基于双指标多等级的土壤重金属生态风险评价

采用土壤中重金属的全量和有效态双重指标,建立基于多等级综合评估的土壤中重金属生态风险评价模型,将联合概率曲线法引入土壤评价模型,分析重金属暴露浓度与毒性数据的概率分布,考察重金属对土壤生物的毒害程度,从而确定土壤中重金属对于生态系统的风险。建立从简单到复杂的多等级综合评价方法,表征重金属的污染等级、浓度效应、多种重金属污染物的协同效应、不同重金属的毒性效应和土壤对不同重金属污染物的敏感性。选择典型地区采集有代表性的土壤样品,测定不同重金属的总量和有效态,验证评价模型的实用性和评价分级的合理性。旨在解决土壤重金属风险评价的方法学问题,为土壤环境质量管理提供支持。     

基于碳减排目标的省域碳生态补偿研究

基于低碳社会背景和碳减排目标,通过构建生态补偿理论框架,设定补偿模式、衡量准则、标准和补偿系数,建立了省域横向碳生态补偿模型,并对各省份进行了量化实证。结果表明:(1) 2015年,各省(除云南外)碳排放均大于碳吸收量,净碳排放总量达274. 60×103万t;(2)碳排放水平在空间分布上呈从东至西递减的态势,而各省碳汇是造成地均碳排放和建设用地地均碳排放空间分布差异的主要原因;(3)区内14省超出生态补偿阈值2 635. 30万t,以最适补偿水平需支付163. 00亿元,16省未达到生态补偿阈值,可获补偿91. 11亿元;(4)受经济发展水平、生态资源本底、碳排放目标强度等因素影响,生态补偿结果与经济发展水平呈空间同质,整体呈"东付西补"的分布状态。最后从构建以中央为主导的生态补偿模式、建立碳收支账户和完善多样化补偿方式等角度对省域横向碳生态补偿制度的建设提出了建议,以求为政府制定相关政策提供参考。     

金融危机以来我国制造业空间格局演变及转移态势研究

在产业转移及转型升级的背景下,制造业空间分布及转移逐渐成为地理学研究的热点。以2008、2016年我国制造业工业销售产值、从业人数为研究数据,应用区位熵、热点分析、锡尔系数、动态集聚指数等方法,对金融危机以来我国制造业空间格局演变及转移态势进行探究。研究发现：（1）我国制造业空间分布具有较强的时空异质性,劳动密集型与资本密集型制造业以及技术密集型与知识密集型制造业分别呈现“西密东疏”、“东密西疏”的空间分异格局,并且不同类型的制造业空间集聚态势也存在显著差异;（2）东部地区的烟草制品、化学纤维等制造业发展不平衡问题较为突出,对我国区域间与区域内制造业空间分布差异的影响较大,而中、西部地区则相对较小,但有逐渐扩大的趋势;（3）制造业转移的主体是劳动密集型与资本密集型制造业,转移的方向是从东部向中、西部地区,转移层次具有较高的梯度性。研究有助于丰富我国制造业空间分布及转移相关理论,为我国经济、产业高质量发展提供借鉴意义。     

聚苯乙烯/CdS/TiO_2双壳层核壳纳米颗粒可见光催化降解甲基橙

采用溶胶-凝胶法,在聚苯乙烯(PS)/CdS核壳纳米颗粒表面包覆致密TiO_2层,制备出具有双壳层结构的PS/CdS/TiO_2纳米复合颗粒,考察了制备条件对材料结构的影响,并利用甲基橙溶液对其光催化性能进行了评价。SEM、TEM、XRD和FTIR分析结果表明,制得的微球单分散性良好,壳层包覆完整,厚度均匀。PS/CdS/TiO_2制备的适宜反应时间为12~18 h,适宜反应pH为7~9。PS/CdS/TiO_2较PS/CdS具有更为优异的可见光催化性能。     

Effects of humic acids derived from lignite and cattle manure on antioxidant enzymatic activities of barley root

