全文获取类型
收费全文 | 18341篇 |
免费 | 142篇 |
国内免费 | 111篇 |
专业分类
安全科学 | 361篇 |
废物处理 | 626篇 |
环保管理 | 2659篇 |
综合类 | 3759篇 |
基础理论 | 4959篇 |
环境理论 | 6篇 |
污染及防治 | 3907篇 |
评价与监测 | 982篇 |
社会与环境 | 1270篇 |
灾害及防治 | 65篇 |
出版年
2018年 | 693篇 |
2017年 | 666篇 |
2016年 | 626篇 |
2015年 | 207篇 |
2014年 | 206篇 |
2013年 | 959篇 |
2012年 | 520篇 |
2011年 | 1151篇 |
2010年 | 732篇 |
2009年 | 853篇 |
2008年 | 1029篇 |
2007年 | 1320篇 |
2006年 | 435篇 |
2005年 | 416篇 |
2004年 | 372篇 |
2003年 | 479篇 |
2002年 | 450篇 |
2001年 | 479篇 |
2000年 | 333篇 |
1999年 | 221篇 |
1998年 | 175篇 |
1997年 | 146篇 |
1996年 | 179篇 |
1995年 | 177篇 |
1994年 | 201篇 |
1993年 | 180篇 |
1992年 | 183篇 |
1991年 | 181篇 |
1990年 | 208篇 |
1989年 | 194篇 |
1988年 | 166篇 |
1987年 | 163篇 |
1986年 | 148篇 |
1985年 | 165篇 |
1984年 | 158篇 |
1983年 | 162篇 |
1982年 | 160篇 |
1981年 | 163篇 |
1980年 | 149篇 |
1979年 | 145篇 |
1978年 | 142篇 |
1977年 | 129篇 |
1976年 | 136篇 |
1975年 | 114篇 |
1974年 | 142篇 |
1973年 | 125篇 |
1972年 | 125篇 |
1971年 | 105篇 |
1970年 | 106篇 |
1967年 | 116篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
831.
H. Barndõk M. Peláez C. Han W. E. Platten III P. Campo D. Hermosilla A. Blanco D. D. Dionysiou 《Environmental science and pollution research international》2013,20(6):3582-3591
This study reports the synthesis and characterization of composite nitrogen and fluorine co-doped titanium dioxide (NF-TiO2) for the removal of contaminants of concern in wastewater under visible and solar light. Monodisperse anatase TiO2 nanoparticles of different sizes and Evonik P25 were assembled to immobilized NF-TiO2 by direct incorporation into the sol–gel or by the layer-by-layer technique. The composite films were characterized with X-ray diffraction, high-resolution transmission electron microscopy, environmental scanning electron microscopy, and porosimetry analysis. The photocatalytic degradation of atrazine, carbamazepine, and caffeine was evaluated in a synthetic water solution and in an effluent from a hybrid biological concentrator reactor (BCR). Minor aggregation and improved distribution of monodisperse titania particles was obtained with NF-TiO2-monodisperse (10 and 50 nm) from the layer-by-layer technique than with NF-TiO2?+?monodisperse TiO2 (300 nm) directly incorporated into the sol. The photocatalysts synthesized with the layer-by-layer method achieved significantly higher degradation rates in contrast with NF-TiO2-monodisperse titania (300 nm) and slightly faster values when compared with NF-TiO2-P25. Using NF-TiO2 layer-by-layer with monodisperse TiO2 (50 nm) under solar light irradiation, the respective degradation rates in synthetic water and BCR effluent were 14.6 and 9.5?×?10?3?min?1 for caffeine, 12.5 and 9.0?×?10?3?min?1 for carbamazepine, and 10.9 and 5.8?×?10?3?min?1 for atrazine. These results suggest that the layer-by-layer technique is a promising method for the synthesis of composite TiO2-based films compared to the direct addition of nanoparticles into the sol. 相似文献
832.
