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961.
962.
响应曲面法优化电化学氧化技术处理染料废水 总被引:2,自引:0,他引:2
采用IR和XRD等手段对自制磷钼酸铁(FePMo12)杂多酸进行表征,表明杂多阴离子具有Keggin结构。将FePMo12负载于修饰后的分子筛上制备FePMo12/APTES-4A催化剂填充于电化学反应器中,考察电化学氧化体系对酸性大红3R染料废水的脱色效果,其脱色率高于二维电化学反应器。利用Box-Behnken中心组合实验设计及响应面(RSM)分析,以pH值,板间距,槽电压,曝气量为实验因素,建立了以酸性大红3R的脱色率为响应值的二次多项式回归模型。研究表明,当电解时间为60 min时,曝气量0.05 m3/h、pH为2、板间距3.0 cm、槽电压11.0 V,在此条件下色度去除率可达69.4%,模型预测值与实验值能很好地吻合。方差分析结果表明,槽电压和pH、pH和曝气量的交互作用对响应值具有显著性影响。 相似文献
963.
采用好氧/缺氧连续流砂过滤器中试实验研究深度处理北京某污水处理厂二级出水。实验结果表明,当连续流砂过滤器好氧段聚合氯化铝投量为20 mg/L,缺氧段碳源投量为32 mg/L时,COD、NH+4-N、TN和TP的平均去除率分别为34.77%、86.54%、66.94%和84.10%,最终出水均达到北京市新(改、扩)建城镇污水处理厂排放A标准(DB11/890-2012)。克隆文库法分析石英砂表面生物膜中的细菌群落结构表明,其优势菌群为β-proteobacteria,其中大部分能以废水中碳源为电子供体还原硝酸盐。 相似文献
964.
965.
Perfluoroalkyl acids (PFAs), one kind of emerging contaminants, have attracted great attentions in recent years. However, the study about their bioaccumulation mechanism remains scarce. In this research, the bioaccumulation of six kinds of PFAs in water flea Daphnia magna was studied. The uptake rates of PFAs in D. magna ranged from 178 to 1338 L kg?1 d?1, and they increased with increasing perfluoroalkyl chain length; the elimination rates ranged from 0.98 to 2.82 d?1. The bioaccumulation factors (BAFs) of PFAs ranged from 91 to 380 L kg?1 in wet weight after 25 d exposure; they increased with increasing perfluoroalkyl chain length and had a significant positive correlation with the n-octanol/water partition coefficients (log Kow) of PFAs (p < 0.05). This indicated that the hydrophobicity of PFAs plays an important role in their bioaccumulation. The BAFs almost kept constant when the PFA concentrations in aqueous phase increased from 1 to 10 μg L?1. Scenedesmus subspicatus, as the food of D. magna, did not significantly affect the bioaccumulation of PFAs by D. magna. Furthermore, the body burden of PFAs in the dead D. magna was 1.08–2.52 times higher than that in the living ones, inferring that the body surface sorption is a main uptake route of PFAs in D. magna. This study suggested that the bioaccumulation of PFAs in D. magna is mainly controlled by their partition between organisms and water; further research should be conducted to study the intrinsic mechanisms, especially the roles of protein and lipid in organisms. 相似文献
966.
967.
成都市生态城市建设的路径设计 总被引:5,自引:0,他引:5
文章结合成都市自然资源的优势和特点,依据生态原理的基本思想,从城市河流生态的保护与建设;成都绿化的生态建设与城市生态社区示范建设;城乡融合生态系统的基本设计;成都郊县市生态农业、生态聚落的建设和生态建设总体布局与功能分区等五个方面进行了具体的分析,提出了相关的设计路径和措施。 相似文献
968.
Evaluating Controlling Factors to Ali/(Ca + Mg) Molar Ratio in Acidic Soil Water, Southern and Southwestern China: Multivariate Approach 总被引:2,自引:0,他引:2
Guo JH Zhang XS Vogt RD Xiao JS Zhao DW Xiang RJ Luo JH 《Environmental monitoring and assessment》2007,129(1-3):321-329
Ali/(Ca + Mg) molar ratio in soil water has been used as an indicator to the effects of acid deposition on terrestrial ecosystems.
