Determination of optimum polymeric coagulant in palm oil mill effluent coagulation using multiple-objective optimisation on the basis of ratio analysis (MOORA)

The main limitation of a conventional palm oil mill effluent (POME) ponding system lies in its inability to completely decolourise effluent. Decolourisation of effluent is aesthetically and environmentally crucial. However, determination of the optimum process parameters is becoming more complex with the increase of the number of coagulants and responses. The primary objective of this study is to determine the optimum polymeric coagulant in the coagulation–flocculation process of palm oil mill effluent by considering all output responses, namely lignin–tannin, low molecular mass coloured compounds (LMMCC), chemical oxygen demand (COD), ammonia nitrogen (NH₃-N), pH and conductivity. Here, multiple-objective optimisation on the basis of ratio analysis (MOORA) is employed to discretely measure multiple response characteristics of five different types of coagulants as a function of assessment value. The optimum coagulant is determined based on the highest assessment value and was identified as QF25610 (cationic polyacrylamide). On the other hand, the lowest assessment value was represented by AN1800 (anionic polyacrylamide). This study highlights the simplicity of MOORA approach in handling various input and output parameters, and it may be useful in other wastewater treatment processes as well.     

DOMESTIC WASTEWATER TREATMENT BY PEATLANDS IN A NORTHERN CLIMATE: A WATER QUALITY STUDY1

ABSTRACT: The use of peatlands as the main form of wastewater treatment in a northern climate was studied for the James Bay Energy Society. The Fontanges campsite (70° 17′ 30″ W; 54° 34′ 00″ N) was chosen as the study site. In less than 1.5 km from the point of discharge BOD₅, COD, total hardness, inorganic carbon, orthophosphates, total phosphorus, ammonia and total nitrogen were reduced by at least 90 percent. The peatland treatment system studied is divided into four components, each having a specific function. The first part combines the action of microorganisms and adsorption on peat, thus reducing the organic content while increasing the inorganic constituents. The second part uses peat to adsorb the inorganic elements already present in the wastewater and those produced in the first part of the system. The third component acts as an aerator, increasing the dissolved oxygen and decreasing the BOD₅ levels of the water. The fourth part removes most of the remaining nutrients, thus acting like a tertiary treatment. Overall, peatlands seemed to be effective in treating domestic settled wastewater in a cold climate.     

Statistical Analysis of Air Pollutants and Meteorological Parameters in Afyon, Turkey

In this study, the relation between sulfur dioxide (SO₂) and particulate matter (PM) concentrations periodically measured in the city of Afyon’s atmosphere with meteorological factors such as precipitation, humidity, temperature, wind velocity, and inversion were investigated. The mean values of SO₂ and PM concentrations measured during the winter months of October–March 1990–1999 were correlated with the meteorological parameters of the same period. Simple and multiple linear regression analysis were utilized to evaluate the contribution of meteorological variables. The statistical results show that the pollutants, i.e., SO₂ and PM are dependent upon humidity, temperature, and inversion at the 1% significance level; while the dependence of both pollutants with temperature is negative when those of humidity and inversion are positive. Two models in which temperature and inversion are dependent with multiple variables are recommended for predicting the contribution of meteorological parameters on SO₂ and PM. In addition, the relationship between humidity, temperature, and inversion with pollutants is also determined using nonlinear (polynomial) models.     

Identification and source apportionment of polycyclic aromatic hydrocarbons in ambient air particulate matter of Riyadh, Saudi Arabia

In an effort to assess the occurrence and sources of polycyclic aromatic hydrocarbons (PAHs) in the ambient air of Riyadh, Saudi Arabia, PM₁₀ samples were collected during December 2010. Diagnostic PAH concentration ratios were used as a tool to identify and characterize the PAH sources. The results reflect high PM₁₀ and PAH concentrations (particulate matter (PM)?=?270–1,270 μg/m³). The corresponding average PAH concentrations were in the range of 18?±?8 to 1,003?±?597 ng/m³ and the total concentrations (total PAHs (TPAHs) of 17 compounds) varied from 1,383 to 13,470 ng/m³ with an average of 5,871?±?2,830 ng/m³. The detection and quantification limits were 1–3 and 1–10 ng/ml, respectively, with a recovery range of 42–80 %. The ratio of the sum of the concentrations of the nine major non-alkylated compounds to the total (CPAHs/TPAHs) was 0.87?±?0.10, and other ratios were determined to apportion the PM sources. The PAHs found are characteristic for emissions from traffic with diesel being a predominant source.     

Reduced-glutathione concentrations in Boleophthalmus pectinirostris tissues exposed to benzo(a)pyrene

ＩｎｔｒｏｄｕｃｔｉｏｎＢｅｉｎｇａｔｙｐｉｃａｌｐｏｌｙｃｙｃｌｉｃａｒｏｍａｔｉｃｈｙｄｒｏｃａｒｂｏｎｓ(ＰＡＨｓ) ,ｂｅｎｚｏ[ａ]ｐｙｒｅｎｅ(ＢａＰ)ｄｅｓｅｒｖｅｓｓｅｒｉｏｕｓｓｔｕｄｙｂｅｃａｕｓｅＰＡＨｓａｒｅｎｏｗｒｅｃｏｇｎｉｚｅｄａｓｍａｊｏｒｅｎｖｉｒｏｎｍｅｎｔａｌｐｏｌｌｕｔａｎｔｓ .ＥｘｐｏｓｕｒｅｔｏＰａＨｓｉｓｖｉｒｔｕａｌｌｙｕｎａｖｏｉｄａｂｌｅａｎｄｉｓｓｔｒｏｎｇｌｙｓｕｓｐｅｎｄｅｄｏｆｂｅｉｎｇａｃａｕｓａｔｉｖｅｆａｃｔｏｒｉｎｃｅｒｔａｉｎｔｕｍｏ…     

Risk assessment and pathway study of arsenic in industrially contaminated sites of Hyderabad: a case study

Different areas in the industrial region of Patancheru near Hyderabad, Andhra Pradesh (A.P), India are contaminated with high concentration of arsenic, which is attributed to industrial source like veterinary chemicals, pharmaceuticals, pesticide industries, etc. Fourteen villages of this area of Patancheru were assessed for arsenic contamination by collecting samples of water (surface and ground), soil, fodder, milk, and vegetables. The total arsenic content in the whole blood, urine, hair, and nails of the residents showing arsenical skin lesions and other clinical manifestations were also studied. To understand the bioavailability of arsenic in this environment and its possible entry into human food chain, speciation studies of arsenic was carried out and the results are presented in this paper.     