Edge TA El-Shaarawi A Gannon V Jokinen C Kent R Khan IU Koning W Lapen D Miller J Neumann N Phillips R Robertson W Schreier H Scott A Shtepani I Topp E Wilkes G van Bochove E 《Journal of environmental quality》2012,41(1):21-30
Canada's National Agri-Environmental Standards Initiative sought to develop an environmental benchmark for low-level waterborne pathogen occurrence in agricultural watersheds. A field study collected 902 water samples from 27 sites in four intensive agricultural watersheds across Canada from 2005 to 2007. Four of the sites were selected as reference sites away from livestock and human fecal pollution sources in each watershed. Water samples were analyzed for Campylobacter spp., Salmonella spp., Escherichia coli O157:H7, Cryptosporidium spp., Giardia spp., and the water quality indicator E. coli. The annual mean number of pathogen species was higher at agricultural sites (1.54 ± 0.07 species per water sample) than at reference sites (0.75 ± 0.14 species per water sample). The annual mean concentration of E. coli was also higher at agricultural sites (491 ± 96 colony-forming units [cfu] 100 mL(-1)) than at reference sites (53 ± 18 cfu 100 mL(-1)). The feasibility of adopting existing E. coli water quality guideline values as an environmental benchmark was assessed, but waterborne pathogens were detected at agricultural sites in 80% of water samples with low E. coli concentrations (<100 cfu 100 mL(-1)). Instead, an approach was developed based on using the natural background occurrence of pathogens at reference sites in agricultural watersheds to derive provisional environmental benchmarks for pathogens at agricultural sites. The environmental benchmarks that were derived were found to represent E. coli values lower than geometric mean values typically found in recreational water quality guidelines. Additional research is needed to investigate environmental benchmarks for waterborne pathogens within the context of the "One World, One Health" perspective for protecting human, domestic animal, and wildlife health. 相似文献
833.
Pratt C Walcroft AS Tate KR Ross DJ Roy R Reid MH Veiga PW 《Journal of environmental quality》2012,41(1):80-87
Soil methane (CH(4)) biofilters, containing CH(4)-oxidizing bacteria (methanotrophs), are a promising technology for mitigating greenhouse gas emissions. However, little is known about long-term biofilter performance. In this study, volcanic pumice topsoils (0-10 cm) and subsoils (10-50 cm) were tested for their ability to oxidize a range of CH(4) fluxes over 1 yr. The soils were sampled from an 8-yr-old and a 2-yr-old grassed landfill cover and from a nearby undisturbed pasture away from the influence of CH(4) generated by the decomposing refuse. Methane was passed through the soils in laboratory chambers with fluxes ranging from 0.5 g to 24 g CH(4) m(-3) h(-1). All topsoils efficiently oxidized CH(4). The undisturbed pasture topsoil exhibited the highest removal efficiency (24 g CH(4) m(-3) h(-1)), indicating rapid activation of the methanotroph population to the high CH(4) fluxes. The subsoils were less efficient at oxidizing CH(4) than the topsoils, achieving a maximum rate oxidation rate of 7 g CH(4) m(-3) h(-1). The topsoils exhibited higher porosities; moisture contents; surface areas; and total C, N, and available-P concentrations than the subsoils, suggesting that these characteristics strongly influence growth and activity of the CH(4)-oxidizing bacteria. Soil pH values and available-P levels gradually declined during the trial, indicating a need to monitor chemical parameters closely so that adjustments can be made when necessary. However, other key soil physicochemical parameters (moisture, total C, total N) increased over the course of the trial. This study showed that the selected topsoils were capable of continually sustaining high CH(4) removal rates over 1 yr, which is encouraging for the development of biofilters as a low-maintenance greenhouse gas mitigation technology. 相似文献
834.
Switchgrass biochar affects two aridisols 总被引:1,自引:0,他引:1
Ippolito JA Novak JM Busscher WJ Ahmedna M Rehrah D Watts DW 《Journal of environmental quality》2012,41(4):1123-1130
The use of biochar has received growing attention because of its ability to improve the physicochemical properties of highly weathered Ultisols and Oxisols, yet very little research has focused on its effects in Aridisols. We investigated the effect of low or high temperature (250 or 500°C) pyrolyzed switchgrass () biochar on two Aridisols. In a pot study, biochar was added at 2% w/w to a Declo loam (Xeric Haplocalcids) or to a Warden very fine sandy loam (Xeric Haplocambids) and incubated at 15% moisture content (by weight) for 127 d; a control (no biochar) was also included. Soils were leached with 1.2 to 1.3 pore volumes of deionized HO on Days 34, 62, 92, and 127, and cumulative leachate Ca, K, Mg, Na, P, Cu, Fe, Mn, Ni, Zn, NO-N, NO-N, and NH-N concentrations were quantified. On termination of the incubation, soils were destructively sampled for extractable Cr, Cu, Fe, K, Mg, Mn, Na, Ni, P, Zn, NO-N, and NH-N, total C, inorganic C, organic C, and pH. Compared with 250°C, the 500°C pyrolysis temperature resulted in greater biochar surface area, elevated pH, higher ash content, and minimal total surface charge. For both soils, leachate Ca and Mg decreased with the 250°C switchgrass biochar, likely due to binding by biochar's functional group sites. Both biochars caused an increase in leachate K, whereas the 500°C biochar increased leachate P. Both biochars reduced leachate NO-N concentrations compared with the control; however, the 250°C biochar reduced NO-N concentrations to the greatest extent. Easily degradable C, associated with the 250°C biochar's structural make-up, likely stimulated microbial growth, which caused NO-N immobilization. Soil-extractable K, P, and NO-N followed a pattern similar to the leachate observations. Total soil C content increases were linked to an increase in organic C from the biochars. Cumulative results suggest that the use of switchgrass biochar prepared at 250°C could improve environmental quality in calcareous soil systems by reducing nutrient leaching potential. 相似文献
835.
