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Water repellency can induce preferential flow and thus affect water flow and contaminant transport at hazardous waste sites. Since the spatial patterns of water repellency are mostly unknown, it is problematic to use numerical transport models to predict leachate composition. In this study, the spatial variability of soil water repellency was studied at an industrial site contaminated with tar oil, chromium, copper and arsenic. The persistence of water repellency was assessed by the water drop penetration time (WDPT), and the degree of water repellency was quantified by the ethanol percentage (EP) test. Measurements were made at the soil surface along 3.5-12.1 m long transects at different times between March and October 2002. The spatial variability of WDPT, EP, water content, and organic matter content was quantified by variogram analyses. Both the persistence and the degree of water repellency varied seasonally, with the highest water repellency during the summer months. The correlation lengths of WDPT values ranged between 16 and 406 cm, whereas EP values showed no spatial correlation. For field-moist samples, a critical soil water threshold, below which water repellency prevails, was estimated to be 2.5-4%. For oven dry samples, the WDPT values were dependent on the water content prior to drying. The wide range of correlation lengths and the temporal dynamics of spatial repellency patterns suggest that simulations of solute leaching must consider the spatial and temporal variability of soil hydrophobic properties.  相似文献   
178.
The development of criteria for the comparative assessment of technologies and substances beyond the toxicological approach and the development of an integrated pattern of criteria is still at the beginning. The criteria presented here for integrating the precautionary principle into the substance and technology assessment have to be further operationlised and completed, in the same way as the criteria which have been discussed and developed within the framework of
  • - the poisoning and pollutant paradigm
  • - the equilibrium paradigm
  • - the sustainability and “Mitwelt” paradigm
  • - the energy and the general technology assessment debate.
  • The resolution of the criteria has to be improved and their range (which is certainly limited) has to be explored more precisely. The application of the criteria should never occur mechanically. Technology assessment and substance assessment are not only scientific, but essentially social and, hence, discursive processes. It is not so much the assessment of individual substances which should be in the center of the debate, but rather the comparative assessment of competing techniques, substances and substancerelated development pathways (see vonGleich andRubik, 1966 as a first approach to assess the environmental effects of old and new materials). According to the example of the energy strategies, only the development of competing strategies in the substance field could create the necessary prerequisites for a broad public discourse and thus for a democratisation of the basic substancerelated policy decisions. This discourse is a duty which science and economy have toward society.  相似文献   
    179.
    Measurements were made with a Clark electrode in a closed system under conditions of different, regulatable water current velocities. Six simultaneous parallel measurements are possible with only one electrode. The volume of respiration chambers amounts to 80 ml for small animals and 300 ml for larger ones. Technical details of the apparatus and measuring procedures are described. The accuracy amounts to 0.5 μl O2 for the 80 ml chamber, and 2 μl O2 for the 300 ml chambers. The apparatus has been successfully used on various marine evertebrates and algae.  相似文献   
    180.
    Repertoire size, the number of unique song or syllable types in the repertoire, is a widely used measure of song complexity in birds, but it is difficult to calculate this exactly in species with large repertoires. A new method of repertoire size estimation applies species richness estimation procedures from community ecology, but such capture-recapture approaches have not been much tested. Here, we establish standardized sampling schemes and estimation procedures using capture-recapture models for syllable repertoires from 18 bird species, and suggest how these may be used to tackle problems of repertoire estimation. Different models, with different assumptions regarding the heterogeneity of the use of syllable types, performed best for different species with different song organizations. For most species, models assuming heterogeneous probability of occurrence of syllables (so-called detection probability) were selected due to the presence of both rare and frequent syllables. Capture-recapture estimates of syllable repertoire size from our small sample did not differ significantly from previous estimates using larger samples of count data. However, the enumeration of syllables in 15 songs yielded significantly lower estimates than previous reports. Hence, heterogeneity in detection probability of syllables should be addressed when estimating repertoire size. This is neglected using simple enumeration procedures, but is taken into account when repertoire size is estimated by appropriate capture-recapture models adjusted for species-specific song organization characteristics. We suggest that such approaches, in combination with standardized sampling, should be applied in species with potentially large repertoire size. On the other hand, in species with small repertoire size and homogenous syllable usage, enumerations may be satisfactory. Although researchers often use repertoire size as a measure of song complexity, listeners to songs are unlikely to count entire repertoires and they may rely on other cues, such as syllable detection probability.Communicated by A. Cockburn  相似文献   
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