电-多相催化氧化法处理桉木CTMP模拟废水

提出一种基于复极性固定床反应器的有机废水处理新技术--电-多相催化氧化技术,用于桉木CTMP模拟废水的处理.以γ-Al2O3为载体,采用等体积浸渍法制备活性组分为氧化铜的催化剂,用于实验废水的处理.结果表明,在一定的操作条件下,E-HCR(电-多相催化体系)对鞣酸的降解效果明显好于传统的BPBC(复极性固定床电解槽).在外加电压20V、支持电解质质量浓度1000mg/L、pH值为5.35的条件下.降解初始质量浓度为100 mg/L的鞣酸,去除率大于90%.鞣酸降解前后的紫外和红外光普分析表明:鞣酸经电-多相催化氧化处理后,分于中的酚羟基显著减少,分子中的大部分苯环结构开环降解成小分子物质.研究表明所研制的催化剂对鞣酸的电化学降解有很好的催化效果.     

施用不同磷肥对植烟土壤中磷的淋失和有效磷的影响

采用土柱淋溶模拟试验和室内培养试验,研究不同磷肥施入土壤后磷的淋失和有效磷的变化.结果表明,在施磷量为35 mg/kg条件下,整个淋洗期间,钙镁磷肥、磷酸二氢钙、磷酸一氧铵、磷酸二氢铵、磷酸二氢钾5种肥料磷的淋失率很低;各处理从上而下各层土壤的Olsen-P质量比略有增加.施磷量为60 mg/kg、110 mg/kg、170mg/kg、230 mg/kg时.潮砂田肥料磷的淋失率分别为0.26%、0.74%、2.12%和3.17%;灰泥田肥料磷的淋失率分别为0.79%、1.31%、1.60%和1.94%.钙镁磷肥施人各种土壤后,随着培养时间的延长,土壤有效磷质量比逐渐增加,80 d后达到峰值并趋于稳定;磷酸二氢钾、磷酸二氧铵、磷酸一氢铵和磷酸二氢钙施人上壤后,土壤有效磷质量比逐渐降低,至培育60 d后.变化趋于平缓.不同土壤类型对磷的吸附固定率从大到小为潮砂田、灰泥田.     

粉尘危害事件调查分析

在国内外粉尘危害事件频发的背景下,本文通过系统收集国内外报道的典型粉尘危害事件,探讨了粉尘危害事件的基本特征,并从政府、企业和技术发展3个层面对造成这些粉尘危害事件的成因进行分析。     

基于连通法的甲烷简化机理构筑研究

采用连通法,针对甲烷复杂反应机理,成功地进行了不同水平的机理简化研究。通过建立组分依赖关系的正规化Jacobian矩阵,精确地查明了燃烧组分之间的耦合关系,分别构造出仅包含重要化学路径的两个动力学简化模型,获得的简化机理分别包含227和138个反应,分别涉及39和26种组分。通过对层流预混火焰结构的模拟,所得简化机理和原详细反应动力学机理关于火焰结构的计算吻合很好,计算结果显示,两个简化机理具有较高的模拟精度。     

100起CNG加气站事故的统计分析及对策研究

本文统计了100起CNG加气站典型事故案例,从事故发生的位置、事故类型和事故损失等方面,分析了CNG加气站事故的特点。总结了CNG加气站存在的主要安全问题：CNG气质问题、高压储气容器安全问题、CNG汽车气瓶问题、压缩机问题和售气系统安全问题。并提出了保证加气站安全运行的对策措施：提高加气机安全、提高储气系统质量、解决CNG汽车气瓶问题、提高压缩机质量、提高CNG加气站气质、加强加气站的安全管理。售气系统、高压储气系统、天然气压缩系统是较为危险的系统,应对其进行重点管理。     

某鞋业公司一起不明爆炸事故的分析、处置与预防对策

对某鞋业有限公司发生的一起爆炸事故进行了分析,找出了导致爆炸事故的根源是操作人员不了解氧化剂与易燃、可燃物的混触危险性,将丙酮等有机废料与少量双氧水混合后,形成了对热、撞击、摩擦敏感度非常高的熵炸药（TATP）。处理TATP的最大难点是其敏感性太高,少有不慎,即会发生爆炸,导致人员伤亡事故。特别是打开桶盖过程中,螺纹中可能存有干燥的TATP,桶盖旋转过程中可能发生爆炸。根据TATP和废料的特性,制定了现场存留危险性废料的处置方案并进行了处理,提出了防范该类事故的措施。     

