我国自然保护区有效管理现状及其分析

本文在对我国１０多个省（自治区）２ｏ多个自然保护区的实际调查和全国资料的统计分析基础上，从我国自然保护区的管理体制、管理机构建设、资源的保护与适度开发利用、科学研究与宣传教育等方面，全面分析了我国自然保护区有效管理的现状，总结了取得的成绩和存在的问题，并针对存在的主要问题，提出了相应的对策与建议。     

论乡镇工业排污收费

本文介绍了乡镇工业排污费的征收现状及特点；根据１９８９年全国乡镇工业污染源调查数据对乡镇工业排污费应征值作了测算，并从对乡镇工业、社会、财政收入和农村环境保护的影响以及征收可行性等方面进行了论证；在此基础上，对乡镇工业排污费实征率低的原因作了分析，提出了乡镇工业排污费征收、管理和使用的有关建议。     

Do early colonization patterns of periphytic ciliate fauna reveal environmental quality status in coastal waters?

The feasibility for developing a protocol to assess marine water quality based on early colonization features of periphytic ciliate fauna was studied in coastal waters of the Yellow Sea, northern China. The ciliate communities with 3–28-day ages were collected monthly at four stations with a spatial gradient of environmental stress from August 2011 to July 2012. The spatial patterns of both early (3–7 days) and mature (>10 days) communities of the ciliates represented significant differences among the four stations, and were significantly correlated with environmental variables, especially nutrients and chemical oxygen demand (COD). Seven and eight dominant species were significantly correlated with nutrients or COD within the early and mature communities, respectively. The species richness indices were strongly correlated with nutrients, especially in mature communities. These findings suggest that it is possible to assess the status of water quality using early colonization features of periphytic ciliate fauna in coastal waters.     

Energy consumption model and energy efficiency evaluation for CNC continuous generating grinding machine tools

Abstract

Machine tool, which is the basis energy consumed device in manufacturing system, its energy consumption model and energy efficiency evaluation are the prerequisites for energy saving in manufacturing. Considering the multi-energy-sources features,analysed the mathematical model of a CNC continuous generating grinding machine tool from the view of energy constitute. The energy sources of a CNC continuous generating grinding machine tool are classified into gear grinding system, grinding wheel dressing system and auxiliary system. Based on the power balance equations of energy flow, the energy flow system of a CNC continuous generating grinding machine tool is established. And then the energy consumption mathematical model of a CNC continuous generating grinding machine tool is set up by combining the power balance equations with the operating features of three kinds of energy sources. The case study shows that the proposed energy consumption model can provide fundamental support for energy consumption forecasting, energy efficiency analysis and energy-saving optimisation during the machine tool operation process.     

自然资源代际转移模型研究

代际均衡发展是可持续发展的核心内容之一，而代际均衡的实现在目前情况下有赖于代际主动财富转移改策实施。政府的宏观调控是实施这一政策的有力手段。具体的措施可开征“资源代际补偿税”以建立专项基金制度     

资源代际管理与可持续发展

代际均衡发展是可持续发展战略的重要方面,代际均衡发展的物质基础是代际财富均衡。自然资源是代际财富均衡分配的主要内容,需要进行资源代际管理来保证可持续发展战略的实现。     

Determination of polybrominated diphenyl ethers in soil and sediment from an electronic waste recycling facility

In this study samples of ten species of fish were analyzed for concentrations of organochlorine pesticides, PCBs and heavy metals (Pb, Cd, and Cu). Fish were captured using electric fishing on ten sites along the Dr?me river (Rh?ne-Alpes region). Quantitative determination of the organochlorine and PCBs compounds was performed by gas chromatography-electron-capture detection (GC-ECD). The concentrations of heavy metals were determined by atomic absorption spectrophotometry. Samples contained detectable concentrations of lindane, PCBs, and heavy metals but at concentrations below the maximum residue limit (MRL). Non-parametric statistical analysis was performed to distinguish groups of sites with different levels of contamination. PCBs concentrations increased along the river with four groups of sites significantly different from each other. Cadmium concentrations were below the MRL. Lead contamination showed two groups significantly different and a repartition similar to PCBs. Copper contamination was correlated with the localization of vineyards. We assessed the potential effects of contamination the otter (Lutra lutra). The concentrations of all pollutants analyzed in fish sampled in this study are lower than the threshold values described in literature. The Dr?me river is relatively unpolluted river, and the establishment of otter populations should not be affected by pollution.     

亚铁催化声化学降解罗丹明B

比较了不同金属离子对罗丹明B的声化学降解作用，发现超声时加入Fe^2＋反应速率常数为单独超声波降解时的1．6倍，反应在前5h内符合假一级动力学。研究了亚铁离子强化声化学对罗丹明B的降解作用，考察了Fe^2＋用量，溶液初始pH值，曝气，反应温度和超声功率等因素对脱色速率的影响。研究表明，酸性条件有利于染料的脱色；有曝气时的声化学脱色速率常数是单独超声时的6倍；声化学反应的活化能较低，反应在低温就可以进行；超声功率的改变对脱色速率的影响不大。UV-VIS扫描图谱显示，染料在225nm和256nm处的紫外吸收明显降低，初步探讨了罗丹明B的降解机理。     

一氯苯在钒钛催化剂表面亲核取代反应的DFT计算

采用DFT计算方法对一氯苯在V2O5(001)和脱钛矿表面氧上的亲核取代反应的机理进行了分析。对不同DFT泛函在氯代芳香烃-过渡金属氧化物体系计算中的准确性进行了验证,发现采用B3LYP泛函得到的过渡态相对能量与标准值的偏差为9.63 kJ/mol,产物相对能量的偏差为8.79 kJ/mol,可以用于反应路径的推断。对亲核取代反应的机理进行了分析:首先苯环上与氯原子连接的碳原子受到表面氧的攻击,氯原子被驱离环平面;然后C—O健开始形成,同时C—Cl健断裂;最后苯酚盐结构形成,而驱离的氯原子与提供一个空轨道的过渡金属原子连接。与V2O5(001)表面及脱钛矿(100)和(101)表面相比,脱钛矿(001)表面的桥位氧是亲核取代最有可能发生的位置,吸附能为193.77 kJ/mol,吸附能垒为135.33 kJ/mol。