An evaluation of grid rod failure in a mobile bed scrubber

The body of information presented in this paper is directed to those engineers and maintenance personnel involved in the operation of mobile-bed scrubbers. Materials tests were performed on three specimens of austenitic stainless steel to determine the possible causes of grid rod failure in a mobile-bed scrubber controlling particulate emissions from a pulverized-coal-fired, steam-electric generating station. These three specimens were successively placed in an Instrom universal testing machine and loaded in tension until rupture occurred. The results of these tests, in addition to other supporting data, were used in an attempt to determine the cause of the grid rod failure during scrubber operation. It was determined that the grade of stainless steel used, the scrubber water quality, and certain operational problems could be causes of premature failure.     

An economic modelling approach to the design and delivery of sustainable waste minimisation clubs: Prospects in the new policy framework

Since the early 1990s, waste minimisation clubs have been important sources of information for industry in the UK on clean technology and sustainable waste management practice. Despite this contribution, concern has grown about the declining number of clubs, their performance and the likelihood that they will continue to play a key role in national policy.This paper examines the evidence available and provides estimates of how the numbers varied in England since the first clubs were formed. The results presented indicate that, after initial expansion, numbers went into decline. The paper then explores, using economic theory, why this pattern should have developed and suggests it to be a function of how clubs were designed and managed. The results of the analysis are used to propose alterations in how future clubs could be designed so that they continue to contribute effectively to the development of sustainable waste management in UK industry. These lessons are of value to policy in both the UK and other countries considering the development of this important tool of waste strategy. The paper concludes with a number of suggestions for future research.     

THERMAL DISCHARGES AND PUBLIC POLICY DEVELOPMENT1

ABSTRACT The generation of electric energy in steam-electric power plants is accompanied by the discharge of large quantities of waste heat into the environment. In most cases, this heat is released into natural bodies of water at temperatures relatively close to ambient. In certain locations, such as the Chesapeake Bay, discharges of waste heat may triple in the next decade. It is expected that past practices of thermal discharge, if continued into the future, will result in significant damages to other legitimate users of the water resource, both present and future. This paper reviews the economic causes of these potential damages, and describes the role of public policy as one of removing such causes through regulation incentive or intervention. Possible public policies are reviewed, including prohibition, standards, various types of dollar incentives such as taxes and subsidies, marketable effluent permits, and direct government investment. The innovative power plant siting program recently adopted in Maryland is also discussed. It is concluded that no statements can be made regarding the comparative efficiency or effectiveness of the various policies at the present state of knowledge. It is recommended that policy-makers adopt mixed strategies, preserving as many options as possible for dealing with similar problems in the future.     

Iron-impregnated zeolite catalyst for efficient removal of micropollutants at very low concentration from Meurthe river

In this paper, for the first time, faujasite Y zeolite impregnated with iron (III) was employed as a catalyst to remove a real cocktail of micropollutants inside real water samples from the Meurthe river by the means of the heterogeneous photo-Fenton process. The catalyst was prepared by the wet impregnation method using iron (III) nitrate nonahydrate as iron precursor. First, an optimization of the process parameters was conducted using phenol as model macro-pollutant. The hydrogen peroxide concentration, the light wavelength (UV and visible) and intensity, the iron loading immobilized, as well as the pH of the solution were investigated. Complete photo-Fenton degradation of the contaminant was achieved using faujasite containing 20 wt.% of iron, under UV light, and in the presence of 0.007 mol/L of H₂O₂ at pH 5.5. In a second step, the optimized process was used with real water samples from the Meurthe river. Twenty-one micropollutants (endocrine disruptors, pharmaceuticals, personal care products, and perfluorinated compounds) including 17 pharmaceutical compounds were specifically targeted, detected, and quantified. All the initial concentrations remained in the range of nanogram per liter (0.8–88 ng/L). The majority of the micropollutants had a large affinity for the surface of the iron-impregnated faujasite. Our results emphasized the very good efficiency of the photo-Fenton process with a cocktail of a minimum of 21 micropollutants. Except for sulfamethoxazole and PFOA, the concentrations of all the other microcontaminants (bisphenol A, carbamazepine, carbamazepine-10,11-epoxide, clarithromycin, diclofenac, estrone, ibuprofen, ketoprofen, lidocaine, naproxen, PFOS, triclosan, etc.) became lower than the limit of quantification of the LC-MS/MS after 30 min or 6 h of photo-Fenton treatment depending on their initial concentrations. The photo-Fenton degradation of PFOA can be neglected. The photo-Fenton degradation of sulfamethoxazole obeys first-order kinetics in the presence of the cocktail of the other micropollutants.