构筑安全环境建好奥运场馆--当前锁具市场分析

北京申办2008年奥运成功举国欢腾,如何建好奥运场馆举世瞩目.我们作为从事高保安智能锁具研制多年的中国科技工作者深感有义不容辞的责任,愿借此机会与大家交流,以求建好奥运场馆,推进高保安锁具发展.     

Enhanced organic phosphorus detection in sediments by foam separation and 31P-NMR

Phosphorus (P) is both a nutrient and a pollutant. For instance, excess P induces water eutrophication followed by death of fishes and other water life. Determination of organic P content in sediments is therefore important to study P cycling and environmental pollution. The most widely used method to determine organic P in sediments is NaOH–EDTA extraction followed by ³¹P-NMR detection. However, some organic P compounds are difficult to extract using NaOH–EDTA due to the low solubility, thus can not be detected by ³¹P NMR. Here, we used foam separation to determine organic P in sediment of North Canal of Tianjin City, China. Organic P was first enriched using foam separation coupled with NaOH extraction. The enriched organic P was then analyzed with ³¹P NMR. The results showed that, compared with the traditional extraction method, foam separation coupled with NaOH extraction enriched more P compound because ³¹P NMR detected an extra signal of teichoic acid at chemical shift 1.14. This teichoic acid signal was not detected in the extract prepared using only NaOH–EDTA. Our finding demonstrates that determination using foam separation followed by ³¹P NMR is feasible.     

Natural attenuation characteristics and comprehensive toxicity changes of C9 aromatics under simulated marine conditions

Microcosmic experiments were performed under a simulated marine environment to investigate the natural attenuation of C9 aromatics using nine components (propylbenzene, isopropylbenzene, 2-ethyltoluene, 3-ethyltoluene, 4-ethyltoluene, 1,2,3-trimethylbenzene, 1,2,4-trimethylbenzene, 1,3,5-trimethylbenzene, and indene). This research aims to assess the contribution of biodegradation and abiotic activity to total attenuation of C9 aromatics and ascertain the changes in the comprehensive toxicity of seawater in the natural environment. The process of natural attenuation indicates the agreement with pseudo-first-order kinetics for all nine components in microcosmic experiments. The half-lives of the nine main compounds in C9 aromatics ranged between 0.34 day and 0.44 day under optimal conditions. The experiments showed that the natural attenuation of nine aromatic hydrocarbons mainly occurred via abiotic processes. Seawater samples significantly inhibited the luminescence of P. phosphoreum (the luminescence inhibition ratio reached 100%) at the beginning of the experiment. In addition, the toxicity declined slowly and continued for 25 days. The attenuation kinetics and changes in toxicity could be applied to explore the natural attenuation of C9 aromatics in the marine environment.     

Relationship between physicochemical properties and dewaterability of hydrothermal sludge derived from different source

Sewage sludge (SS) and deinking sludge (DS) were used to comparatively study the hydrothermal dewatering of sludge with different components. For a better overview, an insight into the relationship between physicochemical properties and dewaterability of hydrothermal sludge was provided. Results found that not all kinds of sludge were suitably conditioned by hydrothermal treatment (HT) in term of the elevation of dewaterability. Higher hydrothermal temperature tended to enhance the dewaterability of SS rather than DS, which was supported by the variation of their physicochemical properties (including water distribution, bonding energy, extracellular polymeric substance (EPS), particles size, acid functional groups and zeta potential in this study). In addition, the changes in surface morphology suggested that the reverse effect of HT on sludge dewaterability was mainly due to their dewatering behavior. For SS, the destruction of EPS structure leaded to the release of bound water, thereby strengthening sludge dewatering. Conversely, “Bridging effect” generated by lignocellulose in DS was beneficial for sludge dewatering; however, the increasing hydrothermal temperature degraded part of lignocellulose and weakened “bridging effect”, finally resulting in worse dewaterability of DS.     

甲苯对UASB反应器中溶解性微生物产物的影响

以乙酸钠为外加碳源,考察了UASB反应器内甲苯对可溶性微生物产物（SMP）的影响。实验结果表明：低质量浓度（20~70 mg/L）的甲苯对微生物有刺激作用,使得污泥增殖速率变小,SMP的质量浓度也逐渐减少,经过一段时间的驯化后,系统COD和TOC的去除率分别达到93%和94%以上,下降趋势较小;较高质量浓度（70~200 mg/L）的甲苯对微生物有抑制作用,污泥活性下降,反应器运行状况开始恶化,SMP的质量浓度也逐渐增大,经过一段时间的驯化后,系统COD和TOC的去除率分别维持在81%和83%以上;当甲苯质量浓度超过200 mg/L时,表现为污泥活性严重下降,对COD的去除效果极差。     

电絮凝处理油田生化出水

为了减轻对后续处理中超滤膜的污染,采用电絮凝法处理油田生化出水,降低油田生化出水中的有机物含量。研究了电流强度、曝气时间和pH值对水中总有机碳（TOC）和浊度除去效果的影响以及pH值随曝气时间的变化趋势,通过红外光谱对絮凝处理前后水中总溶解固体进行了分析,优化了电絮凝的工艺条件。研究表明,当水流速度控制在50 mL/s,电流强度为2 A,500 mL絮凝出水的曝气时间为30 min时,整套絮凝工艺对TOC的去除率为48%,浊度去除率为42.9%,COD去除率为44%。     

