Removal of copper ions and dissolved phenol from water using micellar-enhanced ultrafiltration with mixed surfactants

A laboratory study was conducted to evaluate the effects of composition and concentration of mixed anionic/nonionic surfactants on the efficiency of a micellar-enhanced ultrafiltration (MEUF) operation in removing metal ions/organic solutes from aqueous solutions. Based on the analysis of surface tensions and micelle sizes, it was found that for mixed sodium dodecylsulfate (SDS)/Triton X-100 surfactants, the critical micelle concentration (cmc) was significantly lower than that of SDS and mixed micelles formed. The mixed surfactant system was then applied in a cross-flow mode of MEUF, in which the concentration polarization can be neglected, to remove Cu2+ from aqueous solutions. With a surfactant concentration of 10 mM, the Cu2+ rejection was negligible by using pure Triton X-100 and increased with increasing SDS mole fraction with a value as high as 85%, which suggests that the rejection of Cu2+ was due to the electrostatic attraction between Cu2+ and SDS. Furthermore, pronounced Cu2+ rejection was obtained for a 5 mM SDS solution, which was attributable to a decrease in the cmc of SDS by the existence of Cu2+. When the MEUF technique was applied to remove Cu2+ and phenol simultaneously from aqueous solutions, the Cu2+ rejection was slightly enhanced in the presence of phenol. However, the rejection of phenol was comparatively low, approximately 27%, which may be caused by its relatively hydrophilic characteristic.     

Selective leaching of valuable metals from waste printed circuit boards

This study was carried out to recover valuable metals from the printed circuit boards (PCBs) of waste computers. PCB samples were crushed to smaller than 1 mm by a shredder and initially separated into 30% conducting and 70% nonconducting materials by an electrostatic separator. The conducting materials, which contained the valuable metals, were then used as the feed material for magnetic separation, where it was found that 42% of the conducting materials were magnetic and 58% were nonmagnetic. Leaching of the nonmagnetic component using 2 M H2SO4 and 0.2 M H2O2 at 85 degrees C for 12 hr resulted in greater than 95% extraction of Cu, Fe, Zn, Ni, and Al. Au and Ag were extracted at 40 degrees C with a leaching solution of 0.2 M (NH4)2S2O3, 0.02 M CuSO4, and 0.4 M NH4OH, which resulted in recovery of more than 95% of the Au within 48 hr and 100% of the Ag within 24 hr. The residues were next reacted with a 2 M NaCl solution to leach out Pb, which took place within 2 hr at room temperature.     

基于3S技术的地质灾害易损性面评价研究

以等面积法作为基本手段,结合3S(GIS、RS、GPS)技术探讨地质灾害易损性面评价的实现方法。提出了为实现易损性面评估而确立的评价对象的分类方法、空间数据库的建设方法、基于空间数据库的空间分析方法以及信息的集成方法。最后探讨了在GIS环境下的数据可视化表达方式和实现地质灾害易损性面评价的一般操作流程。     

废钻井液固化实验研究

利用经实验筛选的固化剂配方对废钻井液进行了固化处理的室内配方研究。结果表明,经该固化剂配方处理后的固结材料在水中浸泡5d后的浸出液在色度、化学需氧量、pH值、石油类、悬浮物含量和重金属含量等指标方面可达到国家《污水综合排放标准》(GB8978-1996)中的二级标准。     

循环经济的过程和工作重点

循环经济分为3个连续的阶段或环节：生产阶段、消费阶段和废旧物品再制造阶段。在生产阶段促进清洁技术的开发勺应用是实施循环经济的根本举措。当前实施循环经济的重点是：在宏观经济中实施循环经济；在宏观经济方针政策中体现循环经济原则、可持续发展原则和环境保护原则；将保护环境的基本国策纳入进出口政策；以循环经济的原则规划、建设、改造现存的化学工业同区。     

交通事故再现技术研究现状与发展趋势

道路交通事故再现不仅是交通事故责任鉴定和原因分析的重要方法,也是交通事故防治的重要内容。在详细介绍国内外事故再现计算机仿真技术的基础上,分析目前事故再现系统开发中事故现场数据采集技术、碰撞前后速度估算的技术、碰撞过程进行模拟的虚拟现实技术的研究现状与存在的问题,提出进一步优化的方向,进而达到完善交通事故模拟再现的目的。最后指出我国交通事故再现技术进一步研究的内容和发展趋势。     

商贸市场火灾风险评估方法

通过对典型商贸市场的实地调研,依据历年商贸市场火灾事故统计数据,采用将统计方法与专家评分相结合的方法,运用系统安全及模糊数学的相关理论,提出了商贸市场火灾风险评估方法,从而为商贸市场的安全管理及火灾风险评价提供了切实可行的参考依据。     

防护用品质量管理的发展趋势

据最新研究表明．用户的满意程度和企业的盈利能力与产品和服务的质量紧密相关。较高的产品质量和服务质量，能使用户满意，同时也能维持较高的价格。因此，质量改进方案通常会增加企业的盈利能力。     

Water Use by Thermoelectric Power Plants in the United States1

Abstract: Thermoelectric power generation is responsible for the largest annual volume of water withdrawals in the United States although it is only a distant third after irrigation and industrial sectors in consumptive use. The substantial water withdrawals by thermoelectric power plants can have significant impacts on local surface and ground water sources, especially in arid regions. However, there are few studies of the determinants of water use in thermoelectric generation. Analysis of thermoelectric water use data in existing steam thermoelectric power plants shows that there is wide variability in unitary thermoelectric water use (in cubic decimeters per 1 kWh) within and among different types of cooling systems. Multiple‐regression models of unit thermoelectric water use were developed to identify significant determinants of unit thermoelectric water use. The high variability of unit usage rates indicates that there is a significant potential for water conservation in existing thermoelectric power plants.     

乌鲁木齐市燃煤点源现状分析

对乌鲁木齐市燃煤点派数量、耗煤量、污染物的排放量以及在各功能区的分布分别进行了统计分析，对污染物的排放量在不同高度空间的分布也进行了统计分析，从而得出了确切的结论并提出了相应的建议。