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91.
Through a sensitivity analysis, the trade-off between vehicle range and CO2 emissions is investigated as a function of electric emissions coefficient. Various powertrains were analysed for use in a small crossover sport utility vehicle. Gasoline, gasoline electric hybrid, diesel, fuel cell and battery electric vehicles (BEVs) were considered. Using various upstream fuel pathways and a model for vehicle performance, emissions and energy use were estimated. The hydrogen fuel cell vehicle was found preferable to BEVs under conditions of high CO2 emissions per kW-hr and a high vehicle range requirement. The BEV was preferable for all other conditions.  相似文献   
92.
93.
The US EPA has exempted t-butyl acetate from VOC regulations, which increases the likelihood that it may replace other solvents in some settings. This investigation probes its chemosensory properties. In Study 1, subjects (n = 29) sought to detect the odor of t-butyl acetate and of n-butyl acetate in forced-choice testing of stable concentrations, analytically confirmed. Subjects sniffed from cones with a high enough volumetric flow to insure against dilution by nonodorized air. A subject made hundreds of judgments, enough for a psychometric function for each material. The points of 50% detection above chance (“threshold”) occurred at 8 and 2 ppb for t-butyl acetate and n-butyl acetate, respectively. In study 2, subjects (n = 26) sought to detect vapor with the eye via chemesthesis (sensory irritation) in 10-s exposures. Detection at 50% occurred at 177 and 113 ppm for t-butyl acetate and n-butyl acetate, respectively, more than 10,000 times above that for odor detection. The protocols produced results of uncommon precision compared to those in often-misleading archival databases. The nose exhibits much higher sensitivity than the databases indicate. The collections rarely exhibit accuracy better than ±1000%. Collection of accurate data for a VOC can ironically bring on stricter regulation for just it, a situation that calls for a strategy to improve the database by collection of new data, importation of better data, and development of quantitative structure–activity modeling.  相似文献   
94.
Nanotechnology, risk and the environment: a review   总被引:2,自引:0,他引:2  
Nanotechnologies are already interacting with the environment. Scientists and engineers are manipulating matter at the nanoscale, and these nanoscale processes and products are being used by industry in commercially available products. These products are either applied directly to the environment or end up in the environment through indirect pathways. This review examines the state of current environmental risk assessment of nanotechnologies. Nanotechnology is described generally, then both the possible benefits of nanotechnology and the risks are reviewed in a traditional way. Subsequently, a philosophical criticism of the traditional way of looking at risks is offered.  相似文献   
95.
New composite materials based on an alkali-resistant glass-fibre reinforced cement (AR-GRC) system are being developed by using fly ash (FA) produced at coal thermoelectric power plants, and fluid catalytic cracking catalyst residue (FC3R) from the petrol industry as cement replacement materials. These wastes are reactive from the pozzolanic viewpoint, and modify the nature and the microstructure of the cement matrix when a part of the Portland cement is replaced in the formulation of GRC. Several microstructural and mechanical aspects are being studied for AR-GRC systems. The behaviour of composites exposed to ageing shows that the pozzolanic activity of the ground FA added in high amounts and its mixture with the FC3R increase the flexural strength and no evidences of strength decay are observed. Additionally, the fibres due to the high alkalinity of the cementing matrix can be deteriorated. Fibres in the control (only Portland cement) and FC3R containing composites were attacked, whereas composites with FA and their mixture with FC3R show that the fibres have not been attacked, due to the pozzolanic activity of replacing materials that reduce the calcium hydroxide content in the cementing matrix.  相似文献   
96.
Packaging steel is more advantageously recovered and recycled than other packaging material due to its magnetic properties. The steel used for packaging is of high quality, and post-consumer waste therefore produces high-grade ferrous scrap. Recycling is thus an important issue for reducing raw material consumption, including iron ore, coal and energy. Household refuse management consists of collection/disposal, transport, and processing and treatment - incineration and composting being the most widely used methods in Spain. Total Spanish MSW production exceeds 21 million tons per year, of which 28.1% and 6.2% are treated in compost and incineration plants, respectively. This paper presents a comprehensive study of incineration and compost plants in Spain, including a review of the different processes and technologies employed and the characteristics and quality of the recovered ferrous scrap. Of the total amount of packaging steel scrap recovered from MSW, 38% comes from compost plants and 14% from incineration plants. Ferrous scrap from incineration plants presents a high degree of chemical alteration as a consequence of the thermal process to which the MSW is subjected, particularly the conditions in which the slag is cooled, and accordingly its quality diminishes. Fragmentation and magnetic separation processes produce an enhancement of the scrap quality. Ferrous scrap from compost plants has a high tin content, which negatively affects its recycling. Cleaning and detinning processes are required prior to recycling.  相似文献   
97.
