基于多元统计的水质动态评价模型研究与应用

给出一种基于多元统计的水质动态评价模型方法,该模型方法以全局主成分分析(GPCA)方法为主,以动态聚类分析、判别分析为辅助方法。再以湟水流域水质断面为例,根据有机污染、无机污染和综合污染等3个方面对这些水质断面1998—2005年水质污染状态进行定量评价和动态分析。研究结果表明:湟水流域水质断面有机污染较为严重,以上3个方面的污染状态逐年严重,综合污染指数均值从1998年的1.63605上升到2005年的2.38624,2001年以后有加速恶化的迹象。     

Estimation of annual potential evapotranspiration at regional scale based on the effect of moisture on soil respiration

Potential evapotranspiration (PET) is an important component of water cycle. For traditional models derived from the principle of aerodynamics and the surface energy balance, its calculation always includes many parameters, such as net radiation, water vapor pressure, air temperature and wind speed. We found that it can be acquired in an easier way in specific regions. In this study, a new PET model (PETP model) derived from two empirical models of soil respiration was evaluated using the Penman-Monteith equation as a standard method. The results indicate that the PETP model estimation concur with the Penman-Monteith equation in sites where annual precipitation ranges from 717.71 mm to 1727.37 mm (R² = 0.68, p = 0.0002), but show large discrepancies in all sites (R² = 0.07, p = 0.1280). Then we applied our PETP model at the global scale to the regions with precipitation higher than 700 mm using 2.5° CMAP data to obtain the annual PET for 2006. As expected, the spatial pattern is satisfactory overall, with the highest PET values distributed in the lower latitudes or coastal regions, and with an average of 1292.60 ± 540.15 mm year⁻¹. This PETP model provides a convenient approach to estimate PET at regional scales.     

树脂包衣肥料残膜对土壤植物的影响及光降解膜肥料的研制

通过盆栽强化试验研究了树脂包衣肥料残膜对土壤容重及作物生长及土壤外观的影响;研究了光降解残膜在自然光下的降解;并探讨了残膜在土壤中的降解与积累模式。结果表明,土壤中残膜含量在0.1%~0.2%范围内时,对作物生长没有负面影响,甚至随着积累量的增加,还有增加作物产量的倾向,但随着土壤中残膜量的增加,对土壤外观有一定影响。添加光降解剂可以显著加快残膜的降解。由于降解现象的存在,残膜在土壤中的量不会无限制增加,而是呈抛物线型积累。残膜在表层土壤中积累的最大量不会超过某一临界值,该值的大小由每年包衣肥料的施用量、残膜露出土表的比例及降解量、损失量决定。     

滤速对慢滤池深度处理生活污水的影响

为进一步提高再生水水质,将慢滤池用于污水二级处理出水的进一步处理。选取浊度、COD、色度和细菌总数4个指标,利用实验室小试装置,研究了0.1、0.3、0.5m/h这3种滤速下慢滤池的性能。结果表明,滤速由0.1m/h升高至0.3m/h时,慢滤池出水水质略有下降。而滤速由0.3m/h升高至0.5m/h时,慢滤池出水水质下降显著。滤速小于等于0.3m/h时,慢滤出水浊度、COD、色度和细菌总数平均为0.4NTU、25.9mg/L、14.9°、5×10^3CFU/mL。慢滤对这4个指标的平均去除率分别为78.6%、36.0%、34.0%、62.3%。为获得优良的水质,建议慢滤池用于污水深度处理时,滤速宜小于0.3m/h。但实际工程中,用户对再生水水质要求不高时,则可适当增大慢滤池滤速。     

重庆市男性PAHs和PAEs暴露与男性精液质量的相关性分析

多环芳烃(polycyclic aromatic hydrocarbons,PAHs)和邻苯二甲酸酯(phthalate esters,PAEs)是三峡库区水中主要有机污染物。为探讨这2类化学物对三峡库区男性精液质量的影响,课题组于2007年在三峡库区6个区县进行了男性生殖健康的流行病学调查。调查中共收集到有效样本1 346例,对所有样本进行了精液常规检测,选取了冬季采样的232例标本进行了尿液中4种PAHs代谢产物和5种PAEs代谢产物含量的检测,并对这些样本的精子细胞凋亡(Annexin V/PI双标法)和精子脱氧核醣核酸(DNA)损伤(彗星电泳法)进行了检测。运用Spearman等级相关,多元线性回归和logisitic回归分析等方法分析了PAHs和PAEs代谢产物与精液常规指标、精子细胞凋亡、精子DNA损伤的相关关系。结果显示,1 346名三峡库区健康男性精液常规5项指标全部达到世界卫生组织(WHO)标准的比率仅为38.9%。PAHs代谢产物的含量与男性精液常规指标间未发现相关关系,但某些PAHs代谢产物水平与精子凋亡参数及精子DNA损伤指标有一定的关联性,随着尿中PAHs代谢产物浓度的增加,正常未发生凋亡的精子减少,精子DNA的损伤增加。未发现PAEs代谢产物与精液各项参数间的相关关系。本研究结果表明,在重庆市健康育龄男性中PAHs与PAEs的暴露与精液常规指标间没有明确的相关关系,但PAHs暴露与精子DNA损伤显著相关。为明确PAHs的暴露对精子DNA的损伤作用,有必要进行较大规模的队列研究以进行验证。     

