杯芳烃及其衍生物在金属离子分析中的应用

杯芳烃以其特殊的结构和易于衍生化的特点而成为继冠醚和环糊精之后的第3代超分子。章介绍了近几年杯芳烃及其衍生物在碱金属、锕系、镧系、过渡金属等离子分析中的应用。     

Removal of copper from a copper sulphate solution using an ultrasonic-electrolysis process

The application of ultrasonic-electrolysis process for the removal of copper is studied.In the ultrasonic field cavitation acts as jets and agitates the solution and breaks the barrier layer between the cathode surface and the bulk of the solution.Thus increases metal deposition on the cathode surface.The results show that an ultrasonic field is successful for the removal of low copper concentrations in solution.     

新型射汽抽气消声器

介绍了一种自行设计的、新型的汽轮机启动抽气器排汽消声装置，并对其结构原理和设计特点进行了较详细的叙述。应用实践表明，此种消声器降噪效果明显。     

南通市：贯彻《劳动法》的一年

南通市：贯彻《劳动法》的一年姚光谱，唐林森在《劳动法》实施一周年之际，南通市总工会对全市２ｌ９家工矿企业贯彻《劳动法》职业安全卫生情况组织了专题调查。通过调查，总的看来，《劳动法》颁布以后，南通市的工矿企业普遍组织了宣传教育活动，有９０．４％的职工学...     

电子废弃物的再循环利用:企业、政府与公众的角色和责任

电子废弃物不仅种类繁多,而且成分复杂,含有多种有毒、有害物质,已成为固体废物中最大的重金属污染源.长期以来,由于对电子废弃物问题缺乏足够认识和有效管理,电子废弃物对人体健康及生活环境可能构成的危害常常被忽视.实现电子废弃物的再循环利用,关键是明确企业、政府和公众在电子产品设计、生产、消费、回收、处置和再利用整个过程中的相关责任.因此,解决电子废弃物的问题,首先要对相关行为主体的角色进行准确定位.     

对地铁工程风险评估体系框架的研究

地铁工程同一般建设项目相比,受不可预见的水文地质条件、社会环境、施工技术的可靠度、经济发展的程度等多方面因素的影响较重;就必然使地铁工程成为高风险的工程建设项目,然而目前对其风险评估工作还停留在简单的定性和定量的评估水平上。为此,笔者在研究系统论的基础上,从动态系统风险评估的观点出发,运用动态控制的原理,着重研究适合于地铁工程风险评估体系的理论框架,及建立理论框架时应考虑的诸多问题;同时对动态系统风险评估、评价因素可靠性分析技术、各种风险评估方法及评估技术的运用做了简要论述。该框架体系不仅适用于地铁工程的风险评估,同样适用于其他复杂的工程系统的风险评估评价。     

Resource Use Dynamics and Land-Cover Change in Ang Nhai Village and Phou Phanang National Reserve Forest, Lao PDR

This study integrated aerial photographs from 1952, 1981, and 1998, and a satellite image from 2000 with oral histories and socioeconomic surveys to assess changes in forest and land cover in Ang Nhai village, Laos. The study documents the history of resource use and changes in household access to resources in the village. Three distinctive trends were observed in terms of forest and land cover—forest degradation, deforestation, and regeneration. Project results suggest that land and forest cover change dynamically under different circumstances. The case study also points out that integration into the market economy can induce intensification of unused lowland areas, while removing pressures from upland areas previously used for supplementing agricultural production. In addition, the creation of a national reserve forest to restrict local access and forest use was an ineffective tool for regulating encroachment and logging activities.     

Removal of selenate from water by zerovalent iron

Zerovalent iron (ZVI) has been widely used in the removal of environmental contaminants from water. In this study, ZVI was used to remove selenate [Se(VI)] at a level of 1000 microg L(-1) in the presence of varying concentrations of Cl-, SO(2-)4, NO(-)3, HCO(-)3, and PO(3-)4. Results showed that Se(VI) was rapidly removed during the corrosion of ZVI to iron oxyhydroxides (Fe(OH)). During the 16 h of the experiments, 100 and 56% of the added Se(VI) was removed in 10 mM Cl- and SO(2-)4 solutions under a closed contained system, respectively. Under an open condition, 100 and 93% of the added Se(VI) were removed in the Cl- and SO(2-)4 solutions, respectively. Analysis of Se species in ZVI-Fe(OH) revealed that selenite [Se(IV)] and nonextractable Se increased during the first 2 to 4 h of reaction, with a decrease of Se(VI) in the Cl- experiment and no detection of Se(VI) in the SO(2-)4 experiment. Two mechanisms can be attributed to the rapid removal of Se(VI) from the solutions. One is the reduction of Se(VI) to Se(IV), followed by rapid adsorption of Se(IV) to Fe(OH). The other is the adsorption of Se(VI) directly to Fe(OH), followed by its reduction to Se(IV). The results also show that there was little effect on Se(VI) removal in the presence of Cl- (5, 50, and 100 mM), NO(-)3 (1, 5, and 10 mM), SO(2-)4 (5 mM), HCO(-)3 (1 and 5 mM), or PO(3-)4 (1 mM) and only a slight effect in the presence of SO(2-)4 (50 and 100 mM), HCO(-)3 (10 mM), and PO(3-)4 (5 mM) during a 2-d experiment, whereas 10 mM PO(3-)4 significantly inhibited Se(VI) removal. This work suggests that ZVI may be an effective agent to remove Se from Se-contaminated agricultural drainage water.     

Tillage erosion and its effect on soil properties and crop yield in Denmark

Tillage erosion had been identified as a major process of soil redistribution on sloping arable land. The objectives of our study were to investigate the extent of tillage erosion and its effect on soil quality and productivity under Danish conditions. Soil samples were collected to a 0.45-m depth on a regular grid from a 1.9-ha site and analyzed for 137Cs inventories, as a measure of soil redistribution, soil texture, soil organic carbon (SOC) contents, and phosphorus (P) contents. Grain yield was determined at the same sampling points. Substantial soil redistribution had occurred during the past decades, mainly due to tillage. Average tillage erosion rates of 2.7 kg m(-2) yr(-1) occurred on the shoulderslopes, while deposition amounted to 1.2 kg m(-2) yr(-1) on foot- and toeslopes. The pattern of soil redistribution could not be explained by water erosion. Soil organic carbon and P contents in soil profiles increased from the shoulder- toward the toeslopes. Tillage translocation rates were strongly correlated with SOC contents, A-horizon depth, and P contents. Thus, tillage erosion had led to truncated soils on shoulderslopes and deep, colluvial soils on the foot- and toeslopes, substantially affecting within-field variability of soil properties. We concluded that tillage erosion has important implications for SOC dynamics on hummocky land and increases the risk for nutrient losses by overland flow and leaching. Despite the occurrence of deep soils across the study area, evidence suggested that crop productivity was affected by tillage-induced soil redistribution. However, tillage erosion effects on crop yield were confounded by topography-yield relationships.