全文获取类型
收费全文 | 619篇 |
免费 | 33篇 |
国内免费 | 264篇 |
专业分类
安全科学 | 29篇 |
废物处理 | 45篇 |
环保管理 | 46篇 |
综合类 | 372篇 |
基础理论 | 120篇 |
环境理论 | 1篇 |
污染及防治 | 215篇 |
评价与监测 | 34篇 |
社会与环境 | 31篇 |
灾害及防治 | 23篇 |
出版年
2024年 | 1篇 |
2023年 | 10篇 |
2022年 | 33篇 |
2021年 | 28篇 |
2020年 | 14篇 |
2019年 | 26篇 |
2018年 | 23篇 |
2017年 | 27篇 |
2016年 | 29篇 |
2015年 | 26篇 |
2014年 | 46篇 |
2013年 | 58篇 |
2012年 | 48篇 |
2011年 | 49篇 |
2010年 | 42篇 |
2009年 | 41篇 |
2008年 | 47篇 |
2007年 | 36篇 |
2006年 | 47篇 |
2005年 | 26篇 |
2004年 | 24篇 |
2003年 | 29篇 |
2002年 | 38篇 |
2001年 | 19篇 |
2000年 | 30篇 |
1999年 | 22篇 |
1998年 | 18篇 |
1997年 | 17篇 |
1996年 | 16篇 |
1995年 | 10篇 |
1994年 | 14篇 |
1993年 | 7篇 |
1992年 | 4篇 |
1991年 | 5篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1988年 | 2篇 |
1987年 | 1篇 |
1982年 | 1篇 |
排序方式: 共有916条查询结果,搜索用时 443 毫秒
501.
502.
选用已筛选出以芘为唯一碳源的假单胞菌DY-1(Pseudomonas sp.)作为芘降解菌,采用摇瓶振荡培养方法,研究了不同环境条件对菌DY-1降解芘效率的影响以及降解动力学特性。结果表明,在含芘50 mg/L的条件下培养9 d,降解率达83.2%。最适宜温度为30℃,pH值为7.5,摇床转速为120 r/min,接种量为1.5 mL;在不同培养条件下芘的降解符合一级动力学模型;低浓度Zn2+,Cd2+,Cr6+的存在对芘降解效果影响较小,Cu2+,Pb2+对芘的降解有较强的毒性;加入低浓度有机物质,蔗糖可提高DY-1芘的降解;低浓度萘或蒽的存在可促进芘的降解。 相似文献
503.
反硝化生物滤池深度脱氮机理 总被引:3,自引:0,他引:3
研究了反硝化生物滤池对污水中硝酸盐氮的脱氮机制及其影响因素。结果表明,在实验室小试条件下,反硝化生物滤池启动14 d后出水基本达到稳定,NO3--N和TN的去除率分别为80%~88%和76%~80%,COD的去除率达到80%以上。稳定运行期,在室温20~29℃、水力负荷为1.5~2 m3/(m2.h)、COD/TN为3.7~4.5的条件下,反应器对NO3--N和TN的去除率分别为70%~85%和47%~64%,且在运行过程中出现了少量NO2--N的积累。分析反硝化生物滤池沿水流方向有机物浓度及氮形态分布发现,沿水流方向NH4+-N浓度基本保持不变;NO2--N浓度在滤层底部至40 cm高处积累较为明显,其后浓度基本不变。 相似文献
504.
采用一种新的工艺技术方法即水解酸化-改良UASB工艺处理玉米酒精废水。结果表明,在改良UASB运行60 d顺利启动完成后,进水COD在5 470~7 910 mg/L之间,TN在70~107 mg/L之间,TP在115~187 mg/L之间,SS在864~1 490 mg/L之间的条件下,水解酸化对COD和SS的去除率分别达50%和51%,NH3-N经过水解酸化后升高。改良UASB对COD的去除率达80%,对NH3-N、TN和TP也有一定去除,去除率分别为12%、17%和20%,经过水解酸化及改良UASB处理利于后续好氧处理。 相似文献
505.
Jingjing Fang Na Yang Liming Shao 《Journal of the Air & Waste Management Association (1995)》2013,63(11):1287-1297
The concentrations and chromatographic profiles of gaseous pollutants emitted from a municipal solid waste (MSW) biological treatment plant were investigated to identify the major odor substances and atmospheric photochemical reactive species (PRS). Four methods were used to measure different gaseous pollutants in this study, including colorimetric tubes, gas chromatography with mass spectrometry/flame ionization detection/pulsed flame photometric detection (GC-MS/FID/PFPD) preceded by cold trap concentration, GC-FID preceded by solid-phase microextraction (SPME), and high-performance liquid chromatography (HPLC) after derivation by 2,4-dinitrophenylhydrazine (DNPH). Seventy-five gaseous compounds belonging to nine groups (nitrogen compounds, sulfur compounds, alkanes, alkenes, aromatics, terpenes, alcohols, carbonyls, and volatile fatty acids [VFAs]) were identified. In the pre-biotreatment facility, the total concentration of the gaseous pollutants reached the maximum value on day 7 (317 ppm). During the post-biotreatment process, the total concentration of gaseous pollutants decreased from 331 ppm at the beginning to 162 ppm in the end. The group with the greatest decrease was carbonyls, from 64 to 7.4 ppm, followed by alcohols, from 40 to 4.5 ppm, which were both oxygenated compounds. The proportion of aromatics was notably high in the pre-mechanical treatment facility, accounting for 50.6% of the total, revealing the xenobiotic compounds disseminated by stirring and agitating the waste in the initial stage. The proportions of nitrogen compounds were lower in the pre- and post-mechanical treatment facilities (1.5% and 6.9%) than in the pre- and post-biotreatment facilities (11.9% and 13.8%), suggesting that their generation was closely associated with waste degradation. The major odor compounds in the facilities were acetic acid, butyric acid, valeric acid, isovaleric acid, and dimethyl sulfide. The major PRS in the facilities were aromatics, acetaldehyde, butyraldehyde, hexanal, isopentyl aldehyde, alcohol, α-pinene, limonene, and terpinene. Outside the facilities, VFAs and aromatics were the most important compounds causing an environmental impact.
