A method for determining pyrene in mucus using synchronous fluorimetry with multiple standard additions

A new method was proposed to determine pyrene in mucus, which combined the synchronous fluorimetry with the multiple standard addition method (SFMSA). The method was used to determine pyrene in mucus directly without pretreatment. The method detection limit (MDL) for pyrene in mucus was measured as 0.47 ng/ml with a relative standard deviation of 12.7% (n = 7). The standard addition graph was linear in the range 0.05-50.00 ng/ml (r(2) = 0.9989). SFMSA was validated using a GC/MS method as a reference method, and nice agreement was found. The pyrene in mucus can be directly monitored by SFMSA without solvent extraction of samples. This indicates that SFMSA is more timesaving, less laborious and cheaper than the GC/MS method with solvent extraction. SFMSA has lower MDL and higher average recovery than the GC/MS method.     

成都平原经济圈旅游开发与生态环境保护

本文就成都平原经济圈旅游产业建设中所关注的环境保护问题作出分析和预测,强调在旅游开发的同时,还应对旅游资源的开发利用进行合理规划,并对旅游开发带来的污染和加强治理,实现旅游业的可持续发展。     

考洲洋水环境质量现状及受潮汐影响变化分析

文章应用单因子标准指数法、算术均值多因子指数法和营养状态指数法相结合的方法对当前考洲洋海域海水质量状况进行了评价,并依据考洲洋在潮汐涨、落情况下海水质量的变化,定量分析了考洲洋潮汐对其海水水质的影响。结果表明:磷酸盐、无机氮、石油类是影响考洲洋海域环境质量的主要因子,考洲洋内部海域均处于富营养化状态,总体水质状况为良好以下,潮水的涌入能改善考洲洋的水质状况,涨潮时期各航次的算术均值多因子指数之和比退潮时期平均降低了13.92%。且潮汐的变化对主要污染因子的影响顺序为:无机氮>磷酸盐>石油类,最后提出了考洲洋污染防治的对策和建议。     

洪水灾情评价的脉冲耦合神经网络模型

洪水灾情的评价工作对洪水灾害的分类管理具有重要的指导意义。脉冲耦合神经网络模型应用到洪水灾情评价中是一次新尝试,该方法通过脉冲输出从而调节阈值,并且应用动态阈值来确定洪水灾情的等级。这个方法比传统的BP模型简化了权值的训练,模型更加简便、直观。采用脉冲耦合神经网络模型得出的评价结果同灰色关联法、灰色聚类法、灰色模糊综合法的评价结果进行了比较,表明其用于洪水损失评价具有科学性和实用性。     

Ag_6P_2W_(18)O_(62)/TiO_2/膨胀石墨复合光催化剂的制备及甲基橙的降解

以钛酸四丁酯为钛源、膨胀石墨(EG)为载体,通过溶胶凝胶-浸渍法制备了Ag_6P_2W_(18)O_(62)/TiO_2/EG复合光催化剂。采用SEM,EDS,XRD,FTIR,UV-vis等技术对其进行表征,研究了该催化剂在紫外光及可见光下对甲基橙的降解性能。表征结果显示:Ag_6P_2W_(18)O_(62)被成功负载到TiO_2上且保持Dawson结构;经Ag_6P_2W_(18)O_(62)表面修饰后的复合光催化剂可见光吸收性能增强;EG提供的丰富孔道有利于有机污染物吸附去除。实验结果表明:在甲基橙质量浓度为20 mg/L、催化剂加入量为1.0 g/L、反应温度为25℃的条件下,n(Ag)∶n(Ti)=1∶16时的复合光催化剂(ATE-2)的紫外光、可见光催化活性最佳;紫外光下反应70 min时甲基橙去除率为96.5%,可见光下反应40 h时甲基橙去除率为83.5%;ATE-2使用5次后,反应70 min时,其甲基橙去除率仍为92.5%。     

Photodegradation of 2,4-D induced by NO2- in aqueous solutions：The role of NO2

To elucidate the effect of nitrite ion （NO2^-） on the photodegradation of organic pollutants, a 300 W mercury lamp and Pyrex tubes restricting the transmission of wavelengths below 290nm were used to simulate sunlight, and the photodegradation processes of 2,4-dichlorophenoxyacetic acid （2,4-D） with different concentrations of NO2^- in freshwater and seawater were studied. The effect of reactive oxygen species （ROS） on the photolysis of 2,4-D was also demonstrated using electron paramagnetic resonance （EPR）. The results indicated that the 2,4-D photolysis reaction followed the first-order kinetics in freshwater and seawater under different concentrations of NO2^-. Meanwhile, the photochemical reaction rate of 2,4-D increased with increasing concentration of NO2^-. When the concentration of NO2^- was lower than 23 mg/L, the photodegradation rate of 2,4-D in seawater was higher than that in freshwater. However, when the concentration of NO2^- was reached 230 mg/L, 2,4-D degradation slowed down in seawater. It was important to note that EPR spectra showed NO2 radical was generated in the NO5 solution under simulated sunlight irradiation, indicating that 2,4-D photodegradation could be induced by NO2. These results show the key role of NO2^- in photochemistry and are helpful for better understanding of the phototransformation of environmental contaminants in natural aquatic systems.     

南京市火电厂大气污染防治现状及对策研究

利用现有资料结合问卷调研的方法,分析南京市火电厂大气污染防治状况。结果表明:2014年,南京市火电厂总耗煤量达到2 105万t,燃烧技术以煤粉炉为主;总装机容量为9 423 MW,燃煤与燃气机组装机容量分别约占总装机容量的82%与18%;脱硫以石灰石-石膏法为主,约占总装机容量的93%,脱硝以SCR技术为主,约占81%,除尘以高效静电除尘为主,约占78%。建议通过财政补贴鼓励实施超低排放改造,加大天然气供应提高燃气机组比例,并积极出台政策淘汰老旧设备。     

关于加快番禺区生态环境建设的战略思考

文章对番禺区现存生态环境瓶颈与未来压力进行了系统剖析,重点从环境管理与政策的实践层面入手,深入阐述推进“腾笼换鸟”工作和加强生态环境建设的环保举措,同时从战略规划层面入手提出坚持生态优先、以环境优化经济增长,以“腾笼换鸟”推动番禺经济与生态和谐发展的对策和建议,以期对政府决策和社会经济的可持续发展提供借鉴参考。     

炼油工业推行清洁生产浅析

从清洁生产角度出发,在布局、结构和规模等三个方面分析了炼油工业现状与发展趋势;通过对产业政策相关要求的解读,阐明了炼油工业清洁生产技术导向和管理措施,为推动行业清洁生产发展提供借鉴。     

Historical trends of PCBs and PBDEs as reconstructed in a lake sediment from southern Tibetan Plateau

High-altitude lake sediment can be used as a natural archive to reconstruct the history of pollutants. In this work, the temporal distribution of polychlorinated biphenyls(PCBs) and polybrominated diphenyl ethers(PBDEs) were determined using a high-resolution gas chromatography coupled with high-resolution mass spectrometer(HRGC/HRMS) in an alpine lake sediment core collected from the southern Tibetan Plateau(TP) to examine whether the expected decreasing trends due to the implementation of the ...