63.
The control of biodegradable substances is the key issue in evaluating the short and long-term emission potential and environmental impact of a landfill.Aerobic and anaerobic indices, such as respirometric index (RI) and biomethane potential production (GB21), can be used in the estimation of the stability of solid waste samples.Previous studies showed different degrees of relationship between BOD
5/COD ratio compared with RI4.Aim of this study is to standardize the parameter BOD
5/COD ratio and to test the methodology under different operating conditions (dynamic or static leaching and leaching duration, 6 and 24-h) keeping constant temperature and liquid/solid ratio (L/S = 10 l/kg
TS), with the introduction of a COD fractioning method. The COD fractioning is based on the differentiation between the soluble fraction (COD
sol) and the colloidal fraction (COD
coll) using a flocculation method.The BOD
5/COD and the BOD
5/COD
sol indices are both consistent and significant and can be used as stability indices.The BOD
5/COD ratio does not seem to be influenced, for the same test duration, by the type of test, static or dynamic. In the same way the longer test duration (24-h) does not influence significantly the values of BOD
5/COD ratio. As a consequence a leaching test duration of 6-h is preferable to avoid the beginning of the hydrolysis and oxidation processes.
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