全文获取类型
收费全文 | 1303篇 |
免费 | 36篇 |
国内免费 | 237篇 |
专业分类
安全科学 | 43篇 |
废物处理 | 51篇 |
环保管理 | 89篇 |
综合类 | 696篇 |
基础理论 | 265篇 |
环境理论 | 1篇 |
污染及防治 | 295篇 |
评价与监测 | 46篇 |
社会与环境 | 56篇 |
灾害及防治 | 34篇 |
出版年
2023年 | 17篇 |
2022年 | 45篇 |
2021年 | 31篇 |
2020年 | 32篇 |
2019年 | 17篇 |
2018年 | 36篇 |
2017年 | 48篇 |
2016年 | 51篇 |
2015年 | 54篇 |
2014年 | 52篇 |
2013年 | 92篇 |
2012年 | 55篇 |
2011年 | 61篇 |
2010年 | 75篇 |
2009年 | 65篇 |
2008年 | 63篇 |
2007年 | 50篇 |
2006年 | 58篇 |
2005年 | 51篇 |
2004年 | 30篇 |
2003年 | 30篇 |
2002年 | 56篇 |
2001年 | 36篇 |
2000年 | 27篇 |
1999年 | 23篇 |
1998年 | 25篇 |
1997年 | 21篇 |
1996年 | 21篇 |
1995年 | 21篇 |
1994年 | 13篇 |
1993年 | 13篇 |
1990年 | 10篇 |
1989年 | 9篇 |
1986年 | 8篇 |
1985年 | 8篇 |
1983年 | 8篇 |
1976年 | 8篇 |
1966年 | 8篇 |
1965年 | 11篇 |
1964年 | 11篇 |
1963年 | 9篇 |
1962年 | 11篇 |
1961年 | 11篇 |
1960年 | 18篇 |
1959年 | 10篇 |
1958年 | 10篇 |
1957年 | 11篇 |
1956年 | 11篇 |
1955年 | 6篇 |
1954年 | 6篇 |
排序方式: 共有1576条查询结果,搜索用时 0 毫秒
961.
Hong Zhao Yunshan Ge Jianwei Tan Hang Yin Jiadong Guo Wei Zhao Peipei Dai 《环境科学学报(英文版)》2011,23(11):1831-1838
The effects of different mixing ratios of methanol/gasoline blends and new three-way catalytic converter on regulated and unregulated emissions, especially VOC and carbonyl compound emissions were investigated. 相似文献
962.
963.
对辐射环境模型AP9/AE9/SPM进行了系统研究,重点分析了AP9/AE9/SPM辐射环境模型的发展历程、建模数据、模型能力、模型使用方法、模型特点和局限性以及发展趋势。总结了AP9/AE9/SPM辐射环境模型“螺旋式上升”研发途径中所发布的11个版本的特点、数据覆盖时间范围和能量范围。指出AP9/AE9/SPM辐射环境模型在研发过程中是通过不断地将最新的观测数据和理论知识进行整合,达到扩展模型能量覆盖范围、增加空间粒子分布的目的。最新的AP9/AE9/SPM辐射环境模型具备了命令行和图形用户接口应用程序2种灵活便捷的使用方式,能覆盖完整的辐射带空间,基本实现了电子和质子能量范围的全覆盖。但目前最新版本的AP9/AE9/SPM仍然存在一些局限,这些局限会随着辐射带探测数据的积累和人类对辐射带机理的进一步认知而逐渐得到改善。该研究可帮助用户快速了解并正确使用AP9/AE9/SPM辐射环境模型,为我国自主辐射环境模型研发提供重要参考。 相似文献
964.
Bo Shi Weigang Wang Cici Fan Yuchan Zhang Zheng Sun Yanli Zeng Maofa Ge 《环境科学学报(英文版)》2022,34(6):25-33
The reaction of Cl atoms with two C5 aldehydes (3-methyl-2-butenal and 3-methylbutanal) were investigated by proton-transfer-reaction mass spectrum (PTR-MS) using smog chamber at 298 ± 1 K and 760 Torr. A relative rate method was used to determine the rate constants of the title reactions with m-xylene and trans-2-butene as reference compounds: (3.04 ± 0.18) × 10−10 and (2.07 ± 0.14) × 10−10 cm3/(molecule⋅sec) for 3-methyl-2-butenal and 3-methylbutanal, respectively. Additionally, the gas-phase products were also identified by PTR-MS, and the possible reaction mechanisms were proposed basing on the identified products. The detected gas-phase products are similar for two C5 aldehydes reactions, mainly including small molecules of aldehydes, ketones and chlorinated aldehyde compounds. The atmospheric lifetimes (τ) calculated for 3-methyl-2-butenal (τ = 7.0 hr, marine boundary layer (MBL)) and 3-methylbutanal (τ = 10.3 hr, MBL) according to the obtained rate constants. The results indicate that Cl atoms at MBL are competitive with OH radicals for the degradation contribution of C5 aldehyde compounds. 相似文献
965.
