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111.
Chemical forms of Zn, Ni, Cu, and Pb in municipal sewage sludge were investigated by adding humus soil to sludge and by
performing sequential extraction procedures. In the final sludge mixtures, Zn and Ni were mainly found in Fe/Mn oxide-bound (F3) and
organic matter/sulfide-bound (F4) forms. For Zn, exchangeable (F1), carbonate-bound (F2), and F3 forms were transformed to F4 and
residual forms (F5). For Ni, F1 and F2 forms were transformed to F1, F2, and F3 forms. Both Cu and Pb were strongly associated with
the stable forms F4 and F5. For Cu, F2 and F3 forms were major contributors, while for Pb, F3 and F4 forms were major contributors to
F5. Humus soil dosage and pH conditions in the sludge were strongly correlated with the forms of heavy metals. Five forms were used
to evaluate metal mobilities in the initial and final sludge mixtures. The mobilities of the four heavy metals studied decreased after 28
days. The metal mobilities in the final sludge mixtures were ranked in the following order: Ni > Zn > Cu = Pb. Leaching tests showed
that the mobilities of Zn and Ni in lower pH conditions (pH 4) were higher than those in higher pH conditions (pH 8). 相似文献
112.
113.
介绍了中国石化济南分公司硫黄回收联合装置安全环保停工的过程,在硫黄回收联合装置停工前,研究讨论各装置停工密闭吹扫的流程及方法,并确定各装置停工吹扫的顺序、注意事项和前期准备工作。在各装置停工吹扫过程中,严格按照停工方案,采取了分装置吹扫,该装置吹扫完毕后立即加盲板隔离,最后放火炬公用系统采取倒吹扫,实现了装置停工密闭吹扫,达到了各装置停工酸性气系统吹扫不放火炬的要求。 相似文献
114.
115.
建立了用活性炭吸附,丙酮解吸,HP-NNOWAX毛细管柱分离,气相色谱法测定大气中正戊烷和正已烷的方法.二种有机物在一定浓度范围内标准曲线线性良好,对实际样品进行分析,正戊烷加标回收率为94.1%~ 104.3%、正己烷加标回收率为94.7% ~ 105.8%,当采样体积为30 L,二种物质的方法最低捡出质量浓度均为0.0l mg/m3.该方法分析速度快,所需样品量少,前处理简便,分离度好,分析灵敏度高. 相似文献
116.
土壤气采样和分析是蒸气侵入评估的一个常用的工具.以某废弃化工场地为研究区,采集污染区域10个点位处的土壤气(编号SG1至SG10),并分析土壤气中的苯、乙苯、四氯化碳、三氯乙烯、四氯乙烯和三氯甲烷等挥发性有机物.根据测定的土壤气体浓度,结合Johnson &Ettinger(J&E)侵入模型评估了该废弃场地土壤气中挥发性有机物侵入带来的人体健康风险.风险评估结果表明,SG5与SG6处非致癌风险指数大于1,而10个采样点位中有9个(除SG8处)的单一污染物可接受致癌风险均超过1.0E-6.相对于非致癌风险,致癌风险存在面更加广泛,同时程度也比较严重,在进行场地再开发之前需要考虑场地修复等风险管理措施. 相似文献
117.
利用灰色关联分析,可以挑选出与大别山地区地震活动关系密切的影响因子。选取前一年11月太阳黑子数、当年12月地球自转相对变化平均值、当年西太平洋季风活动性数值、当年太阳10.7cm射电流量数值、大别山地区年降雨量平均值、大别山地区年气温平均值、大别山地区采掘业电力消耗值7个因子与大别山地区地震活动数进行灰色关联分析,结果表明:与大别山地区地震活动关联度最大的因子为地球自转相对变化值,与大别山地区的地震活动与该区域的采矿业关联度最低。 相似文献
118.
Phosphorus is a vital nutrient for algal growth, thus, a better understanding of phosphorus availability is essential to mitigate harmful algal blooms in lakes. Wind waves are a ubiquitous characteristic of lake ecosystems. However, its effects on the cycling of organic phosphorus and its usage by phytoplankton remain poorly elucidated in shallow eutrophic lakes. A mesocosm experiment was carried out to investigate the responses of alkaline phosphatase activity fractions to wind waves in large, shallow, eutrophic Lake Taihu. Results showed that wind-driven waves induced the release of alkaline phosphatase and phosphorus from the sediment, and dramatically enhanced phytoplanktonic alkaline phosphatase activity. However, compared to the calm conditions, bacterial and dissolved alkaline phosphatase activity decreased in wind-wave conditions. Consistently, the gene copies of Microcystis phoX increased but bacterial phoX decreased under wind-wave conditions. The ecological effects of these waves on phosphorus and phytoplankton likely accelerated the biogeochemical cycling of phosphorus and promoted phytoplankton production in Lake Taihu. This study provides an improved current understanding of phosphorus availability and the phosphorus strategies of plankton in shallow, eutrophic lakes. 相似文献
119.
Health risks of heavy metals in contaminated soils and food crops irrigated with wastewater in Beijing, China 总被引:24,自引:0,他引:24
Khan S Cao Q Zheng YM Huang YZ Zhu YG 《Environmental pollution (Barking, Essex : 1987)》2008,152(3):686-692
Consumption of food crops contaminated with heavy metals is a major food chain route for human exposure. We studied the health risks of heavy metals in contaminated food crops irrigated with wastewater. Results indicate that there is a substantial buildup of heavy metals in wastewater-irrigated soils, collected from Beijing, China. Heavy metal concentrations in plants grown in wastewater-irrigated soils were significantly higher (P相似文献
120.
胜利油田含油污泥的植物修复研究 总被引:3,自引:2,他引:1
胜利油田滨一污水站产生的含油污泥经俄罗斯菌剂修复后含油量仍较高,为进一步降低其含油量,采用了植物修复技术.在总面积为1 000 m2的含油污泥修复场地上,分别种植了高羊茅、苜蓿、大豆、玉米和高粱,进行了120 d的植物修复.检测了植物修复前后含油污泥的含油量、基本理化性质、生物毒性、微生物数量和代谢功能多样性.对比发现,植物修复后含油污泥的石油降解率最高可达34.09%,持水率提高,生物毒性下降,微生物数量增加及代谢功能多样性增强.实验说明,植物修复是处理含油污泥的有效方法之一. 相似文献