To investigate the effects of humic acids (HAs) on the ability of plants to defend themselves against oxidative stress, barley was hydroponically cultured in the absence and presence of HAs, and the antioxidant enzymatic activities (catalase, superoxide dismutase, ascorbate and glutathione peroxidases) of root tissue were evaluated. Auxin-like structures in HAs, which were extracted from an oxidation product of lignite (LHA) and compost derived from cattle manure (CHA), were identified by pyrolysis-gas chromatography/mass spectrometry (GC/MS) with tetramethylammonium hydroxide. The LHA, which had the lower molecular weight, was more effective in promoting the growth of barley root than CHA. However, the amounts of auxin-like structures in the CHA were much higher than those for LHA. The antioxidant enzymatic activities were initially decreased in the presence of LHA and CHA at the first day after refreshing the culture solution, but were significantly increased on the second day. The CHA sample, which contained relatively high levels of phenolic acids that contained auxin-like structures, was effective in increasing four types of enzymatic activities, while the activities of catalase and ascorbate peroxidase were increased in the presence of LHA, which contains naphthalene derivatives. These results indicate that using HAs as a supplement can be effective in enhancing antioxidation enzymatic activities, while the appearance of the effects is retarded because of the decomposition and release of auxin-like compounds from HAs by organic acids from the plant roots.     

Research and application of method of oxygen isotope of inorganic phosphate in Beijing agricultural soils

Phosphorus (P) in agricultural ecosystems is an essential and limited element for plants and microorganisms. However, environmental problems caused by P accumulation as well as by P loss have become more and more serious. Oxygen isotopes of phosphate can trace the sources, migration, and transformation of P in agricultural soils. In order to use the isotopes of phosphate oxygen, appropriate extraction and purification methods for inorganic phosphate from soils are necessary. Here, we combined two different methods to analyze the oxygen isotopic composition of inorganic phosphate (δ¹⁸O_P) from chemical fertilizers and different fractions (Milli-Q water, 0.5 mol L^?1 NaHCO₃ (pH = 8.5), 0.1 mol L^?1 NaOH and 1 mol L^?1 HCl) of agricultural soils from the Beijing area. The δ¹⁸O_P results of the water extracts and NaHCO₃ extracts in most samples were close to the calculated equilibrium value. These phenomena can be explained by rapid P cycling in soils and the influence of chemical fertilizers. The δ¹⁸O_P value of the water extracts and NaHCO₃ extracts in some soil samples below the equilibrium value may be caused by the hydrolysis of organic P fractions mediated by extracellular enzymes. The δ¹⁸O_P values of the NaOH extracts were above the calculated equilibrium value reflecting the balance state between microbial uptake of phosphate and the release of intracellular phosphate back to the soil. The HCl extracts with the lowest δ¹⁸O_P values and highest phosphate concentrations indicated that the HCl fraction was affected by microbial activity. Hence, these δ¹⁸O_p values likely reflected the oxygen isotopic values of the parent materials. The results suggested that phosphate oxygen isotope analyses could be an effective tool in order to trace phosphate sources, transformation processes, and its utilization by microorganisms in agricultural soils.     

复合链式结构下中国林业碳库系统测度模型构建

温室气体上升导致的全球气候变暖问题不容忽视,增加森林碳汇和木质林产品碳储是缓解温室效应的有效途径。根据森林碳汇功能与林产品碳储功能的关联理论与模型,推导和改进包括森林子碳库、土壤子碳库及木质林产品子碳库在内的林业碳库核算模型及方法,以实现目标碳从森林碳库向木质林产品碳库的过渡与转移。基于气候变化背景下森林-林产品产业链的发展现状,构建包括森林子碳库和林产品子碳库的复合一体化林业碳库模型,使之为中国林业碳库的计量与评价提供判据。首先,对包含森林子碳库和木质林产品子碳库在内的世界林业碳库的发展现状进行探讨,归纳和比较国内外主流的关联林业碳库评估方法模型,从而对中国林业碳库模型的构建提供理论背景支持和逻辑方法支撑。其次,分析现有中国林业碳库评估存在的优势和弊端,找出适合中国林业特点的国家碳库创新评估路径,运用政府间气候变化专门委员会指定的生产法的思路,通过分析目标碳在林产品产业链生产、加工等过程中的流入和支出,提出创新中国林业碳库的模型构想并对其系统内涵进行分析。最后,赋予中国林业碳库系统模型数学表达,分析其数理结构并进行逻辑演绎,在森林子碳库和木质林产品子碳库两个复合链式体系下构建中国林业碳库系统测度模型(ForestProducts Carbon Model/FPCM)。     