However, the main factors controlling this ratio have not been well documented in southern and southwestern China. In this
study, we presented the variation in inorganic aluminum (Ali) and Ali/(Ca + Mg) molar ratio in different sites and soil horizons based on two to three years monitoring data, and evaluated the
main factors controlling Ali/(Ca + Mg) molar ratio using principle component analysis (PCA) and partial least square (PLS) regression. Monitoring data
showed although Ali/(Ca + Mg) molar ratios in most soil water were lower than assumed critical 1.0, higher molar ratios were found in some soil
water at TSP and LXH site. Besides acid loading, both soil properties and soil water chemistry affected the value of Ali/(Ca + Mg) molar ratio in soil water. Partial least square (PLS) indicated that they had different relative importance in
different soil horizons. In A-horizon, soil aluminum saturation (AlS) had higher influence on Ali/(Ca + Mg) molar ratio than soil water chemistry did; higher soil aluminum saturation (AlS) led to higher Ali/(Ca + Mg) molar ratio in soil water. In the deeper horizons (i.e., B1-, B2- and BC-horizon), inorganic aluminum (Ali) in soil water had more and more important role in regulating Ali/(Ca + Mg) molar ratio. On regional scale, soil aluminum saturation (AlS) as well as cation exchange capacity (CEC) was the
dominant factor controlling Ali/(Ca + Mg) molar ratio. This should be paid enough attention on when making regional acid rain control policy in China. 相似文献
969.
X. A. Zuo X. Y. Zhao H. L. Zhao Y. R. Guo T. H. Zhang J. Y. Cui 《Environmental monitoring and assessment》2010,164(1-4):29-42
To assesses the effect of geomorphology, topography, and vegetation changes on spatial pattern of soil organic carbon (C) and total nitrogen (N) in sand dunes, we used the quantitative methods to examine the spatial heterogeneity of vegetation cover, soil organic C, and total N in an 11-year naturally restored mobile dune (RMD11) and a 20-year naturally restored mobile dune (RMD20) that had been fenced to exclude grazing in Horqin Sandy Land, northern China. Our results showed that the vegetation cover, plant density, species number and diversity, soil organic C, and total N increased from RMD11 to RMD20 and increased from the 50 × 50-m plot (crest) to the 100 × 100-m plot (slope) in each dune. Geostatistical analysis showed that the spatial structural variance accounted for the largest proportion of the total sample variance in vegetation cover, soil organic C, and total N in each dune plot. Calculated spatial autocorrelation ranges of vegetation cover, soil organic C, and total N increased from RMD11 to RMD20, indicating that longer time since vegetation restoration results in a more homogeneous distribution of vegetation cover, soil organic C, and total N in sand dunes. In addition, the spatial continuity of vegetation cover, soil organic C, and total N decreased from the 50 × 50-m plot (crest) to the 100 × 100-m plot (slope) in each dune. These results suggest that the spatial distribution of soil organic C and total N in sand dunes is associated closely with geomorphic position related to the dune crest and slope, relative elevation of sampling site, and vegetation cover. Understanding the principles of this relationship between them may guide strategies for the conservation and management of semiarid dune ecosystems. 相似文献
970.
Dynamics of aeolian desertification and its driving forces in the Horqin Sandy Land,Northern China 总被引:2,自引:0,他引:2
Han-chen Duan Tao Wang Xian Xue Shu-lin Liu Jian Guo 《Environmental monitoring and assessment》2014,186(10):6083-6096
Aeolian desertification is one of the most serious environmental and socioeconomic problems in arid, semi-arid, and dry subhumid zones. Understanding desertification processes and causes is important to provide reasonable and effective control measures for preventing desertification. With satellite remote sensing images as data source to assess the temporal and spatial dynamics of desertification from 1975 to 2010 in the Horqin Sandy Land, dynamic changes of aeolian desertification were detected using the human–machine interactive interpretation method. The driving factors of local desertification were analyzed based on natural and socioeconomic data. The results show that aeolian desertified land in the study area covered 30,199 km2 in 2010, accounting for 24.1 % of the study area. The total area of aeolian desertified land obviously expanded from 30,884 km2 in 1975 to 32,071 km2 in 1990, and gradually decreased to 30,199 km2 in 2010; aeolian desertified land represented an increasing trend firstly and then decreased. During the past 35 years, the gravity centers of desertified lands that are classified as extremely severe and severe generally migrated to the northeast, whereas those that are moderate and slight migrated to the northwest. The migration distance of severely desertified land was the largest, which indicated the southern desertified lands were improved during the last few decades. In addition, the climatic variation in the past 35 years has been favorable to desertification in the Horqin Sandy Land. Aeolian desertified land rapidly expanded from 1975 to 1990 under the combined effects of climate changes and unreasonable human activities. After the 1990s, the main driving factors responsible for the decrease in desertification were positive human activities, such as the series of antidesertification and ecological restoration projects. 相似文献