Effect of complexation with humic substances on diffusion of metal ions in water

Most studies on diffusion of metal ions in various water-rock systems have dealt with free ions (hydrated ions). However, it is often the case that metal ions are dissolved as complexed species such as with humic substances (HS) in natural waters. Hence, we need to study the diffusion behavior of these complexes in order to understand fully the diffusion phenomenon in natural. In this study, the diffusion coefficients of free metal ions (M(z+)) and their complexes with HS (M-HS) were compared to understand the effect of complexation with HS on the diffusion of metal ions such as Co(2+), Cd(2+), and rare earth elements (REE(3+)). Although the diffusion coefficients of free metal ions depend on ionic potential, such dependence was not observed in the presence of HS. Comparing the diffusion coefficients of metal complexes with ethylenediaminetetraacetate (EDTA), fulvic acid, and humic acid showed that the molecular weight (MW), or the size of the ligand, is of primary importance for the diffusion of M-HS. As a consequence, the diffusion coefficients of all REE(3+) were similar in the presence of HS, while they were different in the absence of HS due to the different size of each REE(3+). The similarity among the diffusion coefficients of REE-HS was caused by the much larger size of HS compared with each ion. However, the distribution coefficients of M-HS were not similar among REE(3+), Cd(2+), and Co(2+). REE(3+) and Cd(2+) which have higher affinities for larger MW fraction in HS diffused slower than Co(2+) which favors smaller MW fraction. The results show that the affinity for different MW fractions among HS controls the diffusion of M-HS, which must be important to predict precisely the diffusion behavior of metal ions bound to HS in natural systems.     

Present State,of Industrial Waste Management in Japan

Systematic management for industrial waste in Japan has been carried out based on the Waste Disposal and Public Cleansing Law which was enacted in 1970. The law and its ordinances designate 19 kinds of waste materials discharged from business activities as industrial waste and prescribe the generator's responsibility, requirements for treatment contractors, standards for consignment, specific personnel, etc. from the view of proper management. And they also, prescribe disposal standards, structure, and maintenance standards for treatment facilities, including final disposal sites, from the view of proper treatment and disposal. The Standard for Verification provides criteria to categorize as hazardous or nonhazardous industrial waste which is subjected to treatment and disposal in conformity with each standard. The fundamental policies to cope with industrial waste focus on reduction of generation, promotion of recycling, establishment of a comprehensive information management system and participation of the public which can contribute well to prevent environmental pollution caused by inappropriate management of industrial waste.     

Identification of chemical substances in industrial wastes and their pyrolytic decomposition products

In order to quantify the sources of chemical pollutants in the leachate from reclaimed wastes, chemical substances in 11 different types of industrial wastes were identified. Their elution behaviors were also investigated. Alkanes (5.3-890 ng g(-1)), benzenes (8.1-110 ng g(-1)), polyaromatic hydrocarbons (PAHs) (3.2-560 ng g(-1)), alcohols, steroids, phenol (7.1 ng g(-1)), ketones, furans (190-210 ng g(-1)), phthalates (8.9-560 ng g(-1)), benzoquinones, dibenzothiophene (190 ng g(-1)), benthiocarb (4.2 ng g(-1)), sulfur, nitrile compounds, amino compounds, amido compounds, pyridines, quinolines (1.8-15 ng g(-1)), isoquinolines, carbazoles, acridines, chlordenes (1.5-1.6 ng g(-1)) and nonachlors (1.1-1.6 ng g(-1)) were detected in 9 types of industrial wastes. The chemical substances detected in waste at the highest concentrations were alkanes, PAHs and phthalates. Water supply sludge, dust and brick garbage contained many kinds of chemical substances. The elution behaviors of specific chemical substances, COD and nutrients varied by characteristic and production process of each waste. Over 100 different compounds were detected in pyrolysis products including carbohydrate, carotynoid, amino acids, proteins, humic acids, lignin and combustion products.     

Site selection in CO2 ocean sequestration: Dependence of CO2 injection rate on eddy activity distribution

Site selection in CO₂ ocean sequestration is examined based on the idea that a site where injected CO₂ is efficiently diluted is favourable in reducing/avoiding biological impacts. Simulations of CO₂ injection into several sites by an eddy-resolving oceanic general circulation model (OGCM) show that the maximum CO₂ concentration differs by a factor of 10 among sites. The distribution of eddy activity is the most important causative factor producing the geographical differences in CO₂ dilution. Based on the relationship between the maximum CO₂ concentration and eddy activity, we estimated the distribution of the maximum CO₂ injection rate by a proposed method, which does not cause chronic impacts on biota. Around Japan, extensive ocean volume has the potential to dilute 20 million tonnes per year without chronic impacts, and some areas can be injected with 80 million tonnes per year.     

