初始pH值对连续投加铝盐混凝去除小分子有机物的影响机制

以污水厂二级出水中小分子有机物强化混凝去除为目的,提出了连续投加混凝工艺(CDC),并以水杨酸为模型小分子有机物,研究了初始pH值对CDC工艺去除效果的影响以及铝离子与水杨酸的络合特性.结果表明,初始pH值6时CDC工艺的去除率最高,比常规混凝工艺提升了13.8%.但是初始pH值5和7时CDC工艺的提升效果较小.三维荧光结果表明,不同pH值下水杨酸和铝离子的络合特性不同.X射线光电子能谱和电喷雾质谱结果表明,pH值5时CDC工艺前期主要生成1:1络合物Al(OH)(C₇H₄O₃)(H₂O)₂.其络合作用强烈,稳定性较高,难以从水中去除.pH值6时前期主要生成中等聚合铝(如原位Al₁₃),其与水杨酸形成的络合物可以参与到铝离子的生长过程,最终生成表面崎岖形态松散的珊瑚礁状絮体,强化了水杨酸的去除.pH值7时,主要生成不定形氢氧化铝,通过絮体表面吸附小分子有机物.     

Cross-boundary transport and source apportionment for PM2.5 in a typical industrial city in the Hebei Province, China: A modeling study

Cross-boundary transport of air pollution is a difficult issue in pollution control for the North China Plain. In this study, an industrial district (Shahe City) with a large glass manufacturing sector was investigated to clarify the relative contribution of fine particulate matter (PM_2.5) to the city's high levels of pollution. The Nest Air Quality Prediction Model System (NAQPMS), paired with Weather Research and Forecasting (WRF), was adopted and applied with a spatial resolution of 5 km. During the study period, the mean mass concentrations of PM_2.5, SO₂, and NO₂ were observed to be 132.0, 76.1, and 55.5 μg/m³, respectively. The model reproduced the variations in pollutant concentrations in Shahe at an acceptable level. The simulation of online source-tagging revealed that pollutants emitted within a 50-km radius of downtown Shahe contributed 63.4% of the city's total PM_2.5 concentration. This contribution increased to 73.9±21.2% when unfavorable meteorological conditions (high relative humidity, weak wind, and low planetary boundary layer height) were present; such conditions are more frequently associated with severe pollution (PM_2.5 ≥ 250 μg/m³). The contribution from Shahe was 52.3±21.6%. The source apportionment results showed that industry (47%), transportation (10%), power (17%), and residential (26%) sectors were the most important sources of PM_2.5 in Shahe. The glass factories (where chimney stack heights were normally < 70 m) in Shahe contributed 32.1% of the total PM_2.5 concentration in Shahe. With an increase in PM_2.5 concentration, the emissions from glass factories accumulated vertically and narrowed horizontally. At times when pollution levels were severe, the horizontally influenced area mainly covered Shahe. Furthermore, sensitivity tests indicated that reducing emissions by 20%, 40%, and 60% could lead to a decrease in the mass concentration of PM_2.5 of of 12.0%, 23.8%, and 35.5%, respectively.     

磺胺嘧啶和盐酸四环素对四种赤潮藻生长的影响

本文以锥状斯氏藻（Scrippsiella trochoidea）、米氏凯伦藻（Karenia mikimotoi）、球形棕囊藻（Phaeocystis globosa）、中肋骨条藻（Skeletonema costatum）为研究对象,实验室条件下对比研究了磺胺间二甲氧嘧啶钠（SMS）和盐酸四环素（TC）暴露下4种赤潮藻的细胞增长、光合色素组成以及最大光能转化效率（Fv/Fm）等的变化规律。研究结果表明:4种赤潮藻在SMS和TC（7.5～240 mg/L）暴露组细胞密度均未出现半抑制效应,SMS对4种赤潮藻细胞密度的最大抑制效应范围为5.47%～36.26%,略高于TC的最大抑制效应0～35.21%（球形棕囊藻无抑制效应）;藻细胞叶绿素含量在抗生素暴露下均显著下降,但作为抗氧化剂和捕光色素的类胡萝卜素含量则显著增加;低浓度（<50 mg/L）TC暴露下,4种赤潮藻Fv/Fm均显著下降;TC（<30 mg/L）暴露下,4种赤潮藻细胞密度最大促进作用范围为11.30%～38.89%,球形棕囊藻细胞密度增加比例最高;赤潮藻对抗生素的响应存在显著的种间差别,两种抗生素暴露对球形棕囊藻生长的抑制效应明显低于其他3种赤潮藻,高浓度抗生素残留对浮游植物群落演替存在较强的干扰作用。     

Highly Oriented Thermoplastic Poly (vinyl alcohol) Films by Uniaxial Drawing: Effect of Stretching Temperature and Draw Ratio

Journal of Polymers and the Environment - With the advantages of excellent processability and biodegradability, polyvinyl alcohol (PVA) becomes an environmentally friendly and biocompatible...     

