高锰酸盐复合药剂强化混凝改善再生水景观湖水质研究

实验通过投加助凝剂以强化混凝沉淀过程,从而达到去除再生水景观水中的藻类。以PAC为混凝剂,高锰酸盐复合药剂(PPC)为预氧化助凝剂,通过烧杯实验确定PPC、PAC同时投加,最佳投量分别为1 mg/L、60 mg/L。生产性实验中,机械加速澄清池强化混凝对TP、叶绿素、藻密度的去除率分别为54%、32.3%和35.4%,湖水中TP、TN逐渐降低分别由4.9 mg/L、23 mg/L降至0.72 mg/L、10.3 mg/L。PPC提高了混凝沉淀对藻类的去除效果,改善了再生水景观湖水质,降低水中氮磷营养盐的含量。     

脉冲电解法预处理酸性染料废水

研究了脉冲电解法预处理酸性偶氮类染料废水的处理效果,考察了不同工艺条件对废水COD去除率、脱色率和可生化性的影响。结果表明,脉冲电源峰值电压12 V,频率600 Hz,占空比50%的条件下电解40 min后,COD去除率可达59%,废水脱色率达91.4%,BOD5/COD由0.09提高至0.34。在相同条件下,脉冲电解法的电流效率是直流电解法的2倍左右。与现行常用的铁/碳反应床相比,脉冲电解法在成本上也具有一定的优势,应用前景较好。     

组合工艺处理填埋场渗滤液中溶解性有机污染物的去除特性

以采用"SBR+混凝+Fenton氧化+BAF"组合工艺处理的晚期垃圾渗滤液各级出水为研究对象,考察了HA、FA和HyI等溶解性有机物(DOM s)在各个工艺处理过程中的变化。结果表明,组合工艺COD和NH3-N去除率分别达到98.4%和99.3%;对DOM s的去除率为98.3%,其中胡敏酸(HA)、富里酸(FA)和亲水性有机物(HyI)的去除率分别为98.3%、99.5%和95.7%。各处理工艺中SBR和混凝工艺对HA和HyI的去除贡献较大,Fenton氧化工艺对FA去除率较高。Fenton氧化和BAF联用,可以有效去除难降解的溶解性有机污染物,使出水达到《生活垃圾填埋污染控制标准》(GB16889-2008)排放标准。     

好氧活性污泥中自养硝化细菌分离方法研究

分别采用琼脂平板、琼脂糖平板、水洗洋菜平板和硅胶平板分离培养城市污水处理厂好氧活性污泥中的硝化细菌。在相同的培养条件下,琼脂平板和水洗洋菜平板有杂菌生长;硅胶平板制作过程繁琐,培养后期出现失水性干裂;琼脂糖平板没有杂菌生长。通过对分离菌株的表观形态观察和NorB基因检测鉴定分离菌株,证明琼脂糖分离出了目的菌株,适合生长周期长的自养硝化细菌分离培养。     

水合肼生产盐渣中氮化合物的去除

将水合肼生产盐渣分离碳酸钠后,通过吹脱、氧化等工艺降低饱和盐溶液的氮含量(以氨质量浓度计),以达到电解法制备氢氧化钠工艺对原料氯化钠的使用要求。中试试验结果表明:氧化反应最佳工艺条件为以次氯酸钠为氧化剂,次氯酸钠溶液中氢氧化钠质量浓度9.2g/L,次氯酸钠与初始氨的质量比为13,溶液pH 7～8,反应温度30～35℃;在此条件下氧化处理饱和盐溶液,处理后氨质量浓度由350.0 mg/L降至2.1 mg/L。将处理后的饱和盐溶液用于电解法制备氢氧化钠的生产过程,不仅可创造一定的经济效益,而且还解决了水合肼生产中的环境污染问题。     

Rapid detection of toxic metals in non-crushed oyster shells by portable X-ray fluorescence spectrometry

The aim of this study was the multi-elemental detection of toxic metals such as lead (Pb) in non-crushed oyster shells by using a portable X-ray fluorescence (XRF) spectrometer. A rapid, simultaneous multi-element analytical methodology for non-crushed oyster shells has been developed using a portable XRF which provides a quick, quantitative, non-destructive, and cost-effective mean for assessment of oyster shell contamination from Pb. Pb contamination in oyster shells was further confirmed by scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS). The results indicated that Pb is distributed in-homogeneously in contaminated shells. Oyster shells have a lamellar structure that could contribute to the high accumulation of Pb on oyster shells.     

