of Iran, and parts of it were registered as a Ramsar
site in 1975. However, even though, due to many problems, including eutrophication produced by inflow of excess nutrients
and organic materials, the wetland was also listed on the Montreux Record indicating the need to take urgent remedial action.
This study was conducted to study the levels of polychlorinated biphenyls (PCBs) and total mercury (THg) in two fish species
(Esox lucius and Carassius auratus) as bio-indicators of the ecosystem condition in eastern part of Anzali Wetland. The sampling was carried out in six different
periods between years 2009 and 2010. The results showed that the amounts of PCBs in the muscle of northern pike were below
the detection limit of gas chromatography, whereas the average concentration in goldfish was 0.449 mg/kg wet weight. Some
possible reasons for the higher levels of PCBs in goldfish in comparison with pike have been discussed. No significant (p < 0.05) correlation was observed between PCBs and biological factors (weight, length, lipid content) for both species. On
the other hand, the mean concentration of THg in the muscle of pike and goldfish were 182.22 and 75.27 ng/g dry weight, respectively.
Although these concentrations were below US-EPA criterion for human consumption (0.3 mg/kg), it pointed up a significant deterioration
of the ecosystem condition during the past years. Finally, statistical analysis revealed a significant correlation between
THg with weight and an insignificant correlation with length for pike specimens. 相似文献
500.
A sensitive spectrophotometric method has been developed for determination of ametryn in agricultural samples. The proposed
method was based on reaction with pyridine and further coupling with sulfanilic acid to form a colored product. The absorbance
was measured at 400 nm with a molar absorptivity of 2.1 × 105 L mol−1 cm−1. The method shows a linear range from 0.2–20 μg mL−1 with limit of detection and limit of quantification 0.16 and 0.54 μg mL−1, respectively. The method has been successfully applied to the determination of ametryn in sugarcane juice and commercial
formulations after separation of ametryn from triazine herbicides based on solvent extraction. Recovery values were found
to be in the range of 96.0 ± 0.2% to 98.4 ± 0.1%. 相似文献