Phosphorus recovery from biogas fermentation liquid by Ca-Mg loaded biochar

Shortage in phosphorus(P) resources and P wastewater pollution is considered as a serious problem worldwide. The application of modified biochar for P recovery from wastewater and reuse of recovered P as agricultural fertilizer is a preferred process. This work aims to develop a calcium and magnesium loaded biochar(Ca–Mg/biochar) application for P recovery from biogas fermentation liquid. The physico-chemical characterization, adsorption efficiency, adsorption selectivity, and postsorption availability of Ca-Mg/biochar were investigated. The synthesized Ca–Mg/biochar was rich in organic functional groups and in Ca O and Mg O nanoparticles. With the increase in synthesis temperature, the yield decreased, C content increased, H content decreased, N content remained the same basically, and BET surface area increased. The P adsorption of Ca–Mg/biochar could be accelerated by nano-Ca O and nano-Mg O particles and reached equilibrium after 360 min.The process was endothermic, spontaneous, and showed an increase in the disorder of the solid–liquid interface. Moreover, it could be fitted by the Freundlich model. The maximum P adsorption amounts were 294.22, 315.33, and 326.63 mg/g. The P adsorption selectivity of Ca–Mg/biochar could not be significantly influenced by the typical p H level of biogas fermentation liquid. The nano-Ca O and nano-Mg O particles of Ca–Mg/biochar could reduce the negative interaction effects of coexisting ions. The P releasing amounts of postsorption Ca–Mg/biochar were in the order of Ca–Mg/B600 Ca–Mg/B450 Ca–Mg/B300. Results revealed that postsorption Ca–Mg/biochar can continually release P and is more suitable for an acid environment.     

基于地理探测器的区域植被覆盖度的定量影响——以京津风沙源区为例

植被覆盖度（FVC）是衡量生态环境优秀的重要指标.本文基于MODIS NDVI数据,运用像元二分法模型,估算了2000~2018年京津风沙源区FVC,分析了其时空变化特征.在此基础上,基于地理探测器模型,定量分析了自然因素和人类活动因素等12个因子对京津风沙源区FVC空间分布的影响.结果表明,近20a来京津风沙源区FVC整体上呈增加趋势,增加率为8.2%.空间上,研究区73.7%的区域FVC在增加,其中显著增加的区域主要集中在晋北山地丘陵亚区、燕山丘陵山地水源保护亚区、大兴安岭南部亚区和科尔沁沙地亚区的南部.2000~2018年,降水是影响京津风沙源区FVC空间分布的主要自然因子,解释力为63.3%;年末大牲畜头数是影响FVC空间分布的主要人为因子,解释力为34.8%.自然因素和人类活动之间的双因子交互作用以双协同作用和非线性协同作用为主,表明相对于单因子,自然因素和人类活动间的交互作用对FVC的解释力更强.其中,降水与其他11个因子的交互作用对研究区FVC起主导作用,解释力超过60%.     

氧化物催化剂对非热等离子体催化降解甲苯的影响

考察了在干燥气氛下不同氧化物催化剂对非热等离子体催化降解甲苯的影响。从甲苯降解率、碳平衡、CO2选择性和O3去除4个方面,对比了氧化物催化剂的介电性能、表面供氧能力和比表面积与多孔结构对反应产生影响的强弱。结果表明,催化剂的介电性能有利于甲苯降解率、碳平衡和O3产量的提高,但对CO2选择性和O3去除的影响极小;一定能量密度下,催化剂比表面积与多孔结构对CO2选择性和O3去除所产生的影响要强于介电性能;催化剂表面供氧能力可明显促进反应的进行,其对反应所产生的影响要强于比表面积与多孔结构。     

The role of doped-Mn on enhancing arsenic removal by MgAl-LDHs

To meet the challenges posed by global arsenic water contamination, the MgAlMn-LDHs with extraordinary efficiency of arsenate removal was developed. In order to clarify the enhancement effect of the doped-Mn on the arsenate removal performance of the LDHs, the cluster models of the MgAlMn-LDHs and MgAl-LDHs were established and calculated by using density functional theory (DFT). The results shown that the doped-Mn can significantly change the electronic structure of the LDHs and improve its chemical activity. Compared with the MgAl-LDHs that without the doped-Mn, the HOMO-LUMO gap was smaller after doping. In addition, the -OH and Al on the laminates were also activated to improve the adsorption property of the LDHs. Besides, the doped-Mn existed as a novel active site. On the other hand, the MgAlMn-LDHs with the doped-Mn, the increased of the binding energy, as well as the decreased of the ion exchange energy of interlayer Cl⁻, making the ability to arsenate removal had been considerably elevated than the MgAl-LDHs. Furthermore, there is an obvious coordination covalent bond between arsenate and the laminates of the MgAlMn-LDHs that with the doped-Mn.