Naphthenic acids (NAs) are the most water-soluble organic components found in the Athabasca oil sands in Alberta, Canada, and these acids are released into aqueous tailing waters as a result of bitumen extraction. Although the toxicity of NAs to fish is well known, there has been no method available to estimate NAs concentrations in fish. This paper describes a newly developed analytical method using single ion monitoring gas chromatography-mass spectrometry (GC-MS) to measure NAs in fish, down to concentrations of approximately 0.1mgkg(-1) of fish flesh. This method was used to measure the uptake and depuration of commercial NAs in laboratory experiments. Exposure of rainbow trout (Oncorhynchus mykiss) to 3mg NAsl(-1) for 9d gave a bioconcentration factor of approximately 2 at pH 8.2. Within 1d after the fish were transferred to NAs-free water, about 95% of the NAs were depurated. In addition, the analytical method was used to determine if NAs were present in four species of wild fish - northern pike (Esox lucius), lake whitefish (Coregonus clupeaformis), white sucker (Catostomus commersoni), walleye (Sander vitreus) - collected from near the oil sands. Flesh samples from 23 wild fish were analyzed, and 18 of these had no detectable NAs. Four fish (one of each species) contained NAs at concentrations from 0.2 to 2.8mgkg(-1). The GC-MS results from one wild fish presented a unique problem. However, with additional work it was concluded that the NAs concentration in this fish was <0.1mgkg(-1).  相似文献   
98.
The suddenness and scale of the 26 December 2004 tsunami and the challenges posed to affected communities highlighted the benefits of their members having a capacity to confront and adapt to the consequences of such a disaster. Research into adaptive capacity or resilience has been conducted almost exclusively with Western populations. This paper describes an exploratory study of the potential of a measure of collective efficacy developed for Western populations to predict the capacity of members of a collective society, Thai citizens affected by the 2004 tsunami, to confront effectively the recovery demands associated with this disaster. Following a demonstration that this measure could predict adaptive capacity, the role of religious affiliation, ethnicity and place of residence in sustaining collective efficacy is discussed. The implications of the findings for future research on, and intervention to develop, adaptive capacity among Thai citizens in particular and collectivist societies in general are discussed.  相似文献   
99.
Laminarization of flow in a two-dimensional dense gas plume was experimentally investigated in this study. The plume was created by releasing CO2 through a ground-level line source into a simulated turbulent boundary layer over an aerodynamically rough surface in a meteorological wind tunnel. The bulk Richardson number (Ri*), based on negative plume buoyancy, plume thickness, and friction velocity, was varied over a wide range so that the effects of stable stratification on plume laminarization could be observed. A variety of ambient wind speeds as well as three different sizes of roughness arrays were used so that possible effects of roughness Reynolds number (Re*) on plume laminarization could also be identified. Both flow visualization methods and quantitative measurements of velocity and intermittency of turbulence were used to provide quantitative assessments of plume laminarization.Flow visualization provided an overall picture of how the plume was affected by the negative buoyancy. With increasing Ri*, both the plume depth and the vertical mixing were significantly suppressed, while upstream propagation of the plume from the source was enhanced. The most important feature of the flow revealed by visualization was the laminarization of flow in the lower part of the plume, which appeared to be closely related to both Ri* and Re*.Measurements within the simulated dense gas plumes revealed the influence of the stable stratification on mean velocity and turbulence intensity profiles. Both the mean velocity and turbulence intensity were significantly reduced near the surface; and these reductions systematically depended on Ri*. The roughness Reynolds number also had considerable influence on the mean flow and turbulence structure of the dense gas plumes.An intermittency analysis technique was developed and applied to the digitized instantaneous velocity signals. It not only confirmed the general flow picture within the dense plume indicated by the flow visualization, but also clearly demonstrated the changes of flow regime with variations in Ri* and Re*. Most importantly, based on this intermittency analysis, simple criteria for characterizing different flow regimes are formulated; these may be useful in predicting when plume laminarization might occur.  相似文献   
100.
Three isopod species (Crustacea: Isopoda), commonly found in the intertidal and supratidal zones of the North American Pacific coast, were studied with respect to symbiotic microbiota in their midgut glands (hepatopancreas). Ligia pallasii (Oniscidea: Ligiidae) contained high numbers of microbial symbionts in its hepatopancreatic caeca. Numbers of endosymbionts were strongly reduced by ingestion of antibiotics. By contrast, the hepatopancreas of Idotea wosnesenskii (Valvifera: Idoteidae) and Gnorimosphaeroma oregonense (Sphaeromatidea: Sphaeromatidae) did not contain any microbiota. Results of feeding experiments suggest that microbial endosymbionts contribute to digestive processes in L. pallasii, the most terrestrial of the three isopods that we studied. The acquisition of digestion-enhancing endosymbionts may have been an important evolutionary step allowing isopods to colonize terrestrial habitats where relatively indigestible leaf litter is the primary food source. By contrast, the ability to digest phenolic compounds was most developed in one of the more marine species, suggesting that this trait may have evolved independently in isopod species that consume a phenolic-rich diet, whether in marine habitats or on land. Received: 28 August 2000 / Accepted: 8 December 2000  相似文献   
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