Fangjie Li Shengrui Tong Chenhui Ji Xinran Zhang Deng Lin Wenqian Zhang Weiran Li Lili Wang Maofa Ge Lixin Xia 《环境科学学报(英文版)》2022,34(4):85-97
The field observation of 54 non-methane hydrocarbon compounds (NMHCs) was conducted from September 1 to October 20 in 2020 during autumn in Haidian District, Beijing. The mean concentration of total NMHCs was 29.81 ± 11.39 ppbv during this period, and alkanes were the major components. There were typical festival effects of NMHCs with lower concentration during the National Day. Alkenes and aromatics were the dominant groups in ozone formation potential (OFP) and OH radical loss rate (LOH). The positive matrix factorization (PMF) running results revealed that vehicular exhaust became the biggest source in urban areas, followed by liquefied petroleum gas (LPG) usage, solvent usage, and fuel evaporation. The box model coupled with master chemical mechanism (MCM) was applied to study the impacts of different NMHCs sources on ozone (O3) formation in an O3 episode. The simulation results indicated that reducing NMHCs concentration could effectively suppress O3 formation. Moreover, reducing traffic-related emissions of NMHCs was an effective way to control O3 pollution at an urban site in Beijing. 相似文献
966.
For wide-area atmospheric monitoring, krypton-85 is the best indicator for clandestine plutonium separations. The detection and false alarm rates were determined from weekly samples at five different distances from the Karlsruhe reprocessing plant between 1985 and 1988. The detection rate for the separation of 4 kg of plutonium per week was found to be as high as 80-90% at a distance of less than 1 km, 70% at 5 km, 40% at 39 km, and 15% at 130 km. At distances up to 40 km, the false alarm rate is less than 3.5%. On average, the fuel released 28 TBq krypton-85 per kg plutonium. For weapons-grade plutonium, the krypton signal would be lower by a factor of 2. Hence, the given percentages correspond to the detection probabilities for the separation of a significant quantity (8 kg) of plutonium per weekly sample under the specific meteorological conditions of the WAK. The minimum separation rates that could have been detected are 2 gram of weapons-grade plutonium per week at a distance of less than 1 km, 40 g/week at 5 km, 200 g/week at 39 km, and 1000 g/week at 130 km. 相似文献
967.
利用仿生合成的方法,以甘氨酸为模板剂、钛酸正四丁酯作钛源,水热合成一种新型纳米TiO2花式微球,并对其进行了表征。通过考察pH值、温度和Pb(Ⅱ)溶液的初始浓度对吸附效果的影响,研究了TiO2花式微球对水溶液中Pb(Ⅱ)的吸附性能及其吸附动力学特性。结果表明,纳米TiO2花式微球直径约2 μm,平均孔径约56 nm,比表面积约是270.3 m2/g;当pH值为4.0时TiO2花式微球对溶液中Pb(Ⅱ)吸附率达到最高,210 min时基本达到吸附平衡,20、30和40℃的最大吸附量分别为75.64、76.34 和77.52 mg/g。吸附过程遵循准二级速率方程,与Langmuir等温式拟合更好。 相似文献
968.
王 《防灾减灾工程学报》2006,26(4):395-403
应用法国地震学家G.Poup inet等关于双子地震的有关理论,对云南地震台网数字地震资料开展应用研究,通过基线校正、数字滤波、波形对比等方法获得8对3级双子地震和武定地震易门台7对双子地震。对以上双子地震取起始3秒P波作富氏谱分析后进行谱比对数的斜率拟合。结果显示,由发生在6.5级姚安地震前7个月之内与之外时段的地震构成的双子地震,其P波谱比对数斜率绝对值都达到0.030以上,明显高于均由震前7个月之外发生的地震构成的双子地震谱比对数斜率;在距主震2°范围以内的台站可观测到双子波发生的变化。常熟台双子地震P波谱比对数斜率时间进程在南黄海地震发生之前也存在这一现象,但出现异常的时间扩大到9个月之内。 相似文献
969.
安徽省地电阻率观测干扰因素的分析研究 总被引:3,自引:0,他引:3
为了正确鉴别震前异常信息,本文从影响安徽省地电阻率观测数据的干扰因素入手,详细地分析了典型干扰的变化特征及干扰机制,并对干扰的排除提出相应建议,其研究结果对有效地识别干扰及异常判断有一定的指导意义。 相似文献
970.