利用微型动物削减剩余污泥量的研究

在污水的好氧生物处理过程中会产生大量的剩余污泥。污泥的浓缩、脱水、处理和处置需要花费大量的人力和物力 ,而且如果处置不当 ,很容易对环境造成二次污染。因此 ,最大限度减少剩余污泥的排放成为人们关注的问题。根据生态学的理论 ,加强微型动物对细菌的捕食作用 ,可使能量在从低营养级向高营养级传递过程中有一定的损失 ,同时污泥量得以减少。应用两段式生物反应器或者直接向曝气池中投加微型动物均可达到此目的。本文详细地介绍了这两种方法 ,讨论了各自的优点和不足 ,并指出了未来的发展方向     

A framework for policy formulation for small-scale mines: the case of coal in China

The effective management of small-scale mines is one of the major challenges for governments in the mining sector. Small-scale mining may bring tangible, short-term benefits to the communities involved. However, these benefits are frequently outweighed by the costs incurred in terms of illness, injury, pollution, waste of natural resources and market distortions. Governments, international agencies and advisers are generally able to draw up lists of actions which are required to regulate and manage small-scale mines more effectively, but turning plans into sustained action has proved more difficult. Two aspects of policy implementation are crucial to success: the alignment of interests, and the attitude and effectiveness of government. Using a case study of township and village coal mines in China, this article develops an approach to analysing these issues that could assist regional policy makers and advisers in formulating policy, in identifying key obstacles to policy implementation, and in identifying particular parties which need to be infiuenced or educated in order for the policy to succeed.     

论可持续发展的基本组织单元和层次体系

在可持续发展的实践中，选择合适的基本组织单元和建立适当的管理层次体系非常重要。本文在论述各种区域划分类型的基础上，提出可持续发展的基本组织单元应以行政功能区划为主，选择市（带县）作为可持续发展的基本组织单元，同时要兼顾经济因素和自然因素；在我国以国家、省、市（带县）作为可持续发展实践的三级体系较为适宜；并论述了区域内部和外部的调控和优化     

Synthesis of a novel ternary HA/Fe-Mn oxides-loaded biochar composite and its application in cadmium(Ⅱ) and arsenic(Ⅴ) adsorption

Cadmium(Cd) and arsenic(As) are two of the most toxic elements. However, the chemical behaviors of these two elements are different, making it challenging to utilize a single adsorbent with high adsorption capacity for both Cd(Ⅱ) and As(Ⅴ) removal. To solve this problem, we synthesized HA/Fe-Mn oxides-loaded biochar(HFMB), a novel ternary material,to perform this task, wherein scanning electron microscopy(SEM) combined with EDS(SEMEDS) was used to characterize its morphological and physicochemical properties. The maximum adsorption capacity of HFMB was 67.11 mg/g for Cd(Ⅱ) and 35.59 mg/g for As(Ⅴ),which is much higher compared to pristine biochar(11.06 mg/g, 0 mg/g for Cd(Ⅱ) and As(Ⅴ),respectively). The adsorption characteristics were investigated by adsorption kinetics and the effects of the ionic strength and pH of solutions. X-ray photoelectron spectroscopy(XPS)and Fourier-transform infrared spectroscopy(FT-IR) revealed that chelation and deposition were the adsorption mechanisms that bound Cd(Ⅱ) to HFMB, while ligand exchange was the adsorption mechanism that bound As(Ⅴ).     