环境约束下大都市城郊土地利用结构评价——基于信息熵和非期望产出模型分析

土地利用过程中会产生期望和非期望产出,针对以往土地利用结构评价中忽略环境产生的非期望产出而影响土地利用结构效率真实性问题,以大都市城郊的上海青浦区为例,宏观上,运用信息熵模型对该区2005~2014年土地利用结构有序性进行评价;微观上,运用非期望产出模型测算青浦区研究期间土地利用结构效率,为寻求区域土地利用结构效率损失的原因及改善途径提供参考。结果表明:(1)2005~2014年青浦区土地利用结构信息熵值时序上呈现"M"形变化趋势,空间上由中部向东西两翼递减;(2)2005~2014年青浦区土地利用结构效率变化趋势在时间序列上呈现"W"形变化趋势,空间上由中部的中心城区向东西两翼递减格局;(3)将环境的负产出纳入非期望产出模型进行土地利用结构效率评价,能更加准确的反映土地利用结构效率的真实性;(4)影响青浦区土地利用结构效率水平变化的主要因素为纯技术效率的变化,资源过度消耗和环境污染物排放过量是制约青浦区土地利用结构效率提升的主要原因。针对土地利用结构效率损失的原因及区域差异提出效率提升途径。研究结果可为青浦区土地利用结构优化和可持续发展提供科学借鉴。     

Levels and distribution of Dechloranes in sediments of Lake Taihu,China

The occurrence and spatial distribution of dechloranes including mirex, dechlorane plus (DP), dechlorane (Dec) 602, Dec 603, and Dec 604 in surficial sediments of Lake Taihu were investigated in this study. The concentrations of mirex and DP ranged from below detection limit (BDL) to 1.29 ng g^?1 dw and 0.051 to 2.10 ng g^?1 dw, respectively. Dec 602, Dec 603, and Dec 604 on the other hand, were BDL in any of the samples. The contamination levels of DP were higher than that of Mirex at 21 of all 22 sampling sites. Levels of mirex and DP in the lake sediments were correlated when an extremely high mirex value was removed. Both mirex and DP levels were correlated with the amount of organic matters in the sediment samples. Spatial distribution of mirex and DP suggested that these two chemicals in the lake had similar input sources except for one site. Comparison to previously reported flame retardants’ levels in the sediments shows that DP levels were similar with the levels of tetrabromobisphenol A, hexabromocyclododecane but lower than PBDEs and organophosphates levels in Lake Taihu. The higher levels in the north-east part of Lake Taihu adjacent to two major cities: Wuxi and Suzhou, indicated that city effluent might be a major source for DP contamination in the lake.     

隔膜压滤机滤室最优空腔厚度

利用UG软件对隔膜压滤机滤室内流体进行三维建模,导入Gambit中进行网格划分及边界条件的设定,结合Fluent选用RNG k-ε湍流模型,采用多孔介质模型模拟隔膜压滤机滤室内固-液两相流分离,得到不同空腔厚度下滤室内流体的体积分数轮廓图、压强云图,得出滤饼含水率与空腔厚度大小的关系。实验结果表明,模拟和实验结果具有较好的一致性。在压滤机滤室空腔厚度为12 mm时,滤饼含水率为48%,每天污泥处理量为102 t,隔膜压滤机工作效率最高。