生活垃圾预处理后续堆肥化通风方式优化研究

以宜昌市垃圾综合处理场预处理后的筛下物为研究对象,研究了不同通风方式对后续堆肥化效果的影响。对堆体温度、pH、堆高、耗氧速率、腐熟度等指标的监测结果表明,通风方式为"每半小时通风8 min,每天开风机8 h。温度降低到35℃时,停止通风"时,后续堆肥化效果最好。     

Fe-pillared bentonite,a stable Fenton catalyst for treatment of petroleum refinery wastewater

Fe-pillared bentonite (Fe-Bent) was prepared by ion exchange as heterogeneous catalyst for degradation of organic contaminants in petroleum refinery wastewater. X-ray diffraction analysis showed the existence of α-Fe₂O₃. The effects of pH, H₂O₂ concentration, and catalyst dosage on the rate of lowering the chemical oxygen demand (COD) were investigated in detail. Removal efficiency of COD can be up to 92% under the following conditions: dosage of Fe-Bent 7 g L^?1, pH value 3, and H₂O₂ concentration 10 mmol L^?1. Fe-Bent showed good stability for the degradation of organics in petroleum refinery wastewater for five cycles. The adsorption of organics in wastewater onto Fe-Bent could be well described by a pseudo-second-order kinetic model.     

Public attitudes and perceptions to the West-to-East Pipeline Project and ecosystem management in large project construction

Ecosystem management addresses transboundary, interdisciplinary and multiparty issues from an ecosystem perspective. In this regard, public participation of ecosystem management is particularly important for achieving a successful outcome. However, public attitudes and perceptions on ecosystem management in project construction are often ignored in the developing countries. Large project construction in China is booming, for example, oil/gasoline pipelines, water diversion projects, highway networks and high-speed railway networks. These projects may have important impacts on China's economy, as well as ecosystems. The perception of local people on these projects is crucial for their safe fulfilment. In this paper, the West-to-East Pipeline Project (WEPP), a large project in China built in 2004 to transport gas from the north-west to the south-east, was used as a case study to examine public participation and perceptions on ecosystem management. Field interviews were conducted in the summer of 2005 for data collection, and logistic regression models were used for data analysis. Modelling results show that public attitudes to WEPP construction are closely related to education, occupation and place of residence. Generally, interviewees with higher education and more involvement in WEPP have a positive attitude. However, local people have a poor understanding of ecological restoration and ecosystem management. For safe implementation of WEPP, some adjunct projects are required to improve the local economy and ecosystem functions, and different economic compensation schemes should be designed for stakeholders by region. Additionally, development strategies, such as offering part-time jobs, education and training to local farmers, are necessary to change attitudes and improve awareness on ecosystem management. It is also important to strengthen public participation in the early stages of project construction.     

2,2’,4,4’-四溴联苯醚对大型溞的毒性效应

以实验室培养的大型溞为受试生物,进行了2,2’,4,4’-四溴联苯醚(BDE-47)对大型溞的48h急性毒性实验和21d慢性毒性实验,并研究了暴露在不同质量浓度和处理时间的BDE-47中,大型溞的抗氧化酶系中的超氧化物歧化酶(SOD)和谷胱甘肽硫转移酶(GST)的酶活性变化。结果表明,BDE-47对大型溞的48h的半致死浓度为1.04mg·L-1,属于高毒物质;在BDE-47慢性毒性实验低浓度处理组中,大型溞的体长及繁殖能力受到了抑制,而高浓度处理组中大型溞的体长及繁殖能力上升,其中第一次产仔数和产卵总数是表征BDE-47慢性毒性的最灵敏参数。随着BDE-47浓度的增加,大型溞SOD和GST活性均呈现出低浓度诱导高浓度抑制的现象。SOD和GST均表现出一定的敏感性,但相对SOD,GST对BDE-47暴露更为敏感。     

移动床生物膜反应器处理生活污水的研究

通过小试规模的移动床生物膜反应器(MBBR)处理陕西科技大学污水处理厂生活污水的实验研究,探讨了水力停留时间、冲击负荷、pH对反应器处理效果的影响。实验结果表明,在HRT为10 h,进水ρ(COD)为300 mg/L,ρ(NH3-N)为35 mg/L,填料体积填充率为35%,pH为7左右时,MBBR反应器对COD、TN的去除率分别为87.38%、68%。