南京地区污水厂、自来水厂及长江中抗性基因MCR-1和NDM-1的污染特征

近年来,新型抗性基因以其易传播和耐药广等特性,展现出比传统抗性基因更严峻的健康风险,在临床卫生领域受到广泛关注,但目前对其在环境中的行为和风险研究很少.为此,考察了2种有代表性的新型抗性基因MCR-1和NDM-1的污染特征,并借助荧光定量PCR探索了长江下游（南京段）及附近污水厂和自来水厂中MCR-1和NDM-1的分布特征,进而采用RDA（冗余性分析）评价了分布特征受水质指标的影响效果.结果表明:①污水厂进水中MCR-1和NDM-1绝对丰度较高,且随处理流程呈下降趋势,总去除率分别为92.5%和92.7%,但出水中MCR-1和NDM-1绝对丰度仍分别达2.5×108和7.0×106 copies/L.②长江下游（南京段）各采样点MCR-1和NDM-1绝对丰度的范围分别为8.5×107~3.5×109和4.3×105~2.1×107 copies/L,随水流方向呈降低趋势,但在个别采样点出现异常升高的情况,主要受该区域人为污染的影响.③自来水厂处理工艺对MCR-1和NDM-1去除率分别为75.0%和70.6%,但出水中存留的MCR-1和NDM-1绝对丰度分别达1.4×107和6.3×104 copies/L,且MCR-1和NDM-1在排泥水中大量富集.④MCR-1绝对丰度与ρ（COD_Cr）、ρ（NH₃-N）、电导率呈正相关,而NDM-1绝对丰度仅和浊度存在弱相关关系,与其他水质指标无明显相关性.研究显示,污水处理工艺无法有效去除MCR-1和NDM-1,大量抗性基因通过污水厂出水排入长江,同时自来水厂以含有较高绝对丰度抗性基因的长江水作为水源水,最终自来水厂出水中残存的抗性基因可能进入人体,生态健康风险较大.      

Profiles of and variations in aluminum species in PAC-MC used for the removal of blooming microalgae

Polyaluminum chloride modified clay (PAC-MC) is a safe and efficient red tide control agent that has been studied and applied worldwide. Although it is well known that the distribution of hydrolytic aluminum species in PAC affects its flocculation, little is known about the influence of particulars aluminum species on the microalgae removal efficiency of PAC-MC; this lack of knowledge creates a bottleneck in the development of more efficient MCs based on aluminum salts. The ferron method was used in this study to quantitatively analyze the distributions of and variations in different hydrolytic aluminum species during the process of microalgae removal by PAC-MC. The results showed that Al_a, which made up 5%–20% of the total aluminum, and Al_p, which made up 15%–55% of the total aluminum, significantly affected microalgae removal, with Pearson's correlation coefficients of 0.83 and 0.89, respectively. Most of the aluminum in the PAC-MC sank rapidly into the sediments, but the rate and velocity of settlement were affected by the dose of modified clay. The optimal dose of PAC-MC for precipitating microalgae was determined based on its aluminum profile. These results provide guidance for the precise application of PAC-MC in the control of harmful algal blooms.     

Source emissions and climate change impacts on the multimedia transport and fate of persistent organic pollutants, Chaohu watershed, eastern China

Emission intensity and climate change control the transport flux and fate of persistent organic pollutants (POPs) in multiple environmental compartments. This study applied a multimedia model (BETR model) to explore alternations in the spatio-temporal trends of concentrations and transport flux of benzopyrene (BaP), phenanthrene (Phe), perfluorooctane sulfonates (PFOS) and polychlorinated biphenyls (PCBs) in the Chaohu watershed, located in the lower reaches of the Yangtze River, China in response to changes in source emissions and climate. The potential historic and future risks of these pollutants also were assessed. The results suggest that current trends in concentrations and transport were similar to that of their emissions between 2005 and 2018. During the next 100 years, temporal trends and spatial patterns were not predicted to change significantly, which is consistent with climate change. Based on sensitivity and correlation analyses, climate change had significant effects on multi-media concentrations and transport fluxes of BaP, Phe, PFOS and PCBs, and rainfall intensity was the predominant controlling factor. Risk quotients (RQs) of BaP and Phe-in soil increased from 0.42 to 0.95 and 0.06 to 0.35, respectively, from 2005 to 2090, indicating potential risks. The RQs of the other examined contaminants exhibited little potential risk in soil, water, or sediment. Based on spatial patterns, it was inferred that the ecosystem around Lake Chaohu is the most at risk. The study provides insights needed for local pollution control of POPs in the Chaohu watershed. In addition, the developed approach can be applied to other watersheds world-wide.     

