钢渣湿法脱硫试验研究

以某厂钢渣为吸收剂,以旋流板塔为吸收器,对湿法脱硫进行了试验研究。通过分析钢渣脱硫前后的化学成分变化,以及试验脱硫率随反应过程的变化,提出了钢渣湿法脱硫的反应机理。同时,试验研究了液气比、进气SO_2浓度、浆液浓度等主要参数对脱硫率的影响,以及加添加剂的效果。试验结果表明,通过合理的设计和适当的操作,可使钢渣湿法应用于中低脱硫率(50％～70％)的场合,以取得综合治理、以废治废的效果。     

以浮游植物评价金堂水库富营养化

通过对浮游植物的生物量、优势种、初级生产力、叶绿素ａ等指的分析，判断金堂水库质已达富营养化水平；网箱养鱼是产生富营养化的主要原因；富营养化对水库功能的不利影响将是很骓消除的。     

一种新的拓扑指数及其在有机化合物结构/性质相关性研究中的应用

以距离矩阵为基础，提出一种表征化合物分子结构的拓扑指数，并将其用于预报饱和链烃类、醇类和含氮芳香类化合物的性质和活性，获得了满意的结果。     

预处理方法对供应态LD钢超塑性压缩性能的影响

研究了国产新型冷作模具钢LD钢(7Cr7Mo3V2Si)经球化退火与循环退火后的超塑性压缩的力学特性.试验结果表明,经循环退火后的LD钢,其超塑性压缩性能优于球化退火,而且其最佳超塑性压缩的工艺参数也存在差异.     

SBR法处理中药材有机废水工艺研究

应用ＳＢＲ法对中药材有机废水进行了研究。考察了ＣＯＤＣＲ、ＢＯＤ５、ＳＳ、ＮＨ３－Ｈ的处理效果，以及ＰＨ、水温、污泥负荷等条件对去除率的影响。运行结果表明，ＰＨＯ ６．０－９．０、ｔ为１５－３０℃、污沁荷０．３ｋｇＢＯＤ５／ｋｇＭＬＳＳ．ｄ，运行程序：进水０．５ｈ（限制曝气）、曝气１０ｈ、脱氮１．５ｈ，沉降０．５ｈ，排水０．５ｈ、闲置１１ｈ，周期时间２４ｈ时ＣＯＤＣＲ去除率８８％、ＢＯＤ５９４％、     

信息时代环境监测档案规范化管理思考——以四川省环境监测总站为例

信息时代的到来,传统的档案工作业务环节发生了转变,环境监测档案也不例外。以纸质档案为核心的传统管理模式逐步转变为电子文件的管理模式。本文以四川省环境监测总站环境监测档案为例,分析环境监测档案管理现状、存在的问题并提出环境监测档案规范化管理措施与对策。     

Penetration of polar brominated DBPs through the activated carbon columns during total organic bromine analysis

Total organic bromine (TOBr) is a collective parameter representing all the brominated organic disinfection byproducts (DBPs) in water samples. TOBr can be measured using the adsorption-pyrolysis method according to Standard Method 5320B. This method involves that brominated organic DBPs are separated from inorganic halides and concentrated from aqueous solution by adsorption onto the activated carbon (AC). Previous studies have reported that some commonly known brominated DBPs can partially penetrate through the AC during this adsorption step. In this work, the penetration of polar brominated DBPs through AC and ozone-modified AC was explored with two simulated drinking water samples and one chlorinated wastewater effluent sample. Polar brominated DBPs were selectively detected with a novel precursor ion scan method using electrospray ionization-triple quadrupole mass spectrometry. The results show that 3.4% and 10.4% of polar brominated DBPs (in terms of total ion intensity) in the chlorinated Suwannee River fulvic acid and humic acid samples, respectively, penetrated through the AC, and 19.6% of polar brominated DBPs in the chlorinated secondary wastewater effluent sample penetrated through the AC. The ozone-modification of AC minimized the penetration of polar brominated DBPs during the TOBr analysis.     

放电作用下四氯化碳的吸附、脱附及降解特性

考察了填充式反应器中放电对四氯化碳（CCl₄）的吸附、脱附作用影响．结果表明,放电作用下CCl₄在反应器中的移动速度加快,穿透时间的从17min缩短到6min,脱附时间约从60min缩短至14min,反应器对CCl₄的吸附能力显著下降;脉冲电压峰值越高,CCl₄吸附一脱附速率越快,降解效率越高．载气成分对CCl₄影响,在电压为50kV的条件下,分别以氮气和氧气作载气,CCl₄的降解效率可达69.1％和97.6％;放电可对吸附剂起脱附再生作用,具有放电脱附速率快、工艺简单等特点,有较好的应用前景．     

浅析珠三角地区有机废气治理技术的开发应用

珠江三角洲地区大气污染最明显的特点就是臭氧浓度的升高导致大气氧化性增强,而挥发性有机化合物(VOCs)和氮氧化物是大气臭氧生成的重要前体物。珠三角地区工业体系发达,VOCs的生产及使用企业众多,由于VOCs的种类繁多,性质各异,排放条件多样,目前已经形成了一系列的VOCs废气实用治理技术。     

Aquatic predicted no-effect concentration for three polycyclic aromatic hydrocarbons and probabilistic ecological risk assessment in Liaodong Bay of the Bohai Sea, China

Predicted no-effect concentration (PNEC) is often used in ecological risk assessment to determine low-risk concentrations for chemicals. In the present study, native marine species were selected for toxicity testing. The PNECs for three polycyclic aromatic hydrocarbons (PAHs), specifically phenanthrene (Phe), pyrene (Pyr), and benzo[a]pyrene (BaP), were derived from chronic and acute toxicity data with log-normal statistical methods. The achieved PNECs for Phe, Pyr, and BaP were 2.33, 1.09, and 0.011 μg/L, respectively. In Jinzhou Bay and the Shuangtaizi River Estuary of Liaodong Bay in the Bohai Sea, China, the surface water concentrations of the three PAHs were analyzed by gas chromatography–mass spectrometry. Based on two probabilistic ecological risk assessment (PERA) methods, namely probabilistic risk quotient and joint probability curve, the potential risk of Phe, Pyr, and BaP in Jinzhou Bay and Shuangtaizi River Estuary was assessed. The same order of ecological risk (BaP > Phe > Pyr) was found by both models. Our study considered regional characteristics of marine biota during the calculation of PNECs, and the PERA methods provided probabilities of potential ecological risks of chemicals. Within the study area, further research on BaP is required due to its high potential ecological risk.