浑河流域底栖动物生物完整性指数构建与健康评价

应用大型底栖动物生物完整性指数(Benthic Index of Biological Integrity, B-IBI)评价河流健康已成为河流生态系统管理的重要方法。根据2010年5月对浑河流域62个采样点的底栖动物调查数据,基于采样点的水质等级、栖息地质量综合评估指数、人类干扰强度和河岸土地利用评估等标准,选择同属于辽河水系的太子河流域的8个采样点作为参照点,构建浑河流域B-IBI生物完整性指数。通过对34个生物参数的分布范围检验、判别能力分析以及相关性检验,最终确定浑河流域B-IBI生物完整性指数由总分类单元数、EPT(蜉蝣目Ephemeroptera、襀翅目Plecoptera、毛翅目Trichoptera)相对丰度、耐污类群相对丰度、最优势类群分类单元数、直接收集者相对丰度以及香农威纳多样性指数6个参数构成。根据各参数值随干扰增强的变化趋势,采用比值法计算各指标的分值和评价标准。结果表明:浑河流域B-IBI平均得分为2.56,河流健康状态处于一般状态;62个采样点中,9个处于健康状态,13个处于亚健康状态、22个处于一般状态、10个处于差状态,8个处于极差状态;从流域空间尺度上来看,河流健康状态从上游区到下游区逐渐变差。相关性分析表明,B-IBI与水温、电导、溶解性固体总量、硝酸盐、总氮、五日生化需氧量等水环境指标呈现显著负相关,表明B-IBI指数对于水质污染具有较好的指示性作用。综上所述,浑河流域由于受城市工业区的分布影响,大型底栖动物生物完整性呈现出明显的空间分布差异,上游区河流生物完整性较好、中下游底栖动物群落呈现出明显的退化趋势。     

A novel speed model for safety evaluation of freeway alignment in Euclidean 3D space

Objective: Operating speed is a critical indicator to evaluate consistency of road alignment and safety. Although extensive studies have been conducted on developing operating speed models, few researchers have considered the interactive influence of horizontal and vertical alignment in 3D space. The purpose of this study is to develop a speed model based on 3D alignment in Euclidean space rather than traditional horizontal and vertical alignment.

Methods: According to the curve theory of differential geometry, a novel method to estimate operating speed is proposed in our study using 3D space curvature instead of traditional horizontal or vertical parameters to describe the spatial geometric properties for a freeway alignment. Speeds of 54 different alignment segments are observed to develop the speed model. Several observing sites of each segment are selected beforehand, and the speeds of more than 300 vehicles in each site are observed. Space curvature is used as an important index to estimate operating speed.

Results: The findings of this study indicated that both horizontal alignment and vertical alignment contribute to space curvature. Space curvature mainly affects direction control operating performance. However, vehicles overcome the effects of gravity along the vertical alignment in the z direction. Results indicate that operating speed exponentially declines with space curvature and that quadratic parabola decline with vertical grade.

Conclusions: It can be concluded that there is a clear correlation between velocity and spatial curvature, which is proved by variance analysis. The estimation results of the speed models are reliable as tested using a real engineering example. The study would provide a scientific basis for safety evaluation of freeway alignment.     

Nitrogen process in stormwater bioretention: the impact of alternate drying and rewetting on nitrogen migration and transformation

Environmental Science and Pollution Research - Nitrogen migration and transformation in the stormwater bioretention system were studied in laboratory experiments, in which the effects of...     

Optimized production and characterization of cation-independent bioflocculant produced by Klebsiella sp. 59L

Environmental Science and Pollution Research - The cation-independent bioflocculant (59LF) extracted from Klebsiella sp. 59L was characterized. 59LF consisted of protein (4.8%) and total sugar...     

尾矿库安全生产红线划定研究

我国自开展尾矿库专项整治和综合治理行动以来,取得了显著成效,但尾矿库安全风险仍在逐渐增加,易诱发重特大事故,急需进一步研究其安全科技支撑技术。以尾矿库自身安全、堆排现状、溃坝影响、调洪能力等安全生产防控为研究出发点,整合高分对地观测技术、三维激光扫描技术和设计规范,研究划定了尾矿库上游汇水红线、最终堆排红线、下游影响红线、干滩警戒红线等四条安全生产红线。通过案例分析表明,研究划定的尾矿库安全生产红线能够有效地排查尾矿库区域性安全风险。     

Authentication of synthetic environmental contaminants and their (bio)transformation products in toxicology: polychlorinated biphenyls as an example

Environmental Science and Pollution Research - Toxicological studies use “specialty chemicals” and, thus, should assess and report both identity and degree of purity (homogeneity) of...