Removal kinetics of phosphorus from synthetic wastewater using basic oxygen furnace slag

Removal kinetics of phosphorus through use of basic oxygen furnace slag (BOF-slag) was investigated through batch experiments. Effects of several parameters such as initial phosphorus concentration, temperature, BOF-slag size, initial pH, and BOF-slag dosage on phosphorus removal kinetics were measured in detail. It was demonstrated that the removal process of phosphorus through BOF-slag followed pseudo-first-order reaction kinetics. The apparent rate constant (k_obs) significantly decreased with increasing initial phosphorus concentration, BOF-slag size, and initial pH, whereas it exhibited an opposite trend with increasing reaction temperature and BOF-slag dosage. A linear dependence of k_obs on total removed phosphorus (TRP) was established with k_obs = (3.51 ± 0.11) × 10^− 4 × TRP. Finally, it was suggested that the Langmuir–Rideal (L–R) or Langmuir–Hinshelwood (L–H) mechanism may be used to describe the removal process of phosphorus using BOF-slag.     

Removal kinetics of phosphorus from synthetic wastewater using basic oxygen furnace slag

Removal kinetics of phosphorus through use of basic oxygen furnace slag(BOF-slag)was investigated through batch experiments. Effects of several parameters such as initial phosphorus concentration, temperature, BOF-slag size, initial p H, and BOF-slag dosage on phosphorus removal kinetics were measured in detail. It was demonstrated that the removal process of phosphorus through BOF-slag followed pseudo-first-order reaction kinetics. The apparent rate constant(kobs) significantly decreased with increasing initial phosphorus concentration, BOF-slag size, and initial p H, whereas it exhibited an opposite trend with increasing reaction temperature and BOF-slag dosage.A linear dependence of kobson total removed phosphorus(TRP) was established with kobs=(3.51 ± 0.11) × 10- 4× TRP. Finally, it was suggested that the Langmuir–Rideal(L–R)or Langmuir–Hinshelwood(L–H) mechanism may be used to describe the removal process of phosphorus using BOF-slag.     

Characteristics of phosphorus chemistry and its geographical distribution in the Haihe River valley,North China

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Quantitative structure - activity study on the reductivedehalogenation potency of the halogenated aromatics

Ｑｕａｎｔｉｔａｔｉｖｅｓｔｒｕｃｔｕｒｅ－ａｃｔｉｖｉｔｙｓｔｕｄｙｏｎｔｈｅｒｅｄｕｃｔｉｖｅｄｅｈａｌｏｇｅｎａｔｉｏｎｐｏｔｅｎｃｙｏｆｔｈｅｈａｌｏｇｅｎａｔｅｄａｒｏｍａｔｉｃｓＨｕａｎｇＱｉｎｇｇｕｏ；ＷａｎｇＬｉａｎｓｈｅｎｇ；Ｈａｎ...     

苏南典型河段磷的分布及释放特性研究

通过测定常州典型河段河水和底泥中的磷含量,同时分析了磷在不同底泥颗粒中含量分布的变化,阐述了河流中磷的分布和转移趋势。结果表明:河水中的磷含量通常低于底泥间隙水中的磷含量,但当河流发生富营养化后,底泥中的磷大量向上层水体释放,使得河水中的磷含量不断增加。底泥有效磷与总磷含量之间没有明显相关性,而与底泥间隙水的磷含量之间存在着交换平衡。底泥颗粒以2μm~50μm的粒级为主,即以细砂和粉砂质有机-无机聚合体矿物颗粒为主。磷在底泥颗粒中的含量随着底泥粒径的增大而减少,且粒径越大的颗粒对磷的吸附能力越弱,其中的磷向外释放的可能性越大。     

城镇餐饮泔水离心脱水试验研究

简要介绍了城市餐饮泔水的来源、基本特征及目前主要处理技术方法,提出了餐饮泔水无害资源化新工艺。对提出的工艺中泔水离心脱水工序进行了试验研究,并得出最佳离心参数:时间5min、转速3200rmin。     

微纳米气泡/UV/K2S2O8协同处理模拟垃圾渗沥液

以垃圾渗沥液中的主要污染物冰乙酸、正丁酸、正己酸和氨组成的混合物为处理对象,采用微纳米气泡联合紫外灯活化过硫酸盐法处理模拟垃圾渗沥液,考察了反应时间、过硫酸钾投加量、pH、紫外灯功率、微纳米气泡进气量对污染物去除效果的影响。结果表明：微纳米气泡对紫外灯活化过硫酸盐法有显著的协同作用。当反应时间为180 min、过硫酸钾投加量为4 g·L⁻¹、pH=6、紫外灯功率为10 W、微纳米气泡进气量为30 mL·min⁻¹时,污染物的去除效果最佳,COD去除率为60.68%,TOC去除率为48.05%,氨氮去除率为42.1%。自由基淬灭实验结合EPR表征结果表明,羟基自由基和硫酸根自由基为降解过程中主要的活性物质。溶液中无机碳含量增加,说明废水中有机物分解为二氧化碳和水。     

Long-term study of heavy metal pollution in the northern Hangzhou Bay of China: temporal and spatial distribution,contamination evaluation,and potential ecological risk

Environmental Science and Pollution Research - Coastal ecosystem is vulnerable to heavy metal contamination. The northern Hangzhou Bay is under intensifying impact of anthropogenic activities. To...     

An evolutionary analysis of corruption in the process of collecting environmental tax in China

Environmental Science and Pollution Research - Considering the bargaining power of enterprises, this paper distinguishes between “Offering Bribes Voluntarily” (OBV) and “Offering...     

Effect of composite amendments on physicochemical properties of copper tailings repaired by herbaceous plants

Environmental Science and Pollution Research - Phytoremediation is considered to be the most environmentally friendly green restoration technology for dealing with mine waste. Adding amendments can...