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141.
Thomas George S. Naseema Beevi George Xavier N. Pratheesh Kumar Jayesh George 《Environmental monitoring and assessment》2013,185(6):5277-5284
The dissipation kinetics and method for estimation of residues of chlorpyrifos and lambda-cyhalothrin in cardamom were studied and developed. The limit of detection and limit of quantitation arrived for the compounds were 0.01 and 0.025 μg?g?1, respectively. Gas chromatographic response of chlorpyrifos and lambda-cyhalothrin residues was linear in the range of 0.01–0.50 μg?g?1 and the mean recovery obtained was 97.3 % for chlorpyrifos and 98.9 % for lambda-cyhalothrin with satisfactory relative standard deviation values. The mean initial residues of chlorpyrifos applied at a concentration of 0.05 % in cardamom was 2.5 μg?g?1 and the residue was 8.1 μg?g?1 after processing, with a processing factor of 3.24, while lambda-cyhalothrin when applied at 0.0025 % resulted in initial residues of 1.63 μg?g?1 that magnified to 4.86 μg?g?1 on curing, with a processing factor of 2.98. The half-life of chlorpyrifos was in the range of 5.1–5.24 days while that of lambda-cyhalothrin was in the range of 4.40–4.55 days. The processing factor arrived at in the above experiment lead to the conclusion that the residues of chlorpyrifos got magnified to 3.24–3.68 times and that of lambda-cyhalothrin got magnified to 2.98–3.46 times of initial residues, consequent to loss of weight due to dehydration during curing. 相似文献
142.
Moreno T Querol X Alastuey A García do Santos S Fernández Patier R Artiñano B Gibbons W 《Journal of environmental monitoring : JEM》2006,8(10):1060-1068
Source apportionment study was performed, applying principal component analysis to the results of 221 chemical analyses of PM10 and PM2.5 samples collected daily from the industrial (but low traffic) Spanish town of Puertollano over a 14-month period during 2004-2005. Results reveal compositional variations attributable to different mixtures of natural and anthropogenic materials, mainly soil and rock dust (crustal), marine salt (only in PM10), petrochemical refinery emissions, and particles attributed to the combustion of local coal, which is unusually rich in Pb and Sb. During the study period there were 34 pollution episodes when PM10 exceeded 50 tg m(-3), mostly due to winter air temperature inversions, regional atmospheric stagnation, or African dust incursions (North African, NAF days: usually in summer). Whereas the crustal component during NAF episodes averaged 52% with a PM2.5/PM10 ratio of 0.54, this dropped to 29% and a PM2.5/PM10 of 0.67 during non-NAF days when anthropogenic materials predominated. Abnormally enhanced concentrations of pathfinder metallic trace elements provide additional evidence for source apportionment: thus aerosols with raised levels of Pb and Sb are associated with local coal combustion, Ni and V can be linked to petrochemical PM emissions, and Ti, Mn, Rb, and Ce are particularly characteristic of crustal dust incursions. 相似文献
143.
144.
In this paper, a method involving on-line preconcentration with cloud point extraction for the determination of cadmium in biological samples is presented. The procedure is based on the sorption of micelles containing Cd(II) ions and the reagent 4-(5'-bromo-2'-thiazolylazo)orcinol (Br-TAO) in a minicolumn packed with polyester. The surfactant Triton X-114 was used in the formation of micelles. After sorption, the Cd(II) ions were desorbed from the minicolumn with acid eluent and determined by flame atomic absorption spectrometry. Parameters influencing the cloud point extraction were studied. The method showed a detection limit of 0.5 μg l(-1) and an enhancement factor of 27. The accuracy was tested by determination of cadmium in certified reference materials (spinach leaves 1570a and tomato leaves 1573a) from the National Institute of Standards and Technology. 相似文献
145.
146.
Fulvio Amato Xavier Querol Andrés Alastuey Marco Pandolfi Teresa Moreno José Gracia Pau Rodriguez 《Atmospheric environment (Oxford, England : 1994)》2009,43(29):4472-4480
Despite their burden in urban particulate air pollution, road traffic non-exhaust emissions are often uncontrolled and information about the effectiveness of mitigation measures on paved roads is still scarce. The present study is aimed to evaluate the effectiveness of mechanical sweeping/water flushing treatments in mitigating urban road dust resuspension and to quantify the real benefit in terms of ambient PM10 concentrations. To this aim a specific campaign was carried out in a heavily trafficked central road of Barcelona (Spain), a Mediterranean city suffering from a traffic-related pollution, both for a high car density and a frequent lack of precipitation. Several street washings were performed by means of mechanical sweepers and pressure water during night in all traffic lanes and sidewalks. PM10 levels were simultaneously compared with four reference urban background air quality stations to interpret any meteorological variability. At the downwind measurement site, PM10 concentrations registered a mean daily decrease of 8.8 μg m?3 during the 24 h after street washing treatments. However 3.7–4.9 μg m?3 of such decrease were due to the meteorological variability detected at the upwind site, as well as at two of the reference sites. This reveals that an effective decrease of 4–5 μg m?3 (7–10%) can be related to street washing efficiency. Mitigation of road dust resuspension was confirmed by investigating the chemical composition of airborne-PM10 filters. Concentrations of Cu, Sb, Fe and mineral matter decrease significantly with respect to concentrations of elemental carbon, used as tracer for exhaust diesel emissions. High efficiency of street washing in reducing road dust loads was found by performing periodic samplings both on the treated and the untreated areas. 相似文献
147.