Characteristics of nanoparticles emitted from burning of biomass fuels

The characteristics of the particles of the smoke that is emitted from the burning ofbiomass fuels were experimentally investigated using a laboratory-scale tube furnace and different types of biomass fuels： rubber wood, whole wood pellets and rice husks. Emitted amounts of particles, particle-bound polycyclic aromatic hydrocarbons （PAHs） and water-soluble organic carbon （WSOC） are discussed relative to the size of the emitted particles, ranging to as small as nano-size （〈70 nm）, and to the rate of heating rate during combustion, differential thermal analysis （DTA） and thermogravimetric analysis （TG） techniques were used to examine the effect of heating rate and biomass type on combustion behaviors relative to the characteristics of particle emissions. In the present study, more than 30% of the smoke particles from the burning ofbiomass fuel had a mass that fell within a range of 〈 100 nm. Particles smaller than 0.43 μm contributed greatly to the total levels of toxic PAHs and WSOC. The properties of these particles were influenced by the fuel component, the combustion conditions, and the particle size. Although TC--DTA results indicated that the heating rate in a range of 10-20℃did not show a significant effect on the combustion properties, there was a slight increase in the decomposition temperature as heating rate was increased. The nano-size particles had the smallest fraction of particle mass and particle-bound PAHs, but nonetheless these particles registered the largest fraction of particle-bound WSOC.     

Development of a catalytic cracking process for converting waste plastics to petrochemicals

The catalytic degradation of polyolefin using H-gallosilicates was examined using a bench-scale reactor (0.8kg/h) with semicontinuous feeding and the following plastics: (1) low-density polyethylene (LDPE) pellets; (2) linear low-density polyethylene (L-LDPE) pellets; (3) high-density polyethylene (HDPE) pellets; (4) polypropylene (PP) pellets; (5) polyolefin obtained from pulverized industrial waste plastics. The yields of liquid compounds from these materials, which were aromatics in most cases, ranged from 55wt% to 68wt%. With an increase in the ratio of total reactant to catalyst, the liquid yield remained the same. Yields of benzene, toluene, and xylenes (BTXs) decreased rapidly to below 50wt% at a ratio of more than 30. Differences in this ratio for BTXs were always small and were independent of the material. Only about half of the gas product was propane with a fresh catalyst. When the experiments were repeated, propylene, isobutane, and isobutene were found to increase.     

中日合作项目职业安全卫生法规与标准体系初步研究

按照中日合作项目《加强中国安全生产科学技术能力计划》,分析了中国职业安全卫生法规标准体系现状,提出了中国《安全生产法》和日本《劳动安全卫生法》的各自特点与不同点。同时,系统梳理了中国危险化学品、机械安全和职业卫生等领域安全生产法规标准体系,分析了其中存在的主要问题,提出了针对性对策和建议。这对健全中国职业安全卫生法规体系建设具有重要的借鉴和参考意义。     

Effect of organic suspended solids and their sedimentation on the surrounding sea area

A study of sediment contamination was made in one of the 23 specific designated important ports in Japan, the inner part of which had been used as wood pool. The study focused on the relationship between contaminants and organic matter in terms of ignition loss and the impact of the wood pool on the port area. Organic matter exists in the form of suspended solids and deposits. Sediment samples were taken from the mouths of the rivers feeding into Shimizu Port, from the wood pool and from Shimizu Port. Samples within Shimizu Port showed that as the ignition loss decreased with distance from the wood pool, other properties including the concentrations of trace metals, ignition loss and sulfide content also decreased with the distance. In conclusion, Shimizu Port seems to function as a buffer area between the wood pool and Suruga Bay.     

日本职业卫生管理及对中国的启示

依据中日合作项目<加强中国国家安全生产科学技术能力计划>成果,系统介绍了日本职业卫生监管机构、法规、职业病确定、作业环境管理等.同时,结合中国职业卫生管理体制尚未完全理顺、法规较滞后、专业人才不足、企业基础资料不全和自主管理体制不健全等现状,提出了进一步明确职业卫生管理体制、完善职业卫生法规、建立职业卫生统计制度、强化企业自主管理能力等建立健全中国职业卫生管理的对策和建议.本文对完善中国职业卫生管理具有重要的参考意义.     

日本职业卫生管理及对中国的启示

依据中日合作项目《加强中国国家安全生产科学技术能力计划》成果,系统介绍了日本职业卫生监管机构、法规、职业病确定、作业环境管理等。同时,结合中国职业卫生管理体制尚未完全理顺、法规较滞后、专业人才不足、企业基础资料不全和自主管理体制不健全等现状,提出了进一步明确职业卫生管理体制、完善职业卫生法规、建立职业卫生统计制度、强化企业自主管理能力等建立健全中国职业卫生管理的对策和建议。本文对完善中国职业卫生管理具有重要的参考意义。