Nano-selenium controlled cadmium accumulation and improved photosynthesis in indica rice cultivated in lead and cadmium combined paddy soils

Selenium nanoparticles (Se NPs) are less toxic and more biocompatible than selenite or selenate. However, studies involving spraying with Se NPs for reducing accumulation of cadmium (Cd) and lead (Pb) in rice grains have been rarely reported as yet. Herein, indica rice seedlings cultivated in Cd+Pb-spiked paddy soils (denoted as positive control) were sprayed with Se NPs sols for four times from tillering to booting stage. Compared to positive control, 50–100 μmol/L Se NPs downregulated Cd transporters-related genes such as OsLCT1, OsHMA2 and OsCCX2 in leaves and OsLCT1, OsPCR1 and OsCCX2 genes in node I at filling stage. Meanwhile, Se-binding protein 1 was distinctly elevated, involving the repression of Cd and Pb transportation to rice grains. Se NPs also differentially improved RuBP carboxylase and chlorophylls especially some key genes and proteins involving photosynthetic system. Besides, 25–50 μmol/L Se NPs diminished reactive oxygen species overproduction from NADPH oxidases whereas boosted glutathione peroxidase, reducing protein carbonylation in rice seedlings. However, the antioxidant isozymes and oxidatively modified proteins were slightly rebounded at 100 μmol/L. Se contents were noticeably elevated and confirmed to exist as selenomethionine in the rice grains following all the treatments by Se NPs. Thus, the optimal dosage of Se NPs for foliar application is 50 μmol/L, which significantly decreased Cd accumulation, improved photosynthesis and Se enrichment whereas caused no distinct reduction of Pb in the grains. Thus, an appropriate dosage of Se NPs can be conducted to decrease Cd accumulation, improve photosynthesis, and organic Se contents in rice grains.     

基于不同周期PM2.5组成高时间分辨观测的PMF源解析研究

于2017年1月1日—12月31日对南京市城区大气细粒子(PM_2.5)化学组分（元素、水溶性离子和碳质组分）的小时质量浓度进行连续观测,采用正矩阵因子分析（Positive Matrix Factorization,PMF）模型分别基于全年观测数据（PMF全年）和逐月观测数据（PMF月份）进行源解析,比较不同观测周期源解析结果的差异以及对PM_2.5各组分浓度估算的准确性.结果表明：不同观测周期下,PMF源解析结果中因子类型未发生改变,但因子组成和贡献分布存在较大差异.由于PMF模型假设同一观测周期内源成分谱不发生变化,只有基于逐月观测数据的PMF源解析才能体现全年范围内因子组成和贡献分布的变化.尽管PMF全年和PMF月份的分析结果均能准确估算PM_2.5组分的月均浓度,但PMF月份结果对各组分小时浓度的估算值和观测值在时间变化上更一致.这是因为PMF模型要求对各组分浓度的平均值进行拟合,易低估（或高估）PM_2.5组分在观测周期内的极大（或极小）值.因此,基于短期（例如,月份）高分辨观测数据的PMF分析...     

中国国土空间规划法律体系：问题检视与框架重构

通过对现行空间规划法律规范的体系性检视,发现由于立法策略、部门立法以及规划立法依附性等原因,其存在顶层立法付之阙如、外部结构冗杂扁平、内部规范碎片冲突等问题。遵循领域法、发展法以及体系化逻辑,国土空间规划立法应以现实问题与治理现代化为导向,在突破部门法壁垒的同时注重法制发展的接续性,力求实现国土空间规划法律体系的形式协调与价值融贯。构建国土空间规划法律体系,对内应确立国土空间规划法的基本法地位并辅之以配套立法,对外应注重与国土空间开发保护法等相关立法、国土空间政策与技术标准的衔接,最终构架起一个主轴明确、层次严密、差序有别的圆锥状国土空间规划法律体系。