Manganese in the urban atmosphere: identifying anomalous concentrations and sources

Purpose  

Industrial emissions can raise urban background levels of inhalable Mn particles in an order of magnitude above normal, eclipsing the contribution made by natural sources and traffic.     

Colorful tails fade when lizards adopt less risky behaviors

Colorful tails that become cryptic during ontogeny are found in diverse taxa. Nevertheless, the evolutionary bases for this change remain debated. Recent work suggests that colorful tails, deflective displays, and striped patterns may represent antipredator mechanisms used by immature lizards to compensate for being more active and hence more vulnerable to predation (increased movement hypothesis, IMH). I challenged the generality of IMH by comparing foraging behavior and frequency of tail displays across five Acanthodactylus lizards that vary in fundamental life history traits, before and after the tail changed color. As these species underwent changes in tail coloration, they congruently adopted less risky behaviors and reduced the frequencies of tail displays. Contrary to expectation, in two species, the hatchling risky behavior resulted not from increased movements but from longer stay in exposed microhabitats. I suggest that colorful tails and deflective tail displays are synergistic antipredator mechanisms neonates use to minimize the fitness consequences of using various risky behaviors rather than increased movement alone.     

Application of preparative capillary gas chromatography (pcGC), automated structure generation and mutagenicity prediction to improve effect-directed analysis of genotoxicants in a contaminated groundwater

Background, aim and scope  

The importance of groundwater for human life cannot be overemphasised. Besides fulfilling essential ecological functions, it is a major source of drinking water. However, in the industrial area of Bitterfeld, it is contaminated with a multitude of harmful chemicals, including genotoxicants. Therefore, recently developed methodologies including preparative capillary gas chromatography (pcGC), MOLGEN-MS structure generation and mutagenicity prediction were applied within effect-directed analysis (EDA) to reduce sample complexity and to identify candidate mutagens in the samples. A major focus was put on the added value of these tools compared to conventional EDA combining reversed-phase liquid chromatography (RP-LC) followed by GC/MS analysis and MS library search.     

Extended Analytical Turbulent Diffusion Model for Particle Dispersion and Deposition in a Horizontal Pipe: Comparison with CFD Simulation

A 2D analytical turbulent diffusion model for particle dispersion and deposition at different heights along the pipe flow and circumferential deposition has been developed. This liquid–solid turbulent diffusion model presented in this paper has emanated from an existing gas–liquid turbulent diffusion model. This model can be used as a handy tool for quick estimation one and two-dimensional deposition fluxes of particles in water distribution networks. A comprehensive 3D numerical investigation has been carried out using multiphase mixture model available in “Fluent 6.2” to verify the above analytical model. Different particles sizes and densities were used for 3D numerical investigations. The deposition was studied as a function of particle diameter, density, and fluid velocity. The deposition of particles, along the periphery of the pipe wall and at different depths, was investigated. Both the models findings matched with qualitative phenomena such as deposition of heavier particles at the bottom of the pipe wall were higher at lower velocities and lower at higher velocities. The lighter particles were found mostly suspended with homogeneous distribution. Smaller particles were also suspended with marginal higher concentration near the bottom of the pipe wall. This marginal higher concentration of the smaller particles was found to be slightly pronounced for lower velocity. These analogies of particles are well discussed with the ratio between free-flight velocity and the gravitational settling velocity. Extended analytical model results were compared with the 3D computational fluid dynamics simulation results. Discrepancies in the model results were discussed.     

Patterns of Streamwater Acidity in Lye Brook Wilderness,Vermont, USA

Under the United States Clean Air Act Amendments of 1977, a class I designation safeguards wilderness areas from the negative effects of new sources of air pollution. We monitored streamwater chemistry in the class I Lye Brook Wilderness in southwestern Vermont from May 1994 through August 1995. Stream samples were collected biweekly at nine sampling locations throughout the wilderness and were analyzed for major cations and anions, dissolved organic carbon, pH, and acid-neutralizing capacity. Eight of nine sites sampled had mean annual acid neutralizing capacity values below zero. During the study period, decreases in streamwater acid neutralizing capacity values were caused primarily by SO₄ ²⁻. At some sites, however, NO₃ ⁻ and naturally occurring, weak organic acids were seasonally important. During high discharge, the low pH and high concentrations of inorganic monomeric Al were at levels that are toxic to acid-sensitive aquatic species. Watershed mass balances were calculated to determine annual gains or losses for measured ions. These budgets indicate that S inputs and outputs were nearly equal, there was a net loss of base cations, and a net gain in N. How long these watersheds can continue to assimilate additional N inputs is unknown.     