Evaluation of the National Land Cover Database for Hydrologic Applications in Urban and Suburban Baltimore,Maryland1

Smith, Monica Lipscomb, Weiqi Zhou, Mary Cadenasso, Morgan Grove, and Lawrence E. Band, 2010. Evaluation of the National Land Cover Database for Hydrologic Applications in Urban and Suburban Baltimore, Maryland. Journal of the American Water Resources Association (JAWRA) 46(2):429-442. DOI: 10.1111/j.1752-1688.2009.00412.x Abstract: We compared the National Land Cover Database (NLCD) 2001 land cover, impervious, and canopy data products to land cover data derived from 0.6-m resolution three-band digital imagery and ancillary data. We conducted this comparison at the 1 km², 9 km², and gauged watershed scales within the Baltimore Ecosystem Study to determine the usefulness and limitations of the NLCD in heterogeneous urban to exurban environments for the determination of land-cover information for hydrological applications. Although the NLCD canopy and impervious data are significantly correlated with the high-resolution land-cover dataset, both layers exhibit bias at <10 and >70% cover. The ratio of total impervious area and connected impervious area differs along the range of percent imperviousness – at low percent imperviousness, the NLCD is a better predictor of pavement alone, whereas at higher percent imperviousness, buildings and pavement together more resemble NLCD impervious estimates. The land-cover composition and range for each NLCD urban land category (developed open space, low-intensity, medium-intensity, and high-intensity developed) is more variable in areas of low-intensity development. Fine-vegetation land-cover/lawn area is incorporated in a large number of land use categories with no ability to extract this land cover from the NLCD. These findings reveal that the NLCD may yield important biases in urban, suburban, and exurban hydrologic analyses where land cover is characterized by fine-scale spatial heterogeneity.     

Dynamic Tracking and Comprehensive Evaluation on the Natural Resources Security Elements and System in China

System theory,pressure-state-response and drivingpressure-state-impact-response model have been applied to establishing China's dynamic tracking evaluation system of natural resources security in this article.Based on analytic hierarchy process and Delphi methods,the natural resources security situation has been evaluated systematically from 1991 to 2007.The result showed that the overall level of China's natural resources security presented a downtrend from 1991 to 2007.The basic reasons are the pressure indicators such as population,GDP,natural resources trade increased gradually,resulting in tension and fragility of natural resources security.     

提高油田伴生气回收率的研究与应用

文章阐述了陆梁油田在开发过程中采用油气混输技术、天然气发电机橇技术、锅炉烧湿气等技术,将伴生气回收率提高至92.10%;油气混输技术能够实现边缘区块油气全密闭输送;集中处理站锅炉燃烧湿气技术可增加处理站天然气外输气量,降低运行成本;小型活动天然气发电机橇的应用,可以充分利用富裕天然气降低生产成本,同时减少富裕天然气火炬放空燃烧量,收到了良好的经济效益和环境效益。     

Perennial filter strips reduce nitrate levels in soil and shallow groundwater after grassland-to-cropland conversion

Many croplands planted to perennial grasses under the Conservation Reserve Program are being returned to crop production, and with potential consequences for water quality. The objective of this study was to quantify the impact of grassland-to-cropland conversion on nitrate-nitrogen (NO3-N) concentrations in soil and shallow groundwater and to assess the potential for perennial filter strips (PFS) to mitigate increases in NO3-N levels. The study, conducted at the Neal Smith National Wildlife Refuge (NSNWR) in central Iowa, consisted of a balanced incomplete block design with 12 watersheds and four watershed-scale treatments having different proportions and topographic positions of PFS planted in native prairie grasses: 100% rowcrop, 10% PFS (toeslope position), 10% PFS (distributed on toe and as contour strips), and 20 PFS (distributed on toe and as contour strips). All treatments were established in fall 2006 on watersheds that were under bromegrass (Bromus L.) cover for at least 10 yr. Nonperennial areas were maintained under a no-till 2-yr corn (Zea mays L.)--soybean [Glycine max. (L.) Merr.] rotation since spring 2007. Suction lysimeter and shallow groundwater wells located at upslope and toeslope positions were sampled monthly during the growing season to determine NO3-N concentration from 2005 to 2008. The results indicated significant increases in NO3-N concentration in soil and groundwater following grassland-to-cropland conversion. Nitrate-nitrogen levels in the vadose zone and groundwater under PFS were lower compared with 100% cropland, with the most significant differences occurring at the toeslope position. During the years following conversion, PFS mitigated increases in subsurface nitrate, but long-term monitoring is needed to observe and understand the full response to land-use conversion.