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71.
Paolo Cabras Alberto Angioni Vincenzo L. Garau Marinella Melis Filippo. M. Pirisi Franco Cabitza 《Journal of environmental science and health. Part. B》2013,48(6):1189-1199
Abstract Residues of three pesticides (dimethoate, parathion, and pyrazophos) in two artichoke cultivars, Masedu and Spinoso sardo, were investigated. The amount of pesticides in artichokes was greatly affected by the head shape. In the case of the calix‐shaped Masedu artichoke, the residues in whole heads at commercial ripening were on average about twice higher than those of the pagoda‐shaped Spinoso sardo artichoke. In the heart this ratio was 4 to 42 times greater. Residue decay rates were very fast, mainly owing to the dilution effect due to head growth. 相似文献
72.
73.
Azo-dyes photocatalytic degradation in aqueous suspension of TiO2 under solar irradiation 总被引:3,自引:0,他引:3
Augugliaro V Baiocchi C Prevot AB García-López E Loddo V Malato S Marcí G Palmisano L Pazzi M Pramauro E 《Chemosphere》2002,49(10):1223-1230
The photodegradation of two common and very stable azo-dyes, i.e. methyl-orange (C14H14N3SO3Na) and orange II (C16H11N2SO4Na), is reported. The photocatalytic oxidation was carried out in aqueous suspensions of polycrystalline TiO2 irradiated by sunlight. Compound parabolic collectors, installed at the “Plataforma Solar de Almería” (PSA, Spain) were used as the photoreactors and two identical reacting systems allowed to perform photoreactivity runs for the two dyes at the same time and under the same irradiation conditions. The disappearance of colour and substrates together with the abatement of total organic carbon content was monitored. The main sulfonate-containing intermediates were found to be in lower number in respect to those obtained under artificial irradiation. In particular there were no more evidence of the presence of hydroxylated transients. The dependence of dye photooxidation rate on: (i) substrate concentration; (ii) catalyst amount; and (iii) initial pH was investigated. The influence of the presence of strong oxidant species (H2O2, S2O82−) and some ions (Cl−, SO42−) on the process was also studied. 相似文献
74.
A sensitivity analysis (SA) was conducted on the analytical models considered in the risk-based corrective-action (RBCA) methodology
of risk analysis, as developed by the American Society for Testing of Materials (ASTM), to predict a contaminant‘s concentration
in the affected medium at the point of human exposure. These models are of interest because evaluations regarding the best
approach to contaminated site remediation are shifting toward increased use of risk-based decision, and the ASTM RBCA methodology
represents the most effective and internationally widely used standardized guide for risk assessment process. This paper identifies
key physical and chemical parameters that need additional precision and accuracy consideration in order to reduce uncertainty
in models prediction, thereby saving time, money and engineering effort in the data collection process. SA was performed applying
a variance-based method to organic contaminants migration models with reference to soil-to-groundwater leaching ingestion
exposure scenario. Results indicate that model output strongly depends on the organic-carbon partition coefficient, organic-carbon
content, net infiltration, Darcy velocity, source-receptor distance, and first-order decay constant. 相似文献
75.
Roberto Mancinelli Vincenzo Di Felice Shafiqul Bari Emanuele Radicetti Enio Campiglia 《国际发展与全球生态学杂志》2018,25(1):35-46
The research was based on a comparative study of three representative rural areas (Dovras, Larissa, and Messapia) in Greece. Remote sensing data were collected (maps, aerial photographs) for the landscape analysis and elaborated using GIS linked with economic and social parameters regarding land use. By using a selected core set of landscape indicators, this research aims at providing a useful tool for assessing agroecosystem management at territorial level and hopefully assist decision-making for the promotion of sustainability. The selected tool showed that the study area of Messapia presented the highest level of environmental sustainability, while the area of Dovras showed the best combination of agricultural productivity and landscape management. Results showed that the ecoregions of Dovras, Larissa, and Messapia presented a landscape composed of important ecological function areas in the percentages of 40%, 15%, and 70%, respectively, and of cultivated areas in the percentages of 55%, 71.19%, and 19.75%, respectively. 相似文献
76.
The pattern of genetic variability of two species of Mediterranean gobiids was compared, with reference to their different
life history traits (Aphia minuta paedomorphic and pelagic; Gobius
niger metamorphosed and benthic). The aim was to evaluate how different life histories can affect the genetic structure in these
marine teleosts. The study was carried out on populations of both species sampled in the western Mediterranean and in the
Adriatic Sea. Seven restriction endonucleases were used for the RFLP analysis of a mitochondrial DNA segment comprising the
NADH dehydrogenase subunits 3, 4L and 4. The results highlighted two different patterns of genetic variation, a weak genetic
structure in A. minuta and population subdivision in G. niger. These observations may be explained not only in terms of the different dispersal capabilities of these species, but also
considering that A. minuta is an abbreviate iteroparous spawner while G. niger is a protracted iteroparous spawner. Because abbreviate iteroparity is a reproductive strategy selected in stable environments
with high resource availability, Pliocene and Pleistocene climate oscillations may have represented factors that negatively
influenced the reproductive success of A. minuta, producing demographic fluctuations and bottlenecks, as suggested by the mismatch distribution analysis. The weak genetic
structure of A. minuta populations seems to be therefore due to a more recent re-colonization of the Mediterranean basin after a severe population
decline, rather than to the high vagility of this pelagic goby. 相似文献
77.
