The effect of thymol and its derivatives on reactions generating reactive oxygen species

The effects of thymol (TOH), thymoquinone (TQ) and dithymoquinone (TQ2) on the reactions generating reactive oxygen species (ROS) such as superoxide anion radical (O2*-), hydroxyl radical (HO*) and singlet oxygen (1O2) were tested using the chemiluminescence (CL) and spectrophotometry methods. All tested compounds acted as scavengers of various ROS. The rate constant of 1O2-dimols quenching by thymol was calculated.     

Confirmation of serial spawning in the chokka squid Loligo vulgaris reynaudii off the coast of South Africa

Ovary maturation and spawning in the chokka squid Loligo vulgaris reynaudii were investigated by collecting squid from across their distributional range on the southeastern coast of South Africa between 1992 and 1993. Based on histological examination of the ovarian tissue and the separation of multiple modes in oocyte size-frequency distribution, ovary development was characterised by eight distinct stages. Our study confirms serial spawning in L. v. reynaudii. Received: 9 October 1998 / Accepted: 22 April 1999     

Nutrients in soil solution following selective logging of a humid tropical ‘terra firme’ forest north of Manaus,Brazil

Sustainable use of the Amazon forest for timber production is conditioned by the effect of logging on the system's nutrient cycling. This paper reports the results of a soil moisture and soil water chemistry monitoring campaign before and immediately after a selective logging which removed 35 m³ wood/ha. Soil moisture was measured using tensiometers, and soil water chemistry using suction samplers in five disturbance classes: tractor tracks, clearing centres, clearing edges, forest edges and untouched forest. The results show that the soil under the tractor tracks and clearings contained more moisture than under the untouched forest. The suction samplers extracted substantially more nitrate, ammonium, calcium, magnesium and potassium from the clearing centres, the tractor tracks and the clearing edges than from the forest sites. The results are explained in terms of altered microbial activity, changes in crown interception and uptake by roots.     

Perception and Attitude of Residents Toward Urban Green Spaces in Guangzhou (China)

Fast economic and social changes in recent years in China have brought massive expansion, redevelopment, and restructuring of cities. These changes offer cities the opportunity to improve environmental quality through urban green spaces (UGSs) and to address the challenges of meeting community aspirations. This study explored peoples’ minds concerning UGSs in Guangzhou city in south China in relation to the following: (1) knowledge and perception of 25 ecosystem services and 8 negative impacts; (2) attitude toward site condition and management; (3) expectation of landscape design; and (4) preference ranking of venues. A questionnaire was designed to solicit opinions from 340 respondents randomly chosen from residents living in the study area. The results indicated widespread recognition of ecosystem services and strong support of UGS programs. Negative responses were weakly expressed. Amelioration of urban microclimate and environmental quality were emphasized. Environmental functions stressed in publicity programs, together with aggravating environmental problems in the city, tended to focus respondents’ attention on UGS benefits. Wildlife habitat, species conservation and other natural ecosystem services drew limited concerns. Awareness of economic benefits was very low. Visual-landscape contributions with strong preference for naturalistic design and recreational benefits were highlighted. Compared with other countries, Guangzhou residents were characterized by visual–scenic–recreation orientation and pragmatic–utilitarian perception of UGSs, reflecting underlying differences in the understanding of inherent ecosystem services of green spaces. Relevant UGS policies and practices could adopt the approaches of market survey, citizen participation, and precision planning in order to meet increasingly mature and refined demands. Citizens’ understanding of high-order ecosystem services could be enhanced to encourage appreciation of nature and their associated benefits.     

Concentrations and activity ratios of uranium isotopes in the groundwater of the Okchun Belt in Korea.

Groundwater samples obtained from the Okchun Belt in Korea were separated into particulate and filtered fraction using a 0.45 microm membrane filter and concentrations and activity ratios of uranium isotopes in the fractions were determined by chemical separation and alpha-spectrometric measurements. Most of the uranium isotopes in the groundwater were found in the filtered water. Only less than 1% of the total uranium was detected in the particulate fraction. The concentrations and activity ratios of uranium isotopes in the groundwater measured in this study were variable, depending upon sampling site. Owing to a rapid material exchange between the subterranean hot waters and the rock strata, the concentrations of 238U in the groundwater in the hot spring area were found to be about four times higher than those elsewhere. Because of the alpha-particle recoil effect, the activity ratios of 234U/238U in the groundwater taken at "cold" spring sites were variable within the range 1.20 to 3.58, depending on the residence time of the groundwater. In the hot spring area, the activity ratios of 234U/238U were close to the equilibrium value (1.10 +/- 0.07) due to rapid erosion of the rock strata by the hot spring water.     