Waste reduction through variable charging programs: its sustainability and contributing factors

 In this study, we analyzed the sustainability and determinant factors of waste reduction through variable charging schemes. We drew three main conclusions from the study. (1) Waste reduction was achieved by variable charging and was sustained over an average of at least 10 years. The results regarding the sustainability of the price effect were inconclusive. (2) The main factors contributing to the combustible waste reduction achieved through variable charging were two-tier pricing and the price of waste bags. The effect of two-tier pricing programs was positive. (3) Waste paper recycling and variable charging reinforce each other to promote waste reduction. Received: September 3, 2001 / Accepted: January 13, 2002     

Toward Adaptive Management: The Impacts of Different Management Strategies on Fish Stocks and Fisheries in a Large Regulated Lake

We applied the adaptive management approach to analyze the demand and feasibility of adaptive management of fish stocks in a large regulated lake, Oulujärvi, in northern Finland. The process consisted of four phases: (1) analysis of the current state of the fisheries system (fishers, related markets and industry, fisheries researches and authorities, related organizations, etc.); (2) analysis of the objectives of different stakeholders; (3) the composition of alternative management strategies and assessment of their impacts; and (4) recommendations for future management. We used catch statistics from the period 1973–1995 to analyze fish stocks and fishing. Fish species involved were brown trout (Salmo trutta L.), whitefish [Coregonus lavaretus (L.) sl.], vendace (Coregonus albula L.); and pikeperch (Stizostedion lucioperca L.). Questionnaires and interviews were applied to ascertain the opinions of different groups of fishermen. Several models and cost–benefit analysis were used to assess the ecological, economic, and social impacts of three alternative management strategies. The results emphasize that when determining stocking levels and fishing regulations, the system should be considered as a whole, and impacts on major fish species and different groups of fishermen should be assessed. The stocking policy and fishing regulations should also be flexible to accommodate changing biotic and societal conditions. The key questions in applying the adaptive management process in Oulujärvi fisheries are how to determine clear objectives for fisheries management, find a fisheries management structure that provides workable interactions between different stakeholders, and arrange cost-effective monitoring. The lessons learned from the Oulujärvi experience and recommendations for fisheries management are relevant to other lakes with conflicting objectives of different stakeholders.     

Agricultural Land Use Effects on Sediment Loading and Fish Assemblages in Two Minnesota (USA) Watersheds

We examined the relationship between water quality and fish communities within two agricultural areas using a computer simulation model. Our analyses focused on a coolwater stream, Wells Creek in southeastern Minnesota, and a warmwater stream, the Chippewa River in western Minnesota. We used the Agricultural Drainage and Pesticide Transport (ADAPT) model in relation to land use to calculate instream suspended sediment concentrations using estimates of sediment delivery, runoff, baseflow and streambank erosion, and quantified the effects of suspended sediment exposure on fish communities. We predicted the effects of agricultural practices on stream fish communities under several possible land use scenarios, with reference to current conditions. Land use changes led to reductions in sediment loading of up to 84% in Wells Creek and 49% in the Chippewa River. The reduction in sediment loading across scenarios may be directly related to a reduction in runoff by about 35% in both study areas. We found a 98% decrease in lethal concentrations of suspended sediment on fish in Wells Creek with an increase in conservation tillage, riparian buffers, and permanent vegetative cover. However, the effects of suspended sediment did not significantly decrease in the Chippewa River. This difference between study areas was likely due to differences in tolerance to suspended sediment between coolwater and warmwater fish communities and differences in topography, runoff and bank erosion between the two streams. The Minnesota Cooperative Fish and Wildlife Research Unit is jointly sponsored by the US Geological Survey, the University of Minnesota, the Minnesota Department of Natural Resources, and the Wildlife Management Institute.