Adsorption of lead on multi-walled carbon nanotubes with different outer diameters and oxygen contents: Kinetics, isotherms and thermodynamics

The effects of different outer diameters and surface oxygen contents on the adsorption of heavy metals onto six types of multi-walled carbon nanotubes (MWCNTs) were investigated in an aqueous solution and lead was chosen as a model metal ion. The results indicated that the percentage removal and adsorption capacity of lead remarkably increased with decreasing outer diameter due to larger specific surface area (SSA). The SSA-normalized maximum adsorption capacity (qm /SSA) and SSA-normalized adsorption coefficient (Kd /SSA) were strongly positively correlated with surface oxygen content, implying that lead adsorption onto MWCNTs significantly increases with the rise of oxygen content and decreases with decreasing SSA. The calculated thermodynamic parameters indicated that adsorption of lead on MWCNTs was endothermic and spontaneous. When the oxygen content of MWCNTs increased from 2.0% to 5.9%, the standard free energy (△ G0 ) became more negative, which implied that the oxygenated functional groups increased the adsorption affinity of MWCNTs for lead. Through calculation of enthalpy (△ H0 ), G0 and free energy of adsorption (Ea ), lead adsorption onto MWCNTs was recognized as a chemisorption process. The chemical interaction between lead and the phenolic groups of MWCNTs could be one of the main adsorption mechanisms due to highly positive correlations between the phenolic groups and K d /SSA or q m /SSA.     

不同材质对催化裂化装置催化剂粉尘粘附性能的试验研究

在三座DN150 mmX1600 mm有机玻璃塔试验装置上,考察了DN15的塑料拉西环、陶瓷拉西环和不锈钢拉西环三种材质填料对催化剂的粘附能力。在催化剂浓度5‰,液相负荷40 L/h,气相负荷80 m3/h的条件下,经过408h的连续运转,结果表明不同材质填料对催化剂的粘附能力均存在饱和状态,粘附在填料上的催化剂不随时间的持续增加而增多。其中,塑料填料对催化剂的粘附能力最强,增重0.125kg;不锈钢填料次之,增重为0.115kg;陶瓷填料最弱,增重为0.055kg。可为相关领域的工业应用提供借鉴和数据支撑。     

Identification of key factors governing chemistry in groundwater near the water course recharged by reclaimed water at Miyun County, Northern China

Reclaimed water was successfully used to recover the dry Chaobai River in Northern China, but groundwater may be polluted. To ensure groundwater protection, it is therefore critical to identify the governing factors of groundwater chemistry. Samples of reclaimed water, river and groundwater were collected monthly at Chaobai River from January to September in 2010. Fifteen water parameters were analyzed. Two kinds of reclaimed water were different in type (Na-Ca-Mg-Cl-HCO3 or Na-Ca-Cl-HCO3 ) and concentration of nitrogen. The ionic concentration and type in river were similar to reclaimed water. Some shallow wells near the river bed had the same type (Na-Ca-Mg-Cl-HCO3 ) and high concentration as reclaimed water, but others were consistent with the deep wells (Ca-Mg-HCO3 ). Using cluster analysis, the 9 months were divided into two periods (dry and wet seasons), and all samples were grouped into several spatial clusters, indicating different controlling mechanisms. Principal component analysis and conventional ionic plots showed that calcium, magnesium and bicarbonate were controlled by water-rock interaction in all deep and some shallow wells. This included the dissolution of calcite and carbonate weathering. Sodium, potassium, chloride and sulfate in river and some shallow wells recharged by river were governed by evaporation crystallization and mixing of reclaimed water. But groundwater chemistry was not controlled by precipitation. During the infiltration of reclaimed water, cation exchange took place between (sodium, potassium) and (calcium, magnesium). Nitrification and denitrification both happened in most shallow groundwater, but only denitrification in deep groundwater.     

“一事不再罚”原则在环保行政处罚中的运用

“一事不再罚”是行政处罚的基本原则之一,在我国,“一事不再罚”原则在《行政处罚法》中有集中体现.本文从我国一事不再罚原则的概念和含义出发,结合环保工作实际,从一事不再罚原则在环保行政处罚中的具体应用方面进行探讨.     

我国城市垃圾处理现状及问题分析

随着人口的增长和人们生活城市生活垃圾产量的增长,成分日趋复杂,危害也日益显露和突出,这种危害不是单方面的因素,而是全方面的因素所引起的,如生活水平质量的提高,消费观的改变,人们总体环保意识的欠缺等等,本文通过分析我国城市垃圾处理现状,提出一些切实可行的方法,一起规范和提高我国垃圾处理水平。     

试论加强环境保护对促进人与自然和谐发展的影响

人与自然的关系,一直是人类关注的焦点。人类对于自身在自然界的地位以及二者之间关系的认识经历了漫长而曲折的过程。大家都非常重视人与自然的和谐相处。随着生产力的发展,人类对自然的征服力量越来越强,但人类从未停止对自然界的保护。党的十六届四中全会提出的构建社会主义和谐社会,不仅对人与人、人与社会的和谐提出了要求,还包括人与自然的和谐共处。显然,人与自然的和谐已成为构建和谐社会的有机组成部分。     

2009—2011年包头市大气中颗粒物浓度分析

本文通过对内蒙古包头市2009—2011年PM10浓度和TSP浓度的测定,分析了大气中颗粒物浓度的含量状况。结果表明：2009年3月到9月份之间,出现6次沙尘天气,并且颗粒物浓度超过大气空气质量三级标准,其中最严重的一次PM10浓度达到1．147mg／m^3。PM10浓度一天的变化中,在下午5时和晚间10时达到两个峰值,分别是1．608mg／m^3和1．882mg／m^3。2010年中十一月份的TSP日平均浓度较高,比八月份TSP浓度高7倍。2011年春季空气中颗粒物污染较重,在沙尘天气发生期间,颗粒物浓度含量较高     

黄河宁蒙河段突发性水污染事件中应急监测探讨

介绍了黄河宁蒙河段近几年突发性水污染事件应急监测基本情况,总结了应急监测的特点、作用,对突发性水污染事件中应急监测中存在的问题进行了重点分析,提出了解决的对策。     

内蒙古畜禽养殖及污染防治现状初步分析

本文在分析内蒙古五类畜禽的养殖总量、养殖区域特点及其污染物排放总量的基础上,初步分析内蒙古目前的养殖业现状,进一步分析判断现有存在的问题.为寻求解决内蒙古畜禽养殖污染防治最佳方案,顺利完成畜禽养殖业污染物减排任务提供基础分析材料.     

铅酸蓄电池生命周期评价

铅酸蓄电池是世界上产量最大、用途最广的一种二次电池。铅酸蓄电池生命周期过程中每一个环节都有可能对环境带来不利影响,评估从生产到废弃处理关键过程中对环境的影响,可以为制定有效的管理政策提供科研支撑。目前,尚缺乏针对我国特色的铅酸蓄电池行业全生命周期评价的研究,造成此行业的污染防治无据可依。因此,本研究针对铅酸蓄电池的生命周期进行评价,通过设定研究目的与范围、收集数据与分析清单、获得影响评价和解释结果,研究了铅酸蓄电池对环境的影响,结果表明铅酸蓄电池在生产环节的板栅浇铸过程和废弃处理环节的脱硫过程应属于管理中着重控制的部分。