S. J. Herrmann J. A. Turner J. S. Carsella D. W. Lehmpuhl D. R. Nimmo 《Environmental management》2012,50(6):1111-1124
Aquatic bryophytes, Hygrohypnum ochraceum, were deployed “in situ” at 14 sites in the Fountain Creek Watershed, spring and fall, 2007 to study selenium (Se) accumulation. Dissolved, total, and pore (sediment derived) water samples were collected and water quality parameters determined while plants were exposed to the water for 10?days. There was a trend showing plant tissue-Se uptake with distance downstream and we found a strong correlation between Se in the water with total hardness in both seasons. There was a modest association between Se-uptake in plants with hardness in the spring of 2007 but not the fall. Plants bioconcentrated Se from the water by a factor of 5.8?×?103 at Green Mountain Falls and 1.5?×?104 at Manitou Springs in the fall of 2007. Both are examples of the bioconcentration abilities of the plants, primarily in the upper reaches of the watershed where bioconcentration factors were highest. However, the mean minima and maxima of Se in the plants in each of the three watershed segments appeared similar during both seasons. We found direct relationships between the pore and dissolved Se in water in the spring (R 2?=?0.84) and fall (R 2?=?0.95) and dissolved Se and total hardness in the spring and fall (R 2?=?0.92). The data indicate that H. ochraceum was a suitable indicator of Se bioavailability and Se uptake in other trophic levels in the Fountain Creek Watershed based on a subsequent study of Se accumulation in fish tissues at all 14 sites. 相似文献
836.
Simulating Land-Cover Change in Montane Mainland Southeast Asia 总被引:6,自引:0,他引:6
We used the conversion of land use and its effects (CLUE-s) model to simulate scenarios of land-cover change in Montane mainland
southeast Asia (MMSEA), a region in the midst of transformation due to rapid intensification of agriculture and expansion
of regional trade markets. Simulated changes affected approximately 10 % of the MMSEA landscape between 2001 and 2025 and
16 % between 2001 and 2050. Roughly 9 % of the current vegetation, which consists of native species of trees, shrubs, and
grasses, is projected to be replaced by tree plantations, tea, and other evergreen shrubs during the 50 years period. Importantly,
4 % of this transition is expected to be due to the expansion of rubber (Hevea brasiliensis), a tree plantation crop that may have important implications for local-to-regional scale hydrology because of its potentially
high water consumption in the dry season. 相似文献
837.
Groninger JW 《Environmental management》2012,49(4):833-845
Foreign and domestic government agencies and other international organizations pursue reforestation programs in rural upper
watershed areas of Afghanistan over the past decade to alleviate poverty, combat the insurgency and rehabilitate a depleted
forest resource base. Popular programs incorporate cash-for-work to conduct hillside terracing, check dam construction and
tree-planting for nut production, fuel wood, timber, dune stabilization, and erosion abatement. Programmatic approaches have
varied as a function of accessibility, security and local objectives. Uncertain land tenure and use rights, weak local environmental
management capacity, and a focus on agricultural production to meet immediate needs limit interest, nationally and locally.
Unreliable security, a lack of high quality tree planting stock, limited technical knowledge and coordination among government
agencies, and poor security hamper program expansion. Reforestation success would be most likely where these issues are least
acute. The Afghan government should focus on supporting community based natural resource management, developing and disseminating
improved conservation tree nursery strategies, and promoting watershed management schemes that incorporate forestry, range
management and agronomic production. Reforestation practitioners could benefit from the human and material resources now present
as part of the international war effort. Successes and failures encountered in Afghanistan should be considered in order to
address similar problems in insecure regions elsewhere when reforestation may help reverse environmental degradation and contribute
to broader social stabilization efforts. 相似文献
838.
