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711.
Naile JE Khim JS Wang T Wan Y Luo W Hu W Jiao W Park J Ryu J Hong S Jones PD Lu Y Giesy JP 《Environmental pollution (Barking, Essex : 1987)》2011,159(4):907-917
Polychlorinated-dibenzo-p-dioxins and -dibenzofurans (PCDD/Fs) were measured in soils and sediments from the Yellow Sea region. Korean soils and sediments mostly contained detectable PCDD/Fs and showed a widespread distribution among locations. Soil and sedimentary PCDD/Fs from China were comparable to or less than those in Korea. The patterns of relative concentrations of individual congeners in soils were different between the two countries, but similar in sediments. Sources of PCDD/Fs in China and Korea were found to be independent of each other and their distributions reflected matrix-dependent accumulation. Spatial distribution indicated some point sources in Korea while Chinese sources were more widespread and diffuse. PCDD/Fs measured in the coastal areas of the Yellow Sea were comparable to or less than those previously reported in for eastern Asia. However, ∑TEQs in soils and sediments were near to or, in some cases exceeded environmental quality guidelines. 相似文献
712.
Distribution, speciation and availability of antimony (Sb) in soils and terrestrial plants from an active Sb mining area 总被引:1,自引:0,他引:1
Gudny Okkenhaug Yong-Guan ZhuLei Luo Ming LeiXi Li Jan Mulder 《Environmental pollution (Barking, Essex : 1987)》2011,159(10):2427-2434
Here, we present one of the first studies investigating the mobility, solubility and the speciation-dependent in-situ bioaccumulation of antimony (Sb) in an active Sb mining area (Xikuangshan, China). Total Sb concentrations in soils are high (527-11,798 mg kg−1), and all soils, including those taken from a paddy field and a vegetable garden, show a high bioavailable Sb fraction (6.3-748 mg kg−1), dominated by Sb(V). Elevated concentrations in native plant species (109-4029 mg kg−1) underpin this. Both chemical equilibrium studies and XANES data suggest the presence of Ca[Sb(OH)6]2, controlling Sb solubility. A very close relationship was found between the citric acid extractable Sb in plants and water or sulfate extractable Sb in soil, indicating that citric acid extractable Sb content in plants may be a better predictor for bioavailable Sb in soil than total acid digestible Sb plant content. 相似文献
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717.
With intensified contradiction between the rapid development of modern industry and the carrying capacity of natural environment,coordinating the relationship between economic benefits and ecological benefits is a significant issue to be solved for modern industrial engineering.This paper firstly conducts the comparative analysis between traditional and ecological industry as well as traditional and modern industrial engineering,and indicates that eco-industrial engineering is an inevitable choice for sustainable development of modern industrial engineering;Then,based on industrial ecology,environmental economics and sustainable development theory,the connotation and definition of ecoindustrial engineering are proposed,and the theoretical and practical development of the concepts of eco-industrial engineering are further investigated.Furthermore,the research subject,research content,academic system architecture and evaluation methods of eco-industrial engineering are discussed.Finally,combining the current scientific and technological development,we put forward the important scientific value and practical significance of constructing eco-industrial engineering for the utilization of these concepts. 相似文献
718.
改性污泥活性炭对水中镉离子的吸附性能 总被引:3,自引:0,他引:3
以城市污水处理厂的剩余污泥为原料,氯化锌为活化剂制备污泥活性炭,对一部分污泥活性炭用6.0 mol/L的硝酸进行改性,并研究了未改性和改性的污泥活性炭对Cd2+的吸附行为的影响。结果表明,在pH为5.0、Cd2+初始浓度为100 mg/L、吸附剂投加量为2.0 g/L、反应温度为25℃时,未改性的污泥活性炭吸附容量为8.45 mg/g,硝酸改性的污泥活性炭吸附容量达到了23.35 mg/g。改性和未改性的污泥活性炭对Cd2+都有较好的吸附容量,硝酸改性大幅度提高了污泥活性炭对Cd2+的吸附性能。常温下改性污泥活性炭对Cd2+的吸附符合Langmuir吸附等温式。 相似文献
719.
市政污泥水热炭化废水组成成分特征 总被引:1,自引:0,他引:1
污泥水热炭化处理被认为是极具潜力的污泥安全处置与资源化利用的技术措施之一。为了解废水中碳、氮、磷、钾和重金属含量随水热炭化反应温度和反应时间的变化规律,对市政污泥190℃和260℃水热炭化不同时间(1、6、12、18和24 h)后的废水组成成分进行了研究。结果表明,水热炭化处理后,废水颜色由黑色变成浅黄色;pH由6.40提高到9.14;TOC、COD和BOD5最高分别增加了13 175 mg/L、55 998 O2mg/L和31 723 O2mg/L;氮和钾含量显著提高,但磷含量降低;Cd、Cr含量由未检测到分别增加到0.060 mg/L和2.326 mg/L,As、Pb含量均由0.032 mg/L分别增加到1.408 mg/L和0.590 mg/L,但Cu、Mn及Zn含量降低。比起反应时间,反应温度对废水组成成分的影响更大。 相似文献
720.
柠檬酸浸出土壤中铜、锌的优化设计 总被引:1,自引:0,他引:1
以某工业废弃地土壤为供试材料,采用批次实验方法,研究了柠檬酸对重金属Cu、Zn的浸出效果。并在单因素实验基础上,探讨不同pH值、柠檬酸浓度、固液比和浸提时间等对浸出效果的影响,进而对实验条件进行正交优化组合,确定优化工艺参数为:pH值为3.2,柠檬酸浓度为0.4 mol/L,壤土固液比为1/10,土壤中Cu、Zn接近平衡的时间分别为1 h和1.5 h。结果表明,在此条件下,对这2种金属来说,Cu较Zn易释放,Cu、Zn的最大浸出率分别为74.8%和65.3%。柠檬酸浸提前后,土壤中有机质含量下降范围为0.61%~3.16%。单从土壤有机质含量来看,柠檬酸对土壤质量影响较小,具有较好的应用前景。 相似文献