Meteorological effects on the evolution of high ozone episodes in the greater Seoul area

Three high O3 episodes--7 days in 1992 (July 3-July 9), 9 days in 1994 (July 21-July 29), and another 3 days in 1994 (August 22-August 24)--were selected on the basis of morning (7:00 a.m.-10:00 a.m.) average wind direction and speed and daily maximum O3 concentrations in the greater Seoul, Korea, of 1990-1997. To better understand their characteristics and life cycles, surface data from the Seoul Weather Station (SWS) and surface and 850-hPa wind field data covering northeast Asia around the Korean Peninsula were used for the analysis. In the July 1992 episode, westerly winds were most frequent as a result of the influence of a high-pressure system west of the Korean Peninsula behind a trough. In contrast, in the July 1994 episode, easterly winds were most frequent as a result of the effect of a typhoon moving north from the south of Japan. Despite different prevailing wind directions, the peak O3 concentrations for each episode occurred when a sea/land breeze developed in association with weak synoptic forcing. The August 1994 episode, which was selected as being representative of calm conditions, was another typical example in which a well-developed     

NONSTEADY FLOW TO A WELL WITH TIME DEPENDENT DRAWDOWN1

Confined flow toward a single well of finite radius in an extensive aquifer of uniform transmissibility is studied under the assumption of time-dependent drawdown. Three particular cases are considered: (a) linear drawdown (including constant drawdown); (b) exponential drawdown; (c) periodic (sinusoidal) drawdown. The differential equation governing unsteady axial symmetric flow toward a single well in a confined aquifer is solved for the three different situations by the use of the Laplace transform method. The resulting expressions are integrated by adapting a modified Gemant scheme. General computer programs have been developed and operated for several combinations of characteristics. The results are plotted to show the effect of time dependent drawdown on the variation of the well discharge and the piezometric head distribution.     

Free amino acids and osmoregulation in the intertidal pulmonate Onchidium tumidium

The aim of this study is to elucidate the osmoregulatory capabilities of the intertidal pulmonate Onchidium tumidium. Our results indicate that O. tumidium could tolerate hyperosmotic stress more effectively than hypoosmotic stress. In 10% seawater (SW), it was capable of maintaining its plasma hyperosmotic and hyperionic to the external medium. However, it rapidly gained weight in 10% SW, and no restoration of body weight was observed. In contrast, in 90% SW it was able to recover its body weight partially. In a hyperosmotic medium, accumulation of intracellular free amino acids (FAA) was responsible for cell volume regulation. The accumulated FAA might originate from protein catabolism, which occurred in the internal organs (IO). In contrast, the relatively smaller amination:deamination ratio of glutamate dehydrogenase in the body wall (BW) and IO of specimens exposed to hypoosmotic stress might lead to a higher rate of amino acid catabolism. This was supported by the greater ammonia contents in the BW and IO of, and higher rate of ammonia excretion by, specimens exposed to 10% SW. Received: 11 March 1998 / Accepted: 2 May 1999     

Trace Metal Contents (Al, Cu and Zn) of Tea: Tea and Soil from Two Tea Plantations, and Tea Products from Different Provinces of China

The present project aims to investigate the possible contamination of teas with the trace metals: Al, Cu and Zn. Tea bushes sampled from two tea plantations in the northern part of Guangdong Province accumulated higher concentrations of Cu and Zn in young leaves, and of Al in old leaves. The analysis of the three metals in tea produced in different provinces indicated higher Al levels in those obtained from Guangdong and Yunnan Provinces, which may be due to the lower soil pH in these areas. Green tea had the lowest Al concentration among the four types of tea studied, as only the bud and two young leaves are used, whereas older leaves are used for other types of tea (black, Oolong and Puerh tea). The transfer of Al, Cu and Zn from soil to different parts of tea bushes was low in general, except for Zn at Lechang tea plantation which next to a Pb/Zn mine, where a higher transfer was observed from young leaves to tea products, indicating possible metal contamination during tea processing. However, low concentrations of Cu and Zn (less than 0.07 mg Cu L^-1 and 0.17 mg Zn L^-1), and moderate amounts of Al (2.1-2.5 mg L^-1) were obtained in the tea liquor (1% hot water extracts).     

Comparison of PCDD and PCDF in flyash collected from muncipal incinerators of different countries

Flyash samples were collected from the electrostatic precipitators of seven municipal refuse incinerators of four different countries. Analytical results of PCDD and PCDF in these samples shows a very similar iosmer distribution pattern for all PCDD/PCDF although concentrations of PCDD and PCDF vary. These results imply that PCDD/PCDF were formed through the same mechanism in those incinerators regardless of garbage composition or incinerator design.