刚性桩复合地基的理论、实测与安全性研究

科学合理的设计理论是工程安全性和经济性的保障,现场监测是确保工程安全和质量最有效的手段。本文以提高刚性桩复合地基工程的安全性为目的,围绕关乎建筑物安全的“沉降量”等参数指标,从设计理论与试验监测两个方面开展研究。本文完善了刚性桩复合地基的设计理论,通过现场监测试验取得了第一手的数据资料,可作为今后类似工程的设计和施工参考。本研究为进一步提高刚性桩复合地基的安全性提供了理论和实践保障。     

Aerobic degradation of methyl tert-butyl ether by a Proteobacteria strain in a closed culture system

The contamination of methyl ten-butyl ether （MTBE） in underground waters has become a widely concerned problem all over the world. In this study, a novel dosed culture system with oxygen supplied by H2O2 was introduced for MTBE aerobic biodegradation. After 7 d, almost all MTBE was degraded by a pure culture, a member of β-Proteobacteria named as PMI, in a closed system with oxygen supply, while only 40% MTBE was degraded in one without oxygen supply. Dissolved oxygen （DO） levels of the broth in closed systems respectively with and without H2O2 were about 5-6 and 4 mg/L. Higher DO may improve the activity of monooxygemase, which is the key enzyme of metabolic pathway from MTBE to tert-butyl alcohol and finally to CO2, and may result in the increase of the degrading activity of PM1 cell. The purge and trap GC-MS result of the broth in closed systems showed that tea-butyl alcohol, isopronol and acetone were the main intermediate products.     

Oxidative stress and DNA damages induced by cadmium accumulation

Experimental evidence shows that cadmium （Cd） could induce oxidative stress and then causes DNA damage in animal cells, however, whether such effect exists in plants is still unclear. In the present study, Vicia faba plants was exposed to 5 and 10 mg/L Cd for 4 d to investigate the distribution of Cd in plant, the metal effects on the cell lipids, antioxidative enzymes and DNA damages in leaves. Cd induced an increase in Cd concentrations in plants. An enhanced level of lipid peroxidation in leaves and an enhanced concentration of H2O2 in root tissues suggested that Cd caused oxidative stress in Vicia faba. Compared with control, Cd-induced enhancement in superoxide dismutase activity was significant at 5 mg/L than at 10 mg/kg in leaves, by contrast, catalase and peroxidaseactivities were significantly suppressed by Cd addition. DNA damage was detected by neutral/neutral, alkaline/neutral and alkaline/alkaline Comet assay. Increased levels of DNA damages induced by Cd occurred with reference to oxidative stress in leaves, therefore, oxidative stress induced by Cd accumulation in plants contributed to DNA damages and was possibly an important mechanism of Cd-phytotoxicity in Vicia faba plants.     

Antioxidant responses to benzo[a]pyrene, tributyltin and their mixture in the spleen of Sebasticus marmoratus

It has been reported that there is an interaction between Benzo[a]pyrene （BaP）, a widespread carcinogenic polycyclic aromatic hydrocarbon, and tributyltin （TBT）, an organometal used as an antifouling biocide. This study was therefore designed to examine the potential in vivo influence of BaP, TBT and their mixture on splenic antioxidant defense systems of Sebastiscus marmoratus. The fish were exposed to water containing environmentally relevant concentrations of BaP, TBT and their mixture. Spleens were collected for biochemical analysis after exposure for 7, 25, 50 d and after recovery for 7, 20 d. Cotreatment with BaP and TBT for 7 d potentiated the induction of glutathione peroxidase （GPx） activity by BaP or TBT alone. The cotreatment for 25 and 50 d resulted in inhibition of GPx activity, which was similar to the effect of TBT. Splenic glutathione S-transferase （GST） activities were significantly elevated in S. marmoratus exposed to BaP starting from 7 d and remained high up to 25 d. However, no further activity change was found with prolonged exposure. Cotreatment of BaP and TBT primarily inhibited the GST activity, which was similar to the effect of TBT. Cotreatment with BaP and TBT for 25 or 50 d potentiated the depletion of GSH （glutathione） by BaP or TBT alone. MDA （malondialdehyde） contents in spleen of S. marmoratus were not significantly altered compared with the control during the test period. Spleen, as an immune organ, is sensitive to exposure of BaP or TBT. It should have an effective mechanism to counteract oxidative damage. Antioxidative defense systems in spleen of S. marmoratus should be considered as potential biomarkers. Short-term exposure of BaP or TBT could result in induction of antioxidant defense system. A significant decrease of these indices, such as GSH, GST, GPx might indicate more severe contamination.