Inhibition, recovery and oxime-induced reactivation of muscle esterases following chlorpyrifos exposure in the earthworm Lumbricus terrestris

Assessment of wildlife exposure to organophosphorus (OP) pesticides generally involves the measurement of cholinesterase (ChE) inhibition, and complementary biomarkers (or related endpoints) are rarely included. Herein, we investigated the time course inhibition and recovery of ChE and carboxylesterase (CE) activities in the earthworm Lumbricus terrestris exposed to chlorpyrifos, and the ability of oximes to reactivate the phosphorylated ChE activity. Results indicated that these esterase activities are a suitable multibiomarker scheme for monitoring OP exposure due to their high sensitivity to OP inhibition and slow recovery to full activity levels following pesticide exposure. Moreover, oximes reactivated the inhibited ChE activity of the earthworms exposed to 12 and 48 mg kg⁻¹ chlorpyrifos during the first week following pesticide exposure. This methodology is useful for providing evidence for OP-mediated ChE inhibition in individuals with a short history of OP exposure (≤1 week); resulting a valuable approach for assessing multiple OP exposure episodes in the field.     

Reduction of heavy metal content in Hiroshima Bay oysters (Crassostrea gigas) by purification

Cultured oysters from Hiroshima Bay were analysed to determine the content of nine trace elements, cadmium (Cd), lead (Pb), chromium (Cr), arsenic (As), manganese (Mn), nickel (Ni), copper (Cu), zinc (Zn), and iron (Fe) and compared with oysters treated for 48 h in both artificial sea water and a solution of 0.5% ethylenediaminetetraacetic acid (EDTA) in artificial sea water. It was found that the values of As and Fe in both groups of treated oysters were significantly lower than in the untreated oysters and that the Pb and Mn levels tended to be lower. It was also found that oysters treated in 0.5% EDTA solution in artificial sea water had lower levels of Cd and Cu than the oysters treated only in artificial sea water.     

Characteristics of urban ozone level in Hong Kong

ＩｎｔｒｏｄｕｃｔｉｏｎＯｚｏｎｅｉｓａｎａｉｒｐｏｌｌｕｔａｎｔｆｏｒｍｅｄｔｈｒｏｕｇｈａｓｅｒｉｅｓｏｆｐｈｏｔｏｃｈｅｍｉｃａｌｒｅａｃｔｉｏｎｉｎｔｒｏｐｏｓｐｈｅｒｅａｎｄｉｓｏｎｅｏｆｔｈｅｍｏｓｔｉｍｐｏｒｔａｎｔｐｈｙｔｏｔｏｘｉｃａｉｒｐｏｌｌｕｔａｎｔｓ.Ｉｎｇｅｎｅｒａｌ,ｄｉｒｅｃｔｅｍｉｓｓｉｏｎｏｆｏｚｏｎｅｆｒｏｍａｎｔｈｒｏｐｏｇｅｎｉｃｓｏｕｒｃｅｓｉｓｎｅｇｌｉｇｉｂｌｅｉｎｔｈｅｆｒｅｅｔｒｏｐｏｓｐｈｅｒｅ .Ａｃｃｏｒｄｉｎｇｔｏｔｈｅｓｔｕｄｙｏｎｆｏｒ…     

Hydrogen sulfide effects on ammonia removal by a biofilter seeded with earthworm casts

Ammonia (NH3) removal efficencies were evaluated when hydrogen sulfide (H2S) and NH3 in binary mixture gases were supplied to a ceramic biofilter seeded with earthworm (Lumbricus terrestris) casts. The effect of inlet H2S concentration and space velocity (SV) on the removal of NH3 was investigated after the acclimation of the biofilter with NH3 gas. When NH3 was singly supplied to the biofilter, NH3 removal was maintained at almost 100% until inlet NH3 concentration was increased up to 600 microL L(-1) and SV up to 330 h(-1), at which the elimination capacity of NH3 was 148 g N m(-3) h(-1). When H2S was supplied simultaneously, however, the accumulation of toxic sulfide ions showed dual effects on NH3 removal efficiencies. First, no effects were observed at inlet H2S loading below 60 g S m(-3) h(-1); however, inhibition by H2S at higher loading was observed above 60 g S m(-3) h(-1). The point at which loading achieved a maximum of more than 99% NH3 removal efficiency was 139 g N m(-3) h(-1), when inlet H2S concentration was held under 100 microL L(-1), but it dropped to 76 and 30 g N m(-3) h(-1) when the inlet H2S concentration increased to 220 and 460 microL L(-1), respectively. The critical points of inlet H2S loading that guaranteed over 99% NH3 removal were determined as 100, 100, 60, and 40 g S m(-3) h(-1) at inlet NH3 concentrations of 100, 200, 400, and 600 microL L(-1), respectively. Inlet NH3 loading had synergic effects of increasing the inhibition of inlet H2S loading on the NH3 removability of the biofilter.