We investigate turbulent mixing in a tidally driven, mid-latitude, shallow-water basin. The study is carried out numerically
at a laboratory-scale, using large-eddy simulation. We compared the results of the simulation with those of a correspondent
purely oscillatory flow (Stokes boundary layer). The effect of rotation on the flow dynamics is twofold. First, rotation gives
rise to a mean spanwise flow that concurs to redistribute the turbulent energy among the Reynolds stresses, in particular
between the horizontal directions, thus increasing the mixing across the water column and thickening the layer where developed
turbulence is observable. Second, the presence of the horizontal component of the background vorticity (latitude effect) breaks
the symmetry between the two semi-cycles of the oscillation, since turbulence results suppressed/enhanced during the first/second
semi-cycle. These two effects significantly modify the turbulent characteristics with respect to the purely oscillating flow,
although the mechanisms that generates turbulence present similar features. The qualitative agreement between our results
and some measurements carried out in two sites with characteristics similar to the case analyzed suggests that the outcomes
here provided may be of general use for the analysis of mid-latitude, neutrally stratified, shallow-water basins mainly driven
by semi-diurnal tidal currents. 相似文献
78.
The Allee effect (the positive relationship between population growth rate and population size) is a constraint of some animal populations at low numbers, which increases their likelihood of extinction because of a decrease in reproduction and/or survival. We were able to demonstrate that the Allee effect can be the result of a mortality increase affecting floaters (i.e. dispersing individuals able to enter as breeders in the reproductive population when a breeding territory or a potential mate – owner of a suitable breeding territory – becomes available). Previously, potential mechanisms underlying Allee effects were always related to the breeding portion of a population only. In contrast, our understanding of or solutions to population declines due to the Allee effects can reside elsewhere, away from breeding territories. 相似文献
79.
Sofo A Scopa A Dumontet S Mazzatura A Pasquale V 《Journal of environmental science and health. Part. B》2012,47(7):653-659
The effect of four triazinyl-sulfonylurea herbicides (cinosulfuron, prosulfuron, thifensulfuron methyl, triasulfuron) on soil microbial biomass, soil respiration, metabolic activity, metabolic quotient, and some enzymatic activities (acid and alkaline phosphatase, β-glucosidase, arylsulphatase, and fluorescein diacetate hydrolysis) were monitored under controlled conditions over 30 days. The herbicides were applied at the normal field dose (FD) and at ten-fold (10 FD) the field dose, in order to mimic a long term toxic effect. The measured soil microbial parameters showed that the FD had slight effects on soil microflora, while at 10 FD the tested herbicides exerted a stronger detrimental effect on soil microbial biomass and its biochemical activities. 相似文献
80.
Serena Felline Ernesto Mollo Alessandra Ferramosca Vincenzo Zara Francesco Regoli Stefania Gorbi Antonio Terlizzi 《Marine Biology》2014,161(6):1275-1283
Biological invasions are deemed as one of the most severe threats to biodiversity and can result in huge economic impacts on natural resources. Many studies have assessed structural changes caused by the introduction of nonindigenous species, but urgent questions remain to be answered about the complex indirect effects of invasive pests on marine biodiversity at the species and ecosystem level. Previous investigations focusing on the biological invasion by Caulerpa racemosa in the Mediterranean indicated that the lipophilic algal metabolite caulerpin accumulates in the tissues of the native edible white sea bream Diplodus sargus feeding on the exotic alga. The level of caulerpin in D. sargus has been thus used as an indicator of the trophic exposure of the fish to the seaweed and related with adverse effects on the fish health. In the present study, we show that the C. racemosa-based diet can also alter muscle fatty acids composition in the white sea bream by reducing the percentage of polyunsaturated fatty acids of the n-3 and n-6 series, such as eicosapentaenoic (C20:5), docosahexaenoic (C22:6) and arachidonic acids (C20:4). This represents both a real threat to the health of fish unable to biosynthesize these essential fatty acids and an impoverishment of an important source of essential fatty acids for human nutrition, which helps to prevent cardiovascular diseases, diabetes, hepatic steatosis, cancer and neurological disorders. On the whole, this work sheds light on an unexplored and critical aspect of biological invasions with implication on the health of both humans and the environment. 相似文献