Noemí Pérez Teresa Moreno Xavier Querol Andrés Alastuey Ravinder Bhatia Baruch Spiro Melanie Hanvey 《Atmospheric environment (Oxford, England : 1994)》2010,44(21-22):2552-2562
We report on ambient atmospheric aerosols present at sea during the Atlantic–Mediterranean voyage of Oceanic II (The Scholar Ship) in spring 2008. A record was obtained of hourly PM10, PM2.5, and PM1 particle size fraction concentrations and 24-h filter samples for chemical analysis which allowed for comparison between levels of crustal particles, sea spray, total carbon, and secondary inorganic aerosols. On-board monitoring was continuous from the equatorial Atlantic to the Straits of Gibraltar, across the Mediterranean to Istanbul, and back via Lisbon to the English Channel. Initially clean air in the open Atlantic registered PM10 levels <10 μg m?3 but became progressively polluted by increasingly coarse PM as the ship approached land. Away from major port cities, the main sources of atmospheric contamination identified were dust intrusions from North Africa (NAF), smoke plumes from biomass burning in sub-Saharan Africa and Russia, industrial sulphate clouds and other regional pollution sources transported from Europe, sea spray during rough seas, and plumes emanating from islands. Under dry NAF intrusions PM10 daily mean levels averaged 40–60 μg m?3 (30–40 μg m?3 PM2.5; c. 20 μg m?3 PM1), peaking briefly to >120 μg m?3 (hourly mean) when the ship passed through curtains of higher dust concentrations amassed at the frontal edge of the dust cloud. PM1/PM10 ratios ranged from very low during desert dust intrusions (0.3–0.4) to very high during anthropogenic pollution plume events (0.8–1). 相似文献
148.
Francisco E. Fontúrbel Alina B. Candia Daniela A. Salazar Javiera Malebrán Catalina González-Browne Carezza Botto-Mahan 《Die Naturwissenschaften》2014,101(7):599-602
Habitat fragmentation and degradation are important biodiversity change drivers worldwide. Their effects have been described for many animal groups, but little is known about marsupials. We conducted a meta-analysis aiming to evaluate the actual effects of habitat fragmentation and degradation on forest marsupials. From a literature survey, we obtained 85 case studies reporting disturbance comparisons. We found a negative overall effect, as well as a negative effect for habitat fragmentation, but not for habitat degradation. Marsupials from Oceania were negatively affected by habitat disturbance, whereas there was no effect for those from South America. Arboreal marsupials were negatively affected, whereas terrestrial marsupials did not. Species from the families Dasyuridae (Antechinus spp.) and Microbiotheriidae (Dromiciops gliroides) showed to be sensitive to habitat disturbance. 相似文献
149.
A comparative Life Cycle Assessment (LCA) of solar photo-Fenton and solar photoelectro-Fenton, two solar-driven advanced oxidation processes (AOPs) devoted to the removal of non-biodegradable pollutants in water, is performed. The study is based on the removal, at laboratory scale, of the amino acid α-methylphenylglycine, a good example of soluble and non-biodegradable target pollutant. The system under study includes chemicals, electricity, transport of all raw materials to the plant site, and the generation of emissions, but it does not take into account the impact of the infrastructure needed to build a hypothetical solar plant. Nine environmental impact categories are included in the LCA: global warming potential, ozone depletion potential, aquatic eutrophication potential, acidification potential, human toxicity potential, photochemical ozone formation potential, fresh water aquatic ecotoxicity potential, marine aquatic ecotoxicity potential, and terrestrial ecotoxicity potential and abiotic resource depletion potential. Although previous experimental results show that both AOPs are able to efficiently degrade the pollutant, the LCA indicates that solar-driven photo-Fenton is the most environmentally friendly alternative, mainly because the use of electricity in solar photoelectro-Fenton experiments involves high environmental impacts. 相似文献
150.
Sebastien Pouchoulin Pedro Xavier Ramos Emmanuel Mignot Laurent Schindfessel Tom De Mulder Nicolas Riviere 《Environmental Fluid Mechanics》2018,18(5):1293-1295
The authors measured and computed the hydrodynamics and passive scalar dispersion in 90-degree open channel confluences over flat and degraded beds with a dominant upstream or tributary inflow. The present discussion essentially deals with the direction of rotation of the secondary currents, reported for the flat bed configuration with dominant tributary inflow. This rotation direction is indeed surprisingly opposite to the ones reported in the literature, both from calculations and measurements, even if present geometry slightly differs from literature geometries. 相似文献