Relationships Between Nitrogen Transformation Rates and Gene Abundance in a Riparian Buffer Soil 总被引:1,自引:0,他引:1
Lin Wu Deanna L. Osmond Alexandria K. Graves Michael R. Burchell Owen W. Duckworth 《Environmental management》2012,50(5):861-874
Denitrification is a critical biogeochemical process that results in the conversion of nitrate to volatile products, and thus is a major route of nitrogen loss from terrestrial environments. Riparian buffers are an important management tool that is widely utilized to protect water from non-point source pollution. However, riparian buffers vary in their nitrate removal effectiveness, and thus there is a need for mechanistic studies to explore nitrate dynamics in buffer soils. The objectives of this study were to examine the influence of specific types of soluble organic matter on nitrate loss and nitrous oxide production rates, and to elucidate the relationships between these rates and the abundances of functional genes in a riparian buffer soil. Continuous-flow soil column experiments were performed to investigate the effect of three types of soluble organic matter (citric acid, alginic acid, and Suwannee River dissolved organic carbon) on rates of nitrate loss and nitrous oxide production. We found that nitrate loss rates increased as citric acid concentrations increased; however, rates of nitrate loss were weakly affected or not affected by the addition of the other types of organic matter. In all experiments, rates of nitrous oxide production mirrored nitrate loss rates. In addition, quantitative polymerase chain reaction (qPCR) was utilized to quantify the number of genes known to encode enzymes that catalyze nitrite reduction (i.e., nirS and nirK) in soil that was collected at the conclusion of column experiments. Nitrate loss and nitrous oxide production rates trended with copy numbers of both nir and 16s rDNA genes. The results suggest that low-molecular mass organic species are more effective at promoting nitrogen transformations than large biopolymers or humic substances, and also help to link genetic potential to chemical reactivity. 相似文献
839.
Rubber and pulp plantations represent a double threat to Hainan's natural tropical forests 总被引:1,自引:0,他引:1
Hainan, the largest tropical island in China, belongs to the Indo-Burma biodiversity hotspot and harbors large areas of tropical forests, particularly in the uplands. The Changhua watershed is the cradle of Hainan's main river and a center of endemism for plants and birds. The watershed contains great habitat diversity and is an important conservation area. We analyzed the impact of rubber and pulp plantations on the distribution and area of tropical forest in the watershed, using remote sensing analysis of Landsat images from 1988, 1995 and 2005. From 1988 to 1995, natural forest increased in area (979-1040?sq?km) but decreased rapidly (763?sq?km) over the next decade. Rubber plantations increased steadily through the study period while pulp plantations appeared after 1995 but occupied 152?sq?km by 2005. Rubber and pulp plantations displace different types of natural forest and do not replace one another. Because pulp is not as profitable as rubber and existing pulp processing capacity greatly exceeds local supply, considerable pressure exists on remaining upland forests. We recommend for future management that these plantation forests be reclassified as 'industrial', making a clear policy distinction between natural and industrial forestry. Additionally, the local government should work to enforce existing laws preventing forest conversion on marginal and protected areas. 相似文献
840.
Irritant gases in concentrations that occur in polluted atmospheres might play a role in the degranulation and histamine release processes of mast cells in lung tissue. To test this hypothesis, young rats weighing 140-150 g were exposed to 1 ppm nitrogen dioxide for 2 hr. One group was killed immediately, and another group 24-27 hr after exposure. A third group was exposed to 0.5 ppm nitrogen dioxide for 4 hr and killed immediately. Animals serving as controls were placed for 1 hr into the exposure chamber ventilated with ambient air. Standard histological preparations were made after Carnoy’s fixative and subsequent staining with toluidine blue. The mast cells of the control animals appeared relatively intact with no evidence of disorientation. The cells of the animals exposed to NO2 and sacrificed immediately revealed rupture and loss of cytoplasmic granules with some disorientation. These changes were observed in the pleura, bronchi, and surrounding tissue with the effects more marked in the mediastinum. The mast cells of exposed animals sacrificed about 24-27 hr after discontinuing the exposure showed in some cases a combination of ruptured and intact cells with a predominance of the latter, and in other cases could not be differentiated from the controls. These findings indicate that 24 hr or more are required to reverse the acute effects of NO2 inhalation. The toxicological implications will be discussed. The release of granular substances in the lung tissue when NO2 is inhaled signifies the onset of an acute inflammation. 相似文献