Implications: The aim of this work is to assess the gaseous environmental impacts of mechanical biological treatment technology. The emission of gaseous pollutants greatly affects the living quality of nearby residents and odor complaints are becoming a major problem now. In this study, the authors utilized various pretreatment and analytical methods to obtain integrated emission information of gaseous pollutants. The results showed the transformation and fate of the gas pollutants during the treatment processes, which would help to improve the processes and to mitigate gaseous pollution. Supplemental Materials: Supplemental materials are available for this paper. Go to the publisher's online edition of the Journal of the Air & Waste Management Association for information on the concentrations of the nine compound families at different sampling locations in the plant. 相似文献
506.
双波长紫外吸收法有机废水COD测量技术与仪器设计 总被引:1,自引:0,他引:1
紫外吸收法直接测定有机废水COD是一种无需化学试剂、无样品前处理、无二次污染的绿色无损检测技术,但在实际应用中发现,有机废水中的悬浮物对测量结果产生较大影响.以实际废水水样为例,详细阐述了双波长紫外吸收法测量有机废水COD的操作方法及其消除悬浮物干扰的原理,并介绍了运用该技术设计开发的COD在线测量仪器.该仪器采用嵌入式计算机系统实时采集和处理数据,根据实际废水在双波长测量条件下的有效紫外吸光度快速推算出其COD值,具有快速、准确、无污染的特点. 相似文献
507.
508.
Estimate of initial isoprene contribution to ozone formation potential in Beijing, China 总被引:6,自引:0,他引:6
Xin Xie Min Shao Ying Liu Sihua Lu Chih-Chung Chang Zhong-Ming Chen 《Atmospheric environment (Oxford, England : 1994)》2008,42(24):6000-6010
Volatile organic compounds (VOCs) are important precursors of tropospheric ozone formation. Isoprene contributions to ozone formation by using ambient mixing ratios are generally underestimated because of rapid chemical losses. In this study, ambient mixing ratios of major VOC species were continuously measured at Peking university (PKU) and YUFA, urban and sub-urban sites in Beijing, the city that will host 2008 Olympic Games. The observed mixing ratios of methyl vinyl ketone (MVK), methacrolein (MACR) and isoprene were used to derive the mixing ratios of initial isoprene, which means the ambient isoprene level before it undergoes any photochemical reaction with OH radicals. The average mixing ratios of initial isoprene were 3.3±1.6 and 2.9±1.5 ppbv at PKU and YUFA sites, respectively. The percentages of initial isoprene in total initial VOCs were 10.8% at PKU site and 11.4% at YUFA site, in reasonable agreement with the isoprene contribution in total VOC emissions as derived from source inventories. Maximum increment reactivity (MIR) was used to evaluate the ozone formation potential (OFP) for major VOC species. The OFP for initial isoprene accounted for 23% of the total OFPs for all measured species, compared to 11% using ambient mixing ratios of isoprene at PKU site. Similarly, at YUFA site, the ambient measured isoprene and initial isoprene contributed 10% and 22%, respectively, to the OFPs for total measured VOCs. It seems that isoprene has similar contribution to ozone formation at both sites in Beijing city. 相似文献
509.
Carbonation presents a good prospect for stabilizing alkaline waste materials. The risk of metal leaching from carbonated waste was investigated in the present study; in particular, the effect of the carbonation process and leachate pH on the leaching toxicity of the alkaline air pollution control (APC) residues from municipal solid waste incinerator was evaluated. The pH varying test was conducted to characterize the leaching characteristics of the raw and carbonated residue over a broad range of pH. Partial least square modeling and thermodynamic modeling using Visual MINTEQ were applied to highlight the significant process parameters that controlled metal leaching from the carbonated residue. By lowering the pH to 8-11, the carbonation process reduced markedly the leaching toxicity of the alkaline APC residue; however, the treated APC residue showed similar potential risk of heavy metal release as the raw ash when subjected to an acid shock. The carbonated waste could, thereby, not be disposed of safely. Nonetheless, carbonation could be applied as a temporary stabilization process for heavy metals in APC residues in order to reduce the leaching risk during its transportation and storage before final disposal. 相似文献
510.
Lim Tan E Shao R Grimes CA Ghee Ong K 《Journal of environmental monitoring : JEM》2007,9(11):1276-1281
This paper describes the application of magnetoelastic sensors for quantifying the size and deposition rate of sediment samples in costal areas, lakes, and rivers. The magnetoelastic sensor, which is made of inexpensive amorphous ferromagnetic alloy, measures parameters of interest by tracking the changes in its resonant frequency and/or amplitude. Since an increase in mass loading on the sensor surface changes its resonant frequency and amplitude, the deposition rate of sediment particles can be determined in real time by tracking these two quantities. Based on a theoretical model, the size distribution of the sediment particles was also